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Номер 4, страница 203 - гдз по химии 10 класс учебник Еремин, Кузьменко
Авторы: Еремин В. В., Кузьменко Н. Е., Теренин В. И., Дроздов А. А., Лунин В. В.
Тип: Учебник
Издательство: Просвещение
Год издания: 2023 - 2026
Уровень обучения: углублённый
Цвет обложки: белый, зелёный с радугой
Допущено Министерством просвещения Российской Федерации
Популярные ГДЗ в 10 классе
Глава 3. Углеводороды. Параграф 37. Химические свойства бензола и его гомологов - номер 4, страница 203.
App\Models\Task {#1030 // resources/views/models/task/default.blade.php #connection: "mysql" #table: "tasks" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:24 [ "id" => 663146 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_page_start" => "203" "field_page_end" => null "field_url" => "/10-klass/himiya/eremin-uchebnik/37-4" "field_display_title" => "4" "field_outside_task" => null "field_task_type" => Illuminate\Database\Eloquent\Collection {#1037 #items: array:1 [ 0 => App\Models\Term {#1036 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:6 [ "id" => 26 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "номер" "field_cases" => array:6 [ "field_accusative_case" => "номер" "field_creative_case" => "номером" "field_dative_case" => "номеру" "field_genitive_case" => "номера" "field_nominative_case" => "номер" "field_prepositional_case" => "номере" ] "field_short_name" => "№" ] #original: array:6 [ "id" => 26 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "номер" "field_cases" => array:6 [ "field_accusative_case" => "номер" "field_creative_case" => "номером" "field_dative_case" => "номеру" "field_genitive_case" => "номера" "field_nominative_case" => "номер" "field_prepositional_case" => "номере" ] "field_short_name" => "№" ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "field_match" => null "breadcrumbs" => [] "edition_groups" => Illuminate\Database\Eloquent\Collection {#1035 #items: [] #escapeWhenCastingToString: false } "top_parent_branch" => Illuminate\Database\Eloquent\Collection {#1079 #items: array:1 [ 0 => App\Models\Branch {#1034 #connection: "mysql" #table: "branches" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:24 [ "id" => 662723 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_display_title" => "Углеводороды" "field_branch_order" => "3" "field_url" => null "field_branch_type" => Illuminate\Database\Eloquent\Collection {#1039 #items: array:1 [ 0 => App\Models\Term {#1038 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:7 [ "id" => 29 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Глава" "field_cases" => array:6 [ …6] "field_page_check_not_needed" => null "field_short_name" => null ] #original: array:7 [ "id" => 29 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Глава" "field_cases" => array:6 [ …6] "field_page_check_not_needed" => null "field_short_name" => null ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "field_page_start" => "139" "field_branch_display" => "0" "field_branch_expanded" => "0" "field_display_branch_in_title" => "1" "field_display_task_interval" => "0" "field_display_branch_page" => "1" "field_branch_title_in_content" => "0" "field_navigation_title" => null "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "field_branch_cover" => [] "field_branch_covers" => [] "book" => Illuminate\Database\Eloquent\Collection {#1040 #items: array:1 [ 0 => App\Models\Book {#1041 #connection: "mysql" #table: "books" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:50 [ "id" => 1003 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_tree_default_status" => "tasks" "field_pages_status" => null "field_subject" => Illuminate\Database\Eloquent\Collection {#1042 …2} "field_class" => Illuminate\Database\Eloquent\Collection {#1044 …2} "field_publisher" => Illuminate\Database\Eloquent\Collection {#1046 …2} "field_author" => Illuminate\Database\Eloquent\Collection {#1048 …2} "field_author_foreign" => Illuminate\Database\Eloquent\Collection {#1054 …2} "field_book_type" => Illuminate\Database\Eloquent\Collection {#1055 …2} "field_country" => Illuminate\Database\Eloquent\Collection {#1057 …2} "field_city" => Illuminate\Database\Eloquent\Collection {#1059 …2} "field_series" => Illuminate\Database\Eloquent\Collection {#1061 …2} "field_umk" => Illuminate\Database\Eloquent\Collection {#1062 …2} "field_level_of_education" => Illuminate\Database\Eloquent\Collection {#1063 …2} "field_standart_of_education" => Illuminate\Database\Eloquent\Collection {#1065 …2} "field_publication_number" => "10" "field_publication_type" => Illuminate\Database\Eloquent\Collection {#1067 …2} "field_under_the_edition" => Illuminate\Database\Eloquent\Collection {#1069 …2} "field_under_the_edition_degree" => "доктор химических наук, академика РАН" "field_cover_description" => "с радугой" "field_publication_year" => "2023" "field_publication_year_until" => null "field_part" => "" "field_part_writing" => "" "field_second_foreign_language" => null "field_for_whom" => null "field_allowed" => "Допущено Министерством просвещения Российской Федерации" "field_reserve_field" => null "field_link_to_source" => null "field_tasks_count" => "697" "field_priority" => "10" "field_default_folder" => "/himiya_10/eremin-u23/" "field_isbn" => null "field_cover" => array:1 [ …1] "field_cover_alts" => array:1 [ …1] "field_covers" => array:1 [ …1] "field_popular_book" => null "field_recommended_books" => Illuminate\Database\Eloquent\Collection {#1070 …2} "field_new_book" => Illuminate\Database\Eloquent\Collection {#1071 …2} "field_old_book" => Illuminate\Database\Eloquent\Collection {#1072 …2} "field_url" => "/10-klass/himiya/eremin-uchebnik" "field_cover_color" => Illuminate\Database\Eloquent\Collection {#1073 …2} "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "breadcrumbs" => array:3 [ …3] ] #original: array:50 [ "id" => 1003 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_tree_default_status" => "tasks" "field_pages_status" => null "field_subject" => Illuminate\Database\Eloquent\Collection {#1042 …2} "field_class" => Illuminate\Database\Eloquent\Collection {#1044 …2} "field_publisher" => Illuminate\Database\Eloquent\Collection {#1046 …2} "field_author" => Illuminate\Database\Eloquent\Collection {#1048 …2} "field_author_foreign" => Illuminate\Database\Eloquent\Collection {#1054 …2} "field_book_type" => Illuminate\Database\Eloquent\Collection {#1055 …2} "field_country" => Illuminate\Database\Eloquent\Collection {#1057 …2} "field_city" => Illuminate\Database\Eloquent\Collection {#1059 …2} "field_series" => Illuminate\Database\Eloquent\Collection {#1061 …2} "field_umk" => Illuminate\Database\Eloquent\Collection {#1062 …2} "field_level_of_education" => Illuminate\Database\Eloquent\Collection {#1063 …2} "field_standart_of_education" => Illuminate\Database\Eloquent\Collection {#1065 …2} "field_publication_number" => "10" "field_publication_type" => Illuminate\Database\Eloquent\Collection {#1067 …2} "field_under_the_edition" => Illuminate\Database\Eloquent\Collection {#1069 …2} "field_under_the_edition_degree" => "доктор химических наук, академика РАН" "field_cover_description" => "с радугой" "field_publication_year" => "2023" "field_publication_year_until" => null "field_part" => "" "field_part_writing" => "" "field_second_foreign_language" => null "field_for_whom" => null "field_allowed" => "Допущено Министерством просвещения Российской Федерации" "field_reserve_field" => null "field_link_to_source" => null "field_tasks_count" => "697" "field_priority" => "10" "field_default_folder" => "/himiya_10/eremin-u23/" "field_isbn" => null "field_cover" => array:1 [ …1] "field_cover_alts" => array:1 [ …1] "field_covers" => array:1 [ …1] "field_popular_book" => null "field_recommended_books" => Illuminate\Database\Eloquent\Collection {#1070 …2} "field_new_book" => Illuminate\Database\Eloquent\Collection {#1071 …2} "field_old_book" => Illuminate\Database\Eloquent\Collection {#1072 …2} "field_url" => "/10-klass/himiya/eremin-uchebnik" "field_cover_color" => Illuminate\Database\Eloquent\Collection {#1073 …2} "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "breadcrumbs" => array:3 [ …3] ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "branch_parent" => Illuminate\Database\Eloquent\Collection {#1076 #items: [] #escapeWhenCastingToString: false } ] #original: array:24 [ "id" => 662723 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_display_title" => "Углеводороды" "field_branch_order" => "3" "field_url" => null "field_branch_type" => Illuminate\Database\Eloquent\Collection {#1039} "field_page_start" => "139" "field_branch_display" => "0" "field_branch_expanded" => "0" "field_display_branch_in_title" => "1" "field_display_task_interval" => "0" "field_display_branch_page" => "1" "field_branch_title_in_content" => "0" "field_navigation_title" => null "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "field_branch_cover" => [] "field_branch_covers" => [] "book" => Illuminate\Database\Eloquent\Collection {#1040} "branch_parent" => Illuminate\Database\Eloquent\Collection {#1076} ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "parent_branches" => Illuminate\Database\Eloquent\Collection {#1198 #items: array:2 [ 0 => App\Models\Branch {#1077 #connection: "mysql" #table: "branches" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:24 [ "id" => 662723 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_display_title" => "Углеводороды" "field_branch_order" => "3" "field_url" => null "field_branch_type" => Illuminate\Database\Eloquent\Collection {#1080 #items: array:1 [ 0 => App\Models\Term {#1078 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:7 [ "id" => 29 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Глава" "field_cases" => array:6 [ …6] "field_page_check_not_needed" => null "field_short_name" => null ] #original: array:7 [ "id" => 29 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Глава" "field_cases" => array:6 [ …6] "field_page_check_not_needed" => null "field_short_name" => null ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "field_page_start" => "139" "field_branch_display" => "0" "field_branch_expanded" => "0" "field_display_branch_in_title" => "1" "field_display_task_interval" => "0" "field_display_branch_page" => "1" "field_branch_title_in_content" => "0" "field_navigation_title" => null "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "field_branch_cover" => [] "field_branch_covers" => [] "book" => Illuminate\Database\Eloquent\Collection {#1081 #items: array:1 [ 0 => App\Models\Book {#1082 #connection: "mysql" #table: "books" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:50 [ "id" => 1003 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_tree_default_status" => "tasks" "field_pages_status" => null "field_subject" => Illuminate\Database\Eloquent\Collection {#1083 …2} "field_class" => Illuminate\Database\Eloquent\Collection {#1085 …2} "field_publisher" => Illuminate\Database\Eloquent\Collection {#1087 …2} "field_author" => Illuminate\Database\Eloquent\Collection {#1089 …2} "field_author_foreign" => Illuminate\Database\Eloquent\Collection {#1095 …2} "field_book_type" => Illuminate\Database\Eloquent\Collection {#1096 …2} "field_country" => Illuminate\Database\Eloquent\Collection {#1098 …2} "field_city" => Illuminate\Database\Eloquent\Collection {#1100 …2} "field_series" => Illuminate\Database\Eloquent\Collection {#1102 …2} "field_umk" => Illuminate\Database\Eloquent\Collection {#1103 …2} "field_level_of_education" => Illuminate\Database\Eloquent\Collection {#1104 …2} "field_standart_of_education" => Illuminate\Database\Eloquent\Collection {#1106 …2} "field_publication_number" => "10" "field_publication_type" => Illuminate\Database\Eloquent\Collection {#1108 …2} "field_under_the_edition" => Illuminate\Database\Eloquent\Collection {#1110 …2} "field_under_the_edition_degree" => "доктор химических наук, академика РАН" "field_cover_description" => "с радугой" "field_publication_year" => "2023" "field_publication_year_until" => null "field_part" => "" "field_part_writing" => "" "field_second_foreign_language" => null "field_for_whom" => null "field_allowed" => "Допущено Министерством просвещения Российской Федерации" "field_reserve_field" => null "field_link_to_source" => null "field_tasks_count" => "697" "field_priority" => "10" "field_default_folder" => "/himiya_10/eremin-u23/" "field_isbn" => null "field_cover" => array:1 [ …1] "field_cover_alts" => array:1 [ …1] "field_covers" => array:1 [ …1] "field_popular_book" => null "field_recommended_books" => Illuminate\Database\Eloquent\Collection {#1111 …2} "field_new_book" => Illuminate\Database\Eloquent\Collection {#1112 …2} "field_old_book" => Illuminate\Database\Eloquent\Collection {#1113 …2} "field_url" => "/10-klass/himiya/eremin-uchebnik" "field_cover_color" => Illuminate\Database\Eloquent\Collection {#1114 …2} "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "breadcrumbs" => array:3 [ …3] ] #original: array:50 [ "id" => 1003 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_tree_default_status" => "tasks" "field_pages_status" => null "field_subject" => Illuminate\Database\Eloquent\Collection {#1083 …2} "field_class" => Illuminate\Database\Eloquent\Collection {#1085 …2} "field_publisher" => Illuminate\Database\Eloquent\Collection {#1087 …2} "field_author" => Illuminate\Database\Eloquent\Collection {#1089 …2} "field_author_foreign" => Illuminate\Database\Eloquent\Collection {#1095 …2} "field_book_type" => Illuminate\Database\Eloquent\Collection {#1096 …2} "field_country" => Illuminate\Database\Eloquent\Collection {#1098 …2} "field_city" => Illuminate\Database\Eloquent\Collection {#1100 …2} "field_series" => Illuminate\Database\Eloquent\Collection {#1102 …2} "field_umk" => Illuminate\Database\Eloquent\Collection {#1103 …2} "field_level_of_education" => Illuminate\Database\Eloquent\Collection {#1104 …2} "field_standart_of_education" => Illuminate\Database\Eloquent\Collection {#1106 …2} "field_publication_number" => "10" "field_publication_type" => Illuminate\Database\Eloquent\Collection {#1108 …2} "field_under_the_edition" => Illuminate\Database\Eloquent\Collection {#1110 …2} "field_under_the_edition_degree" => "доктор химических наук, академика РАН" "field_cover_description" => "с радугой" "field_publication_year" => "2023" "field_publication_year_until" => null "field_part" => "" "field_part_writing" => "" "field_second_foreign_language" => null "field_for_whom" => null "field_allowed" => "Допущено Министерством просвещения Российской Федерации" "field_reserve_field" => null "field_link_to_source" => null "field_tasks_count" => "697" "field_priority" => "10" "field_default_folder" => "/himiya_10/eremin-u23/" "field_isbn" => null "field_cover" => array:1 [ …1] "field_cover_alts" => array:1 [ …1] "field_covers" => array:1 [ …1] "field_popular_book" => null "field_recommended_books" => Illuminate\Database\Eloquent\Collection {#1111 …2} "field_new_book" => Illuminate\Database\Eloquent\Collection {#1112 …2} "field_old_book" => Illuminate\Database\Eloquent\Collection {#1113 …2} "field_url" => "/10-klass/himiya/eremin-uchebnik" "field_cover_color" => Illuminate\Database\Eloquent\Collection {#1114 …2} "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "breadcrumbs" => array:3 [ …3] ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "branch_parent" => Illuminate\Database\Eloquent\Collection {#1117 #items: [] #escapeWhenCastingToString: false } ] #original: array:24 [ "id" => 662723 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_display_title" => "Углеводороды" "field_branch_order" => "3" "field_url" => null "field_branch_type" => Illuminate\Database\Eloquent\Collection {#1080} "field_page_start" => "139" "field_branch_display" => "0" "field_branch_expanded" => "0" "field_display_branch_in_title" => "1" "field_display_task_interval" => "0" "field_display_branch_page" => "1" "field_branch_title_in_content" => "0" "field_navigation_title" => null "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "field_branch_cover" => [] "field_branch_covers" => [] "book" => Illuminate\Database\Eloquent\Collection {#1081} "branch_parent" => Illuminate\Database\Eloquent\Collection {#1117} ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } 1 => App\Models\Branch {#1118 #connection: "mysql" #table: "branches" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:24 [ "id" => 662737 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_display_title" => "Химические свойства бензола и его гомологов" "field_branch_order" => "37" "field_url" => null "field_branch_type" => Illuminate\Database\Eloquent\Collection {#1119 #items: array:1 [ 0 => App\Models\Term {#1120 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:7 [ "id" => 32 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Параграф" "field_cases" => array:6 [ …6] "field_page_check_not_needed" => null "field_short_name" => "§" ] #original: array:7 [ "id" => 32 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Параграф" "field_cases" => array:6 [ …6] "field_page_check_not_needed" => null "field_short_name" => "§" ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "field_page_start" => "198" "field_branch_display" => "0" "field_branch_expanded" => "0" "field_display_branch_in_title" => "1" "field_display_task_interval" => "0" "field_display_branch_page" => "1" "field_branch_title_in_content" => "0" "field_navigation_title" => null "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "field_branch_cover" => [] "field_branch_covers" => [] "book" => Illuminate\Database\Eloquent\Collection {#1121 #items: array:1 [ 0 => App\Models\Book {#1122 #connection: "mysql" #table: "books" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:50 [ "id" => 1003 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_tree_default_status" => "tasks" "field_pages_status" => null "field_subject" => Illuminate\Database\Eloquent\Collection {#1123 …2} "field_class" => Illuminate\Database\Eloquent\Collection {#1125 …2} "field_publisher" => Illuminate\Database\Eloquent\Collection {#1127 …2} "field_author" => Illuminate\Database\Eloquent\Collection {#1129 …2} "field_author_foreign" => Illuminate\Database\Eloquent\Collection {#1135 …2} "field_book_type" => Illuminate\Database\Eloquent\Collection {#1136 …2} "field_country" => Illuminate\Database\Eloquent\Collection {#1138 …2} "field_city" => Illuminate\Database\Eloquent\Collection {#1140 …2} "field_series" => Illuminate\Database\Eloquent\Collection {#1142 …2} "field_umk" => Illuminate\Database\Eloquent\Collection {#1143 …2} "field_level_of_education" => Illuminate\Database\Eloquent\Collection {#1144 …2} "field_standart_of_education" => Illuminate\Database\Eloquent\Collection {#1146 …2} "field_publication_number" => "10" "field_publication_type" => Illuminate\Database\Eloquent\Collection {#1148 …2} "field_under_the_edition" => Illuminate\Database\Eloquent\Collection {#1150 …2} "field_under_the_edition_degree" => "доктор химических наук, академика РАН" "field_cover_description" => "с радугой" "field_publication_year" => "2023" "field_publication_year_until" => null "field_part" => "" "field_part_writing" => "" "field_second_foreign_language" => null "field_for_whom" => null "field_allowed" => "Допущено Министерством просвещения Российской Федерации" "field_reserve_field" => null "field_link_to_source" => null "field_tasks_count" => "697" "field_priority" => "10" "field_default_folder" => "/himiya_10/eremin-u23/" "field_isbn" => null "field_cover" => array:1 [ …1] "field_cover_alts" => array:1 [ …1] "field_covers" => array:1 [ …1] "field_popular_book" => null "field_recommended_books" => Illuminate\Database\Eloquent\Collection {#1151 …2} "field_new_book" => Illuminate\Database\Eloquent\Collection {#1152 …2} "field_old_book" => Illuminate\Database\Eloquent\Collection {#1153 …2} "field_url" => "/10-klass/himiya/eremin-uchebnik" "field_cover_color" => Illuminate\Database\Eloquent\Collection {#1154 …2} "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "breadcrumbs" => array:3 [ …3] ] #original: array:50 [ "id" => 1003 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_tree_default_status" => "tasks" "field_pages_status" => null "field_subject" => Illuminate\Database\Eloquent\Collection {#1123 …2} "field_class" => Illuminate\Database\Eloquent\Collection {#1125 …2} "field_publisher" => Illuminate\Database\Eloquent\Collection {#1127 …2} "field_author" => Illuminate\Database\Eloquent\Collection {#1129 …2} "field_author_foreign" => Illuminate\Database\Eloquent\Collection {#1135 …2} "field_book_type" => Illuminate\Database\Eloquent\Collection {#1136 …2} "field_country" => Illuminate\Database\Eloquent\Collection {#1138 …2} "field_city" => Illuminate\Database\Eloquent\Collection {#1140 …2} "field_series" => Illuminate\Database\Eloquent\Collection {#1142 …2} "field_umk" => Illuminate\Database\Eloquent\Collection {#1143 …2} "field_level_of_education" => Illuminate\Database\Eloquent\Collection {#1144 …2} "field_standart_of_education" => Illuminate\Database\Eloquent\Collection {#1146 …2} "field_publication_number" => "10" "field_publication_type" => Illuminate\Database\Eloquent\Collection {#1148 …2} "field_under_the_edition" => Illuminate\Database\Eloquent\Collection {#1150 …2} "field_under_the_edition_degree" => "доктор химических наук, академика РАН" "field_cover_description" => "с радугой" "field_publication_year" => "2023" "field_publication_year_until" => null "field_part" => "" "field_part_writing" => "" "field_second_foreign_language" => null "field_for_whom" => null "field_allowed" => "Допущено Министерством просвещения Российской Федерации" "field_reserve_field" => null "field_link_to_source" => null "field_tasks_count" => "697" "field_priority" => "10" "field_default_folder" => "/himiya_10/eremin-u23/" "field_isbn" => null "field_cover" => array:1 [ …1] "field_cover_alts" => array:1 [ …1] "field_covers" => array:1 [ …1] "field_popular_book" => null "field_recommended_books" => Illuminate\Database\Eloquent\Collection {#1151 …2} "field_new_book" => Illuminate\Database\Eloquent\Collection {#1152 …2} "field_old_book" => Illuminate\Database\Eloquent\Collection {#1153 …2} "field_url" => "/10-klass/himiya/eremin-uchebnik" "field_cover_color" => Illuminate\Database\Eloquent\Collection {#1154 …2} "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "breadcrumbs" => array:3 [ …3] ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "branch_parent" => Illuminate\Database\Eloquent\Collection {#1157 #items: array:1 [ 0 => App\Models\Branch {#1158 #connection: "mysql" #table: "branches" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:24 [ "id" => 662723 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_display_title" => "Углеводороды" "field_branch_order" => "3" "field_url" => null "field_branch_type" => Illuminate\Database\Eloquent\Collection {#1159 …2} "field_page_start" => "139" "field_branch_display" => "0" "field_branch_expanded" => "0" "field_display_branch_in_title" => "1" "field_display_task_interval" => "0" "field_display_branch_page" => "1" "field_branch_title_in_content" => "0" "field_navigation_title" => null "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "field_branch_cover" => [] "field_branch_covers" => [] "book" => Illuminate\Database\Eloquent\Collection {#1161 …2} "branch_parent" => Illuminate\Database\Eloquent\Collection {#1197 …2} ] #original: array:24 [ "id" => 662723 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_display_title" => "Углеводороды" "field_branch_order" => "3" "field_url" => null "field_branch_type" => Illuminate\Database\Eloquent\Collection {#1159 …2} "field_page_start" => "139" "field_branch_display" => "0" "field_branch_expanded" => "0" "field_display_branch_in_title" => "1" "field_display_task_interval" => "0" "field_display_branch_page" => "1" "field_branch_title_in_content" => "0" "field_navigation_title" => null "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "field_branch_cover" => [] "field_branch_covers" => [] "book" => Illuminate\Database\Eloquent\Collection {#1161 …2} "branch_parent" => Illuminate\Database\Eloquent\Collection {#1197 …2} ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } ] #original: array:24 [ "id" => 662737 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_display_title" => "Химические свойства бензола и его гомологов" "field_branch_order" => "37" "field_url" => null "field_branch_type" => Illuminate\Database\Eloquent\Collection {#1119} "field_page_start" => "198" "field_branch_display" => "0" "field_branch_expanded" => "0" "field_display_branch_in_title" => "1" "field_display_task_interval" => "0" "field_display_branch_page" => "1" "field_branch_title_in_content" => "0" "field_navigation_title" => null "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "field_branch_cover" => [] "field_branch_covers" => [] "book" => Illuminate\Database\Eloquent\Collection {#1121} "branch_parent" => Illuminate\Database\Eloquent\Collection {#1157} ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "content" => Illuminate\Database\Eloquent\Collection {#1224 #items: array:3 [ 0 => App\Models\Element {#1200 #connection: "mysql" #table: "elements" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:7 [ "id" => 818815 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "edition" => Illuminate\Database\Eloquent\Collection {#1201 #items: array:1 [ 0 => App\Models\Edition {#1199 #connection: "mysql" #table: "editions" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:21 [ "id" => 1829 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "title" => "Условие" "field_order" => "1" "field_publisher" => Illuminate\Database\Eloquent\Collection {#1202 …2} "field_content_type" => "free" "field_content_mode" => "text, image" "field_page_content_mode" => "image" "field_content_text_checked" => null "field_page_content_text_checked" => "0" "field_solution_author" => "Автор" "field_moderator" => "vadim" "field_edition_type" => "statement" "field_root_dir" => "0-" "field_responsible" => Illuminate\Database\Eloquent\Collection {#1204 …2} "field_comment" => null "field_similar_book" => Illuminate\Database\Eloquent\Collection {#1205 …2} "field_process_formula" => "katex" …2 ] #original: array:21 [ …21] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } ] #escapeWhenCastingToString: false } "task" => array:2 [ "refs" => "663146" "type" => "task" ] "text" => "<p><strong>4.</strong> Почему ароматические углеводороды горят коптящим пламенем?</p>" "img" => array:1 [ 0 => array:5 [ "name" => "4-1.jpg" "alt" => null "width" => "846" "height" => 106 "path" => "/media/himiya_10/eremin-u23/0-37/4-1.webp?ts=1738779586" ] ] ] #original: array:7 [ "id" => 818815 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "edition" => Illuminate\Database\Eloquent\Collection {#1201} "task" => array:2 [ "refs" => "663146" "type" => "task" ] "text" => "<p><strong>4.</strong> Почему ароматические углеводороды горят коптящим пламенем?</p>" "img" => array:1 [ 0 => array:5 [ "name" => "4-1.jpg" "alt" => null "width" => "846" "height" => 106 "path" => "/media/himiya_10/eremin-u23/0-37/4-1.webp?ts=1738779586" ] ] ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } 1 => App\Models\Element {#1207 #connection: "mysql" #table: "elements" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:6 [ "id" => 819048 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "edition" => Illuminate\Database\Eloquent\Collection {#1208 #items: array:1 [ 0 => App\Models\Edition {#1209 #connection: "mysql" #table: "editions" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:21 [ …21] #original: array:21 [ …21] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } ] #escapeWhenCastingToString: false } "task" => array:2 [ "refs" => "663146" "type" => "task" ] "img" => array:1 [ 0 => array:5 [ "name" => "4-1.jpg" "alt" => null "width" => "1984" "height" => 314 "path" => "/media/himiya_10/eremin-u23/1-37/4-1.webp?ts=1738779664" ] ] ] #original: array:6 [ "id" => 819048 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "edition" => Illuminate\Database\Eloquent\Collection {#1208} "task" => array:2 [ "refs" => "663146" "type" => "task" ] "img" => array:1 [ 0 => array:5 [ "name" => "4-1.jpg" "alt" => null "width" => "1984" "height" => 314 "path" => "/media/himiya_10/eremin-u23/1-37/4-1.webp?ts=1738779664" ] ] ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } 2 => App\Models\Element {#1215 #connection: "mysql" #table: "elements" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:6 [ "id" => 1515550 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "edition" => Illuminate\Database\Eloquent\Collection {#1216 #items: array:1 [ 0 => App\Models\Edition {#1217 #connection: "mysql" #table: "editions" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:21 [ …21] #original: array:21 [ …21] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } ] #escapeWhenCastingToString: false } "task" => array:2 [ "refs" => "663146" "type" => "task" ] "text" => "<p><strong>Решение</strong></p><p>Ароматические углеводороды (арены) горят коптящим пламенем из-за очень высокого содержания углерода в их молекулах по сравнению с другими классами углеводородов. Это приводит к тому, что при горении в обычных условиях (на воздухе) происходит неполное сгорание.</p><p>Ключевым фактором является высокая массовая доля углерода ($\omega(C)$). Давайте сравним ее для ароматического углеводорода бензола и неароматического углеводорода гексана, у которых одинаковое число атомов углерода.</p><p>Массовая доля элемента вычисляется по формуле (используя округленные атомные массы $A_r(C)=12$, $A_r(H)=1$):</p><p>$\omega(Э) = \frac{n \cdot A_r(Э)}{M_r(\text{вещества})} \cdot 100\%$</p><p>Для <strong>бензола ($C_6H_6$)</strong>:</p><p>Относительная молекулярная масса: $M_r(C_6H_6) = 6 \cdot 12 + 6 \cdot 1 = 78$.</p><p>Массовая доля углерода: $\omega(C) = \frac{6 \cdot 12}{78} \cdot 100\% \approx 92.3\%$.</p><p>Для сравнения, для <strong>гексана ($C_6H_{14}$), алкана</strong>:</p><p>Относительная молекулярная масса: $M_r(C_6H_{14}) = 6 \cdot 12 + 14 \cdot 1 = 86$.</p><p>Массовая доля углерода: $\omega(C) = \frac{6 \cdot 12}{86} \cdot 100\% \approx 83.7\%$.</p><p>Как видно из расчетов, в бензоле доля углерода значительно выше. Для полного сгорания углеводорода до углекислого газа ($CO_2$) и воды ($H_2O$) требуется большое количество кислорода. Уравнение полного сгорания бензола выглядит так:</p><p>$2C_6H_6 + 15O_2 \rightarrow 12CO_2 + 6H_2O$</p><p>При горении на воздухе, где концентрация кислорода ограничена (около 21%), его часто не хватает для полного окисления всего углерода. В результате часть углерода не сгорает до $CO_2$, а выделяется в виде мелкодисперсных частиц элементарного углерода — сажи ($C$). Эти раскаленные в пламени частицы сажи и придают ему характерный яркий, но коптящий вид.</p><p>Процесс неполного сгорания можно упрощенно представить так:</p><p>$C_6H_6 + \text{недостаток } O_2 \rightarrow xC + yCO + zCO_2 + kH_2O$</p><p>Таким образом, чем выше содержание углерода в углеводороде, тем больше кислорода требуется для его полного сгорания и тем вероятнее образование сажи при горении в воздушной среде.</p><p><strong>Ответ:</strong></p><p>Ароматические углеводороды горят коптящим пламенем из-за высокой массовой доли углерода в их молекулах. При горении на воздухе кислорода не хватает для полного окисления, что приводит к неполному сгоранию и образованию частиц сажи (элементарного углерода), которые и создают копоть.</p>" ] #original: array:6 [ "id" => 1515550 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "edition" => Illuminate\Database\Eloquent\Collection {#1216} "task" => array:2 [ "refs" => "663146" "type" => "task" ] "text" => "<p><strong>Решение</strong></p><p>Ароматические углеводороды (арены) горят коптящим пламенем из-за очень высокого содержания углерода в их молекулах по сравнению с другими классами углеводородов. Это приводит к тому, что при горении в обычных условиях (на воздухе) происходит неполное сгорание.</p><p>Ключевым фактором является высокая массовая доля углерода ($\omega(C)$). Давайте сравним ее для ароматического углеводорода бензола и неароматического углеводорода гексана, у которых одинаковое число атомов углерода.</p><p>Массовая доля элемента вычисляется по формуле (используя округленные атомные массы $A_r(C)=12$, $A_r(H)=1$):</p><p>$\omega(Э) = \frac{n \cdot A_r(Э)}{M_r(\text{вещества})} \cdot 100\%$</p><p>Для <strong>бензола ($C_6H_6$)</strong>:</p><p>Относительная молекулярная масса: $M_r(C_6H_6) = 6 \cdot 12 + 6 \cdot 1 = 78$.</p><p>Массовая доля углерода: $\omega(C) = \frac{6 \cdot 12}{78} \cdot 100\% \approx 92.3\%$.</p><p>Для сравнения, для <strong>гексана ($C_6H_{14}$), алкана</strong>:</p><p>Относительная молекулярная масса: $M_r(C_6H_{14}) = 6 \cdot 12 + 14 \cdot 1 = 86$.</p><p>Массовая доля углерода: $\omega(C) = \frac{6 \cdot 12}{86} \cdot 100\% \approx 83.7\%$.</p><p>Как видно из расчетов, в бензоле доля углерода значительно выше. Для полного сгорания углеводорода до углекислого газа ($CO_2$) и воды ($H_2O$) требуется большое количество кислорода. Уравнение полного сгорания бензола выглядит так:</p><p>$2C_6H_6 + 15O_2 \rightarrow 12CO_2 + 6H_2O$</p><p>При горении на воздухе, где концентрация кислорода ограничена (около 21%), его часто не хватает для полного окисления всего углерода. В результате часть углерода не сгорает до $CO_2$, а выделяется в виде мелкодисперсных частиц элементарного углерода — сажи ($C$). Эти раскаленные в пламени частицы сажи и придают ему характерный яркий, но коптящий вид.</p><p>Процесс неполного сгорания можно упрощенно представить так:</p><p>$C_6H_6 + \text{недостаток } O_2 \rightarrow xC + yCO + zCO_2 + kH_2O$</p><p>Таким образом, чем выше содержание углерода в углеводороде, тем больше кислорода требуется для его полного сгорания и тем вероятнее образование сажи при горении в воздушной среде.</p><p><strong>Ответ:</strong></p><p>Ароматические углеводороды горят коптящим пламенем из-за высокой массовой доли углерода в их молекулах. При горении на воздухе кислорода не хватает для полного окисления, что приводит к неполному сгоранию и образованию частиц сажи (элементарного углерода), которые и создают копоть.</p>" ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "next" => array:2 [ "refs" => "663147" "type" => "task" ] "previous" => array:2 [ "refs" => "663145" "type" => "task" ] "book" => Illuminate\Database\Eloquent\Collection {#1261 #items: array:1 [ 0 => App\Models\Book {#1225 #connection: "mysql" #table: "books" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:50 [ "id" => 1003 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_tree_default_status" => "tasks" "field_pages_status" => null "field_subject" => Illuminate\Database\Eloquent\Collection {#1226 #items: array:1 [ 0 => App\Models\Term {#1223 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:10 [ …10] #original: array:10 [ …10] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } ] #escapeWhenCastingToString: false } "field_class" => Illuminate\Database\Eloquent\Collection {#1227 #items: array:1 [ 0 => App\Models\Term {#1228 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:6 [ …6] #original: array:6 [ …6] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } ] #escapeWhenCastingToString: false } "field_publisher" => Illuminate\Database\Eloquent\Collection {#1229 #items: array:1 [ 0 => App\Models\Term {#1230 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:6 [ …6] #original: array:6 [ …6] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } ] #escapeWhenCastingToString: false } "field_author" => Illuminate\Database\Eloquent\Collection {#1231 #items: array:5 [ 0 => App\Models\Term {#1232 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:12 [ …12] #original: array:12 [ …12] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } 1 => App\Models\Term {#1233 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:12 [ …12] #original: array:12 [ …12] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } 2 => App\Models\Term {#1234 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:12 [ …12] #original: array:12 [ …12] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } 3 => App\Models\Term {#1235 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:12 [ …12] #original: array:12 [ …12] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } 4 => App\Models\Term {#1236 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:12 [ …12] #original: array:12 [ …12] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } ] #escapeWhenCastingToString: false } "field_author_foreign" => Illuminate\Database\Eloquent\Collection {#1237 #items: [] #escapeWhenCastingToString: false } "field_book_type" => Illuminate\Database\Eloquent\Collection {#1238 #items: array:1 [ 0 => App\Models\Term {#1239 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:10 [ …10] #original: array:10 [ …10] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } ] #escapeWhenCastingToString: false } "field_country" => Illuminate\Database\Eloquent\Collection {#1240 #items: array:1 [ 0 => App\Models\Term {#1241 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:6 [ …6] #original: array:6 [ …6] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } ] #escapeWhenCastingToString: false } "field_city" => Illuminate\Database\Eloquent\Collection {#1242 #items: array:1 [ 0 => App\Models\Term {#1243 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:6 [ …6] #original: array:6 [ …6] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } ] #escapeWhenCastingToString: false } "field_series" => Illuminate\Database\Eloquent\Collection {#1244 #items: [] #escapeWhenCastingToString: false } "field_umk" => Illuminate\Database\Eloquent\Collection {#1245 #items: [] #escapeWhenCastingToString: false } "field_level_of_education" => Illuminate\Database\Eloquent\Collection {#1246 #items: array:1 [ 0 => App\Models\Term {#1247 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:6 [ …6] #original: array:6 [ …6] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } ] #escapeWhenCastingToString: false } "field_standart_of_education" => Illuminate\Database\Eloquent\Collection {#1248 #items: array:1 [ 0 => App\Models\Term {#1249 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:10 [ …10] #original: array:10 [ …10] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } ] #escapeWhenCastingToString: false } "field_publication_number" => "10" "field_publication_type" => Illuminate\Database\Eloquent\Collection {#1250 #items: array:1 [ 0 => App\Models\Term {#1251 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:6 [ …6] #original: array:6 [ …6] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } ] #escapeWhenCastingToString: false } "field_under_the_edition" => Illuminate\Database\Eloquent\Collection {#1252 #items: array:1 [ 0 => App\Models\Term {#1236} ] #escapeWhenCastingToString: false } "field_under_the_edition_degree" => "доктор химических наук, академика РАН" "field_cover_description" => "с радугой" "field_publication_year" => "2023" "field_publication_year_until" => null "field_part" => "" "field_part_writing" => "" "field_second_foreign_language" => null "field_for_whom" => null "field_allowed" => "Допущено Министерством просвещения Российской Федерации" "field_reserve_field" => null "field_link_to_source" => null "field_tasks_count" => "697" "field_priority" => "10" "field_default_folder" => "/himiya_10/eremin-u23/" "field_isbn" => null "field_cover" => array:1 [ 0 => "/media/himiya_10/eremin-u23/covers/cover1.webp?ts=1738768732" ] "field_cover_alts" => array:1 [ 0 => "" ] "field_covers" => array:1 [ 0 => array:4 [ "path" => "/media/himiya_10/eremin-u23/covers/cover1.webp?ts=1738768732" "alt" => "" "width" => "1200" "height" => "1576" ] ] "field_popular_book" => null "field_recommended_books" => Illuminate\Database\Eloquent\Collection {#1253 #items: [] #escapeWhenCastingToString: false } "field_new_book" => Illuminate\Database\Eloquent\Collection {#1254 #items: [] #escapeWhenCastingToString: false } "field_old_book" => Illuminate\Database\Eloquent\Collection {#1255 #items: [] #escapeWhenCastingToString: false } "field_url" => "/10-klass/himiya/eremin-uchebnik" "field_cover_color" => Illuminate\Database\Eloquent\Collection {#1256 #items: array:2 [ 0 => App\Models\Term {#1257 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:6 [ …6] #original: array:6 [ …6] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } 1 => App\Models\Term {#1258 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:6 [ …6] #original: array:6 [ …6] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } ] #escapeWhenCastingToString: false } "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "breadcrumbs" => array:3 [ "class" => 381 "subject" => 558 "class_subject" => 500 ] ] #original: array:50 [ "id" => 1003 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_tree_default_status" => "tasks" "field_pages_status" => null "field_subject" => Illuminate\Database\Eloquent\Collection {#1226} "field_class" => Illuminate\Database\Eloquent\Collection {#1227} "field_publisher" => Illuminate\Database\Eloquent\Collection {#1229} "field_author" => Illuminate\Database\Eloquent\Collection {#1231} "field_author_foreign" => Illuminate\Database\Eloquent\Collection {#1237} "field_book_type" => Illuminate\Database\Eloquent\Collection {#1238} "field_country" => Illuminate\Database\Eloquent\Collection {#1240} "field_city" => Illuminate\Database\Eloquent\Collection {#1242} "field_series" => Illuminate\Database\Eloquent\Collection {#1244} "field_umk" => Illuminate\Database\Eloquent\Collection {#1245} "field_level_of_education" => Illuminate\Database\Eloquent\Collection {#1246} "field_standart_of_education" => Illuminate\Database\Eloquent\Collection {#1248} "field_publication_number" => "10" "field_publication_type" => Illuminate\Database\Eloquent\Collection {#1250} "field_under_the_edition" => Illuminate\Database\Eloquent\Collection {#1252} "field_under_the_edition_degree" => "доктор химических наук, академика РАН" "field_cover_description" => "с радугой" "field_publication_year" => "2023" "field_publication_year_until" => null "field_part" => "" "field_part_writing" => "" "field_second_foreign_language" => null "field_for_whom" => null "field_allowed" => "Допущено Министерством просвещения Российской Федерации" "field_reserve_field" => null "field_link_to_source" => null "field_tasks_count" => "697" "field_priority" => "10" "field_default_folder" => "/himiya_10/eremin-u23/" "field_isbn" => null "field_cover" => array:1 [ 0 => "/media/himiya_10/eremin-u23/covers/cover1.webp?ts=1738768732" ] "field_cover_alts" => array:1 [ 0 => "" ] "field_covers" => array:1 [ 0 => array:4 [ "path" => "/media/himiya_10/eremin-u23/covers/cover1.webp?ts=1738768732" "alt" => "" "width" => "1200" "height" => "1576" ] ] "field_popular_book" => null "field_recommended_books" => Illuminate\Database\Eloquent\Collection {#1253} "field_new_book" => Illuminate\Database\Eloquent\Collection {#1254} "field_old_book" => Illuminate\Database\Eloquent\Collection {#1255} "field_url" => "/10-klass/himiya/eremin-uchebnik" "field_cover_color" => Illuminate\Database\Eloquent\Collection {#1256} "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "breadcrumbs" => array:3 [ "class" => 381 "subject" => 558 "class_subject" => 500 ] ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "page" => Illuminate\Database\Eloquent\Collection {#1527 #items: array:1 [ 0 => App\Models\BookPage {#1032 #connection: "mysql" #table: "book_pages" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:21 [ "id" => 926099 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_page_start" => "203" "field_url" => "/10-klass/himiya/eremin-uchebnik/page-203" "field_display_title" => "203" "field_folder" => "1" "field_image_name" => "203" "field_branch_parent" => Illuminate\Database\Eloquent\Collection {#1023 #items: [] #escapeWhenCastingToString: false } "field_weight" => "0" "field_book_parent" => Illuminate\Database\Eloquent\Collection {#331 #items: array:1 [ 0 => App\Models\Book {#1259 #connection: "mysql" #table: "books" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:50 [ …50] #original: array:50 [ …50] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } ] #escapeWhenCastingToString: false } "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "edition_groups" => Illuminate\Database\Eloquent\Collection {#1295 #items: [] #escapeWhenCastingToString: false } "content" => Illuminate\Database\Eloquent\Collection {#1296 #items: array:1 [ 0 => App\Models\Element {#1297 #connection: "mysql" #table: "elements" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:6 [ …6] #original: array:6 [ …6] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } ] #escapeWhenCastingToString: false } "next" => array:2 [ "refs" => "926100" "type" => "book_page" ] "previous" => array:2 [ "refs" => "926098" "type" => "book_page" ] "tasks" => Illuminate\Database\Eloquent\Collection {#1305 #items: array:12 [ 0 => App\Models\Task {#1306 #connection: "mysql" #table: "tasks" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:24 [ …24] #original: array:24 [ …24] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } 1 => App\Models\Task {#1382 #connection: "mysql" #table: "tasks" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:24 [ …24] #original: array:24 [ …24] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } 2 => App\Models\Task {#1395 #connection: "mysql" #table: "tasks" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:24 [ …24] #original: array:24 [ …24] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } 3 => App\Models\Task {#1408 #connection: "mysql" #table: "tasks" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:24 [ …24] #original: array:24 [ …24] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } 4 => App\Models\Task {#1421 #connection: "mysql" #table: "tasks" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:24 [ …24] #original: array:24 [ …24] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } 5 => App\Models\Task {#1434 #connection: "mysql" #table: "tasks" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:24 [ …24] #original: array:24 [ …24] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } 6 => App\Models\Task {#1447 #connection: "mysql" #table: "tasks" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:24 [ …24] #original: array:24 [ …24] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } 7 => App\Models\Task {#1460 #connection: "mysql" #table: "tasks" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:24 [ …24] #original: array:24 [ …24] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } 8 => App\Models\Task {#1473 #connection: "mysql" #table: "tasks" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:24 [ …24] #original: array:24 [ …24] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } 9 => App\Models\Task {#1486 #connection: "mysql" #table: "tasks" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:24 [ …24] #original: array:24 [ …24] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } 10 => App\Models\Task {#1499 #connection: "mysql" #table: "tasks" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:24 [ …24] #original: array:24 [ …24] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } 11 => App\Models\Task {#1512 #connection: "mysql" #table: "tasks" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:24 [ …24] #original: array:24 [ …24] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } ] #escapeWhenCastingToString: false } ] #original: array:21 [ "id" => 926099 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_page_start" => "203" "field_url" => "/10-klass/himiya/eremin-uchebnik/page-203" "field_display_title" => "203" "field_folder" => "1" "field_image_name" => "203" "field_branch_parent" => Illuminate\Database\Eloquent\Collection {#1023} "field_weight" => "0" "field_book_parent" => Illuminate\Database\Eloquent\Collection {#331} "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "edition_groups" => Illuminate\Database\Eloquent\Collection {#1295} "content" => Illuminate\Database\Eloquent\Collection {#1296} "next" => array:2 [ "refs" => "926100" "type" => "book_page" ] "previous" => array:2 [ "refs" => "926098" "type" => "book_page" ] "tasks" => Illuminate\Database\Eloquent\Collection {#1305} ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } ] #original: array:24 [ "id" => 663146 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_page_start" => "203" "field_page_end" => null "field_url" => "/10-klass/himiya/eremin-uchebnik/37-4" "field_display_title" => "4" "field_outside_task" => null "field_task_type" => Illuminate\Database\Eloquent\Collection {#1037} "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "field_match" => null "breadcrumbs" => [] "edition_groups" => Illuminate\Database\Eloquent\Collection {#1035} "top_parent_branch" => Illuminate\Database\Eloquent\Collection {#1079} "parent_branches" => Illuminate\Database\Eloquent\Collection {#1198} "content" => Illuminate\Database\Eloquent\Collection {#1224} "next" => array:2 [ "refs" => "663147" "type" => "task" ] "previous" => array:2 [ "refs" => "663145" "type" => "task" ] "book" => Illuminate\Database\Eloquent\Collection {#1261} "page" => array:2 [ "refs" => "926099" "type" => "book_page" ] ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] }
№4 (с. 203)
Условие. №4 (с. 203)
скриншот условия
4. Почему ароматические углеводороды горят коптящим пламенем?
Решение. №4 (с. 203)
Решение 2. №4 (с. 203)
Решение
Ароматические углеводороды (арены) горят коптящим пламенем из-за очень высокого содержания углерода в их молекулах по сравнению с другими классами углеводородов. Это приводит к тому, что при горении в обычных условиях (на воздухе) происходит неполное сгорание.
Ключевым фактором является высокая массовая доля углерода ($\omega(C)$). Давайте сравним ее для ароматического углеводорода бензола и неароматического углеводорода гексана, у которых одинаковое число атомов углерода.
Массовая доля элемента вычисляется по формуле (используя округленные атомные массы $A_r(C)=12$, $A_r(H)=1$):
$\omega(Э) = \frac{n \cdot A_r(Э)}{M_r(\text{вещества})} \cdot 100\%$
Для бензола ($C_6H_6$):
Относительная молекулярная масса: $M_r(C_6H_6) = 6 \cdot 12 + 6 \cdot 1 = 78$.
Массовая доля углерода: $\omega(C) = \frac{6 \cdot 12}{78} \cdot 100\% \approx 92.3\%$.
Для сравнения, для гексана ($C_6H_{14}$), алкана:
Относительная молекулярная масса: $M_r(C_6H_{14}) = 6 \cdot 12 + 14 \cdot 1 = 86$.
Массовая доля углерода: $\omega(C) = \frac{6 \cdot 12}{86} \cdot 100\% \approx 83.7\%$.
Как видно из расчетов, в бензоле доля углерода значительно выше. Для полного сгорания углеводорода до углекислого газа ($CO_2$) и воды ($H_2O$) требуется большое количество кислорода. Уравнение полного сгорания бензола выглядит так:
$2C_6H_6 + 15O_2 \rightarrow 12CO_2 + 6H_2O$
При горении на воздухе, где концентрация кислорода ограничена (около 21%), его часто не хватает для полного окисления всего углерода. В результате часть углерода не сгорает до $CO_2$, а выделяется в виде мелкодисперсных частиц элементарного углерода — сажи ($C$). Эти раскаленные в пламени частицы сажи и придают ему характерный яркий, но коптящий вид.
Процесс неполного сгорания можно упрощенно представить так:
$C_6H_6 + \text{недостаток } O_2 \rightarrow xC + yCO + zCO_2 + kH_2O$
Таким образом, чем выше содержание углерода в углеводороде, тем больше кислорода требуется для его полного сгорания и тем вероятнее образование сажи при горении в воздушной среде.
Ответ:
Ароматические углеводороды горят коптящим пламенем из-за высокой массовой доли углерода в их молекулах. При горении на воздухе кислорода не хватает для полного окисления, что приводит к неполному сгоранию и образованию частиц сажи (элементарного углерода), которые и создают копоть.
Другие задания:
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