gdz.top
Номер 3, страница 225 - гдз по химии 10 класс учебник Еремин, Кузьменко
Авторы: Еремин В. В., Кузьменко Н. Е., Теренин В. И., Дроздов А. А., Лунин В. В.
Тип: Учебник
Издательство: Просвещение
Год издания: 2023 - 2026
Уровень обучения: углублённый
Цвет обложки: белый, зелёный с радугой
Допущено Министерством просвещения Российской Федерации
Популярные ГДЗ в 10 классе
Глава 3. Углеводороды. Параграф 42. Галогенопроизводные углеводородов - номер 3, страница 225.
App\Models\Task {#1024 // resources/views/models/task/default.blade.php #connection: "mysql" #table: "tasks" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:24 [ "id" => 663192 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_page_start" => "225" "field_page_end" => null "field_url" => "/10-klass/himiya/eremin-uchebnik/42-3" "field_display_title" => "3" "field_outside_task" => null "field_task_type" => Illuminate\Database\Eloquent\Collection {#331 #items: array:1 [ 0 => App\Models\Term {#1029 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:6 [ "id" => 26 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "номер" "field_cases" => array:6 [ "field_accusative_case" => "номер" "field_creative_case" => "номером" "field_dative_case" => "номеру" "field_genitive_case" => "номера" "field_nominative_case" => "номер" "field_prepositional_case" => "номере" ] "field_short_name" => "№" ] #original: array:6 [ "id" => 26 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "номер" "field_cases" => array:6 [ "field_accusative_case" => "номер" "field_creative_case" => "номером" "field_dative_case" => "номеру" "field_genitive_case" => "номера" "field_nominative_case" => "номер" "field_prepositional_case" => "номере" ] "field_short_name" => "№" ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "field_match" => null "breadcrumbs" => [] "edition_groups" => Illuminate\Database\Eloquent\Collection {#1026 #items: [] #escapeWhenCastingToString: false } "top_parent_branch" => Illuminate\Database\Eloquent\Collection {#342 #items: array:1 [ 0 => App\Models\Branch {#1023 #connection: "mysql" #table: "branches" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:24 [ "id" => 662723 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_display_title" => "Углеводороды" "field_branch_order" => "3" "field_url" => null "field_branch_type" => Illuminate\Database\Eloquent\Collection {#333 #items: array:1 [ 0 => App\Models\Term {#1033 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:7 [ "id" => 29 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Глава" "field_cases" => array:6 [ "field_accusative_case" => "Главу" "field_creative_case" => "Главой" "field_dative_case" => "Главе" "field_genitive_case" => "Главы" "field_nominative_case" => "Глава" "field_prepositional_case" => "Главе" ] "field_page_check_not_needed" => null "field_short_name" => null ] #original: array:7 [ "id" => 29 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Глава" "field_cases" => array:6 [ "field_accusative_case" => "Главу" "field_creative_case" => "Главой" "field_dative_case" => "Главе" "field_genitive_case" => "Главы" "field_nominative_case" => "Глава" "field_prepositional_case" => "Главе" ] "field_page_check_not_needed" => null "field_short_name" => null ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "field_page_start" => "139" "field_branch_display" => "0" "field_branch_expanded" => "0" "field_display_branch_in_title" => "1" "field_display_task_interval" => "0" "field_display_branch_page" => "1" "field_branch_title_in_content" => "0" "field_navigation_title" => null "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "field_branch_cover" => [] "field_branch_covers" => [] "book" => Illuminate\Database\Eloquent\Collection {#1030 #items: array:1 [ 0 => App\Models\Book {#1032 #connection: "mysql" #table: "books" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:50 [ "id" => 1003 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_tree_default_status" => "tasks" "field_pages_status" => null "field_subject" => Illuminate\Database\Eloquent\Collection {#1034 #items: array:1 [ 0 => App\Models\Term {#1035 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:10 [ "id" => 6495 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Химия" "field_abbreviated_name" => null "field_cases" => array:6 [ "field_accusative_case" => "химию" "field_creative_case" => "химией" "field_dative_case" => "химии" "field_genitive_case" => "химии" "field_nominative_case" => "химия" "field_prepositional_case" => "химии" ] "field_foreign_lang_name" => null "field_short_name" => null "field_subject_type" => "technical_subject" "field_translit" => "himiya" ] #original: array:10 [ "id" => 6495 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Химия" "field_abbreviated_name" => null "field_cases" => array:6 [ "field_accusative_case" => "химию" "field_creative_case" => "химией" "field_dative_case" => "химии" "field_genitive_case" => "химии" "field_nominative_case" => "химия" "field_prepositional_case" => "химии" ] "field_foreign_lang_name" => null "field_short_name" => null "field_subject_type" => "technical_subject" "field_translit" => "himiya" ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "field_class" => Illuminate\Database\Eloquent\Collection {#1036 #items: array:1 [ 0 => App\Models\Term {#1037 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:6 [ "id" => 5459 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "10" "field_cases" => array:6 [ "field_accusative_case" => "десятый" "field_creative_case" => "десятым" "field_dative_case" => "десятому" "field_genitive_case" => "десятого" "field_nominative_case" => "десятый" "field_prepositional_case" => "десятом" ] "field_translit" => "desjatyj" ] #original: array:6 [ "id" => 5459 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "10" "field_cases" => array:6 [ "field_accusative_case" => "десятый" "field_creative_case" => "десятым" "field_dative_case" => "десятому" "field_genitive_case" => "десятого" "field_nominative_case" => "десятый" "field_prepositional_case" => "десятом" ] "field_translit" => "desjatyj" ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "field_publisher" => Illuminate\Database\Eloquent\Collection {#1038 #items: array:1 [ 0 => App\Models\Term {#1039 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:6 [ "id" => 5153 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Просвещение" "field_cases" => null "field_translit" => "prosveschenie" ] #original: array:6 [ "id" => 5153 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Просвещение" "field_cases" => null "field_translit" => "prosveschenie" ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "field_author" => Illuminate\Database\Eloquent\Collection {#1040 #items: array:5 [ 0 => App\Models\Term {#1041 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:12 [ "id" => 4330 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Еремин" "field_bio" => null "field_degree_rp" => null "field_foreign_lang_name" => null "field_foreign_lang_patronymic" => null "field_foreign_lang_surname" => null "field_name" => "Вадим" "field_patronymic" => "Владимирович" "field_surname_rp" => null ] #original: array:12 [ "id" => 4330 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Еремин" "field_bio" => null "field_degree_rp" => null "field_foreign_lang_name" => null "field_foreign_lang_patronymic" => null "field_foreign_lang_surname" => null "field_name" => "Вадим" "field_patronymic" => "Владимирович" "field_surname_rp" => null ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } 1 => App\Models\Term {#1042 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:12 [ "id" => 4876 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Кузьменко" "field_bio" => null "field_degree_rp" => null "field_foreign_lang_name" => null "field_foreign_lang_patronymic" => null "field_foreign_lang_surname" => null "field_name" => "Николай" "field_patronymic" => "Егорович" "field_surname_rp" => null ] #original: array:12 [ "id" => 4876 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Кузьменко" "field_bio" => null "field_degree_rp" => null "field_foreign_lang_name" => null "field_foreign_lang_patronymic" => null "field_foreign_lang_surname" => null "field_name" => "Николай" "field_patronymic" => "Егорович" "field_surname_rp" => null ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } 2 => App\Models\Term {#1043 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:12 [ "id" => 5912 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Теренин" "field_bio" => null "field_degree_rp" => null "field_foreign_lang_name" => null "field_foreign_lang_patronymic" => null "field_foreign_lang_surname" => null "field_name" => "Владимир" "field_patronymic" => "Ильич" "field_surname_rp" => null ] #original: array:12 [ "id" => 5912 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Теренин" "field_bio" => null "field_degree_rp" => null "field_foreign_lang_name" => null "field_foreign_lang_patronymic" => null "field_foreign_lang_surname" => null "field_name" => "Владимир" "field_patronymic" => "Ильич" "field_surname_rp" => null ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } 3 => App\Models\Term {#1044 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:12 [ "id" => 4290 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Дроздов" "field_bio" => null "field_degree_rp" => null "field_foreign_lang_name" => null "field_foreign_lang_patronymic" => null "field_foreign_lang_surname" => null "field_name" => "Андрей" "field_patronymic" => "Анатольевич" "field_surname_rp" => null ] #original: array:12 [ "id" => 4290 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Дроздов" "field_bio" => null "field_degree_rp" => null "field_foreign_lang_name" => null "field_foreign_lang_patronymic" => null "field_foreign_lang_surname" => null "field_name" => "Андрей" "field_patronymic" => "Анатольевич" "field_surname_rp" => null ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } 4 => App\Models\Term {#1045 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:12 [ "id" => 5031 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Лунин" "field_bio" => null "field_degree_rp" => "доктор химических наук, академика РАН" "field_foreign_lang_name" => null "field_foreign_lang_patronymic" => null "field_foreign_lang_surname" => null "field_name" => "Валерий" "field_patronymic" => "Васильевич" "field_surname_rp" => "Лунина" ] #original: array:12 [ "id" => 5031 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Лунин" "field_bio" => null "field_degree_rp" => "доктор химических наук, академика РАН" "field_foreign_lang_name" => null "field_foreign_lang_patronymic" => null "field_foreign_lang_surname" => null "field_name" => "Валерий" "field_patronymic" => "Васильевич" "field_surname_rp" => "Лунина" ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "field_author_foreign" => Illuminate\Database\Eloquent\Collection {#1046 #items: [] #escapeWhenCastingToString: false } "field_book_type" => Illuminate\Database\Eloquent\Collection {#1047 #items: array:1 [ 0 => App\Models\Term {#1048 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:10 [ "id" => 6671 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Учебник" "field_book_type_foreign" => null "field_cases" => array:6 [ "field_accusative_case" => "учебник" "field_creative_case" => "учебником" "field_dative_case" => "учебнику" "field_genitive_case" => "учебника" "field_nominative_case" => "учебник" "field_prepositional_case" => "учебнике" ] "field_plural_form" => null "field_short_name" => null "field_short_name_foreign" => null "field_translit" => "uchebnik" ] #original: array:10 [ "id" => 6671 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Учебник" "field_book_type_foreign" => null "field_cases" => array:6 [ "field_accusative_case" => "учебник" "field_creative_case" => "учебником" "field_dative_case" => "учебнику" "field_genitive_case" => "учебника" "field_nominative_case" => "учебник" "field_prepositional_case" => "учебнике" ] "field_plural_form" => null "field_short_name" => null "field_short_name_foreign" => null "field_translit" => "uchebnik" ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "field_country" => Illuminate\Database\Eloquent\Collection {#1049 #items: array:1 [ 0 => App\Models\Term {#1050 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:6 [ "id" => 9 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Россия" "field_cases" => array:6 [ "field_accusative_case" => null "field_creative_case" => null "field_dative_case" => null "field_genitive_case" => null "field_nominative_case" => null "field_prepositional_case" => null ] "field_translit" => "rossiya" ] #original: array:6 [ "id" => 9 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Россия" "field_cases" => array:6 [ "field_accusative_case" => null "field_creative_case" => null "field_dative_case" => null "field_genitive_case" => null "field_nominative_case" => null "field_prepositional_case" => null ] "field_translit" => "rossiya" ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "field_city" => Illuminate\Database\Eloquent\Collection {#1051 #items: array:1 [ 0 => App\Models\Term {#1052 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:6 [ "id" => 15 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Москва" "field_cases" => array:6 [ "field_accusative_case" => null "field_creative_case" => null "field_dative_case" => null "field_genitive_case" => null "field_nominative_case" => null "field_prepositional_case" => null ] "field_translit" => "moskva" ] #original: array:6 [ "id" => 15 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Москва" "field_cases" => array:6 [ "field_accusative_case" => null "field_creative_case" => null "field_dative_case" => null "field_genitive_case" => null "field_nominative_case" => null "field_prepositional_case" => null ] "field_translit" => "moskva" ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "field_series" => Illuminate\Database\Eloquent\Collection {#1053 #items: [] #escapeWhenCastingToString: false } "field_umk" => Illuminate\Database\Eloquent\Collection {#1054 #items: [] #escapeWhenCastingToString: false } "field_level_of_education" => Illuminate\Database\Eloquent\Collection {#1055 #items: array:1 [ 0 => App\Models\Term {#1056 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:6 [ "id" => 39 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "углублённый" "field_cases" => array:6 [ "field_accusative_case" => "углубленный" "field_creative_case" => "углубленным" "field_dative_case" => "углубленному" "field_genitive_case" => "углубленного" "field_nominative_case" => "углубленный" "field_prepositional_case" => "углубленном" ] "field_translit" => "uglublennyy" ] #original: array:6 [ "id" => 39 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "углублённый" "field_cases" => array:6 [ "field_accusative_case" => "углубленный" "field_creative_case" => "углубленным" "field_dative_case" => "углубленному" "field_genitive_case" => "углубленного" "field_nominative_case" => "углубленный" "field_prepositional_case" => "углубленном" ] "field_translit" => "uglublennyy" ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "field_standart_of_education" => Illuminate\Database\Eloquent\Collection {#1057 #items: array:1 [ 0 => App\Models\Term {#1058 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:10 [ "id" => 6706 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "ФГОС (старый)" "field_cases" => array:6 [ "field_accusative_case" => null "field_creative_case" => null "field_dative_case" => null "field_genitive_case" => null "field_nominative_case" => null "field_prepositional_case" => null ] "field_color" => null "field_end_year" => "2022" "field_start_year" => "2019" "field_translit" => "fgos-old" "field_type" => null ] #original: array:10 [ "id" => 6706 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "ФГОС (старый)" "field_cases" => array:6 [ "field_accusative_case" => null "field_creative_case" => null "field_dative_case" => null "field_genitive_case" => null "field_nominative_case" => null "field_prepositional_case" => null ] "field_color" => null "field_end_year" => "2022" "field_start_year" => "2019" "field_translit" => "fgos-old" "field_type" => null ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "field_publication_number" => "10" "field_publication_type" => Illuminate\Database\Eloquent\Collection {#1059 #items: array:1 [ 0 => App\Models\Term {#1060 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:6 [ "id" => 33 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "стереотипное" "field_cases" => array:6 [ "field_accusative_case" => null "field_creative_case" => null "field_dative_case" => null …3 ] "field_translit" => "stereotipnoe" ] #original: array:6 [ "id" => 33 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "стереотипное" "field_cases" => array:6 [ …6] "field_translit" => "stereotipnoe" ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "field_under_the_edition" => Illuminate\Database\Eloquent\Collection {#1061 #items: array:1 [ 0 => App\Models\Term {#1045} ] #escapeWhenCastingToString: false } "field_under_the_edition_degree" => "доктор химических наук, академика РАН" "field_cover_description" => "с радугой" "field_publication_year" => "2023" "field_publication_year_until" => null "field_part" => "" "field_part_writing" => "" "field_second_foreign_language" => null "field_for_whom" => null "field_allowed" => "Допущено Министерством просвещения Российской Федерации" "field_reserve_field" => null "field_link_to_source" => null "field_tasks_count" => "697" "field_priority" => "10" "field_default_folder" => "/himiya_10/eremin-u23/" "field_isbn" => null "field_cover" => array:1 [ 0 => "/media/himiya_10/eremin-u23/covers/cover1.webp?ts=1738768732" ] "field_cover_alts" => array:1 [ 0 => "" ] "field_covers" => array:1 [ 0 => array:4 [ "path" => "/media/himiya_10/eremin-u23/covers/cover1.webp?ts=1738768732" "alt" => "" "width" => "1200" "height" => "1576" ] ] "field_popular_book" => null "field_recommended_books" => Illuminate\Database\Eloquent\Collection {#1062 #items: [] #escapeWhenCastingToString: false } "field_new_book" => Illuminate\Database\Eloquent\Collection {#1063 #items: [] #escapeWhenCastingToString: false } "field_old_book" => Illuminate\Database\Eloquent\Collection {#1064 #items: [] #escapeWhenCastingToString: false } "field_url" => "/10-klass/himiya/eremin-uchebnik" "field_cover_color" => Illuminate\Database\Eloquent\Collection {#1065 #items: array:2 [ 0 => App\Models\Term {#1066 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:6 [ "id" => 45 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "белый" "field_cases" => array:6 [ …6] "field_translit" => "belyy" ] #original: array:6 [ "id" => 45 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "белый" "field_cases" => array:6 [ …6] "field_translit" => "belyy" ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } 1 => App\Models\Term {#1067 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:6 [ "id" => 47 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "зелёный" "field_cases" => array:6 [ …6] "field_translit" => "zelyonyy" ] #original: array:6 [ "id" => 47 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "зелёный" "field_cases" => array:6 [ …6] "field_translit" => "zelyonyy" ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "breadcrumbs" => array:3 [ "class" => 381 "subject" => 558 "class_subject" => 500 ] ] #original: array:50 [ "id" => 1003 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_tree_default_status" => "tasks" "field_pages_status" => null "field_subject" => Illuminate\Database\Eloquent\Collection {#1034} "field_class" => Illuminate\Database\Eloquent\Collection {#1036} "field_publisher" => Illuminate\Database\Eloquent\Collection {#1038} "field_author" => Illuminate\Database\Eloquent\Collection {#1040} "field_author_foreign" => Illuminate\Database\Eloquent\Collection {#1046} "field_book_type" => Illuminate\Database\Eloquent\Collection {#1047} "field_country" => Illuminate\Database\Eloquent\Collection {#1049} "field_city" => Illuminate\Database\Eloquent\Collection {#1051} "field_series" => Illuminate\Database\Eloquent\Collection {#1053} "field_umk" => Illuminate\Database\Eloquent\Collection {#1054} "field_level_of_education" => Illuminate\Database\Eloquent\Collection {#1055} "field_standart_of_education" => Illuminate\Database\Eloquent\Collection {#1057} "field_publication_number" => "10" "field_publication_type" => Illuminate\Database\Eloquent\Collection {#1059} "field_under_the_edition" => Illuminate\Database\Eloquent\Collection {#1061} "field_under_the_edition_degree" => "доктор химических наук, академика РАН" "field_cover_description" => "с радугой" "field_publication_year" => "2023" "field_publication_year_until" => null "field_part" => "" "field_part_writing" => "" "field_second_foreign_language" => null "field_for_whom" => null "field_allowed" => "Допущено Министерством просвещения Российской Федерации" "field_reserve_field" => null "field_link_to_source" => null "field_tasks_count" => "697" "field_priority" => "10" "field_default_folder" => "/himiya_10/eremin-u23/" "field_isbn" => null "field_cover" => array:1 [ 0 => "/media/himiya_10/eremin-u23/covers/cover1.webp?ts=1738768732" ] "field_cover_alts" => array:1 [ 0 => "" ] "field_covers" => array:1 [ 0 => array:4 [ "path" => "/media/himiya_10/eremin-u23/covers/cover1.webp?ts=1738768732" "alt" => "" "width" => "1200" "height" => "1576" ] ] "field_popular_book" => null "field_recommended_books" => Illuminate\Database\Eloquent\Collection {#1062} "field_new_book" => Illuminate\Database\Eloquent\Collection {#1063} "field_old_book" => Illuminate\Database\Eloquent\Collection {#1064} "field_url" => "/10-klass/himiya/eremin-uchebnik" "field_cover_color" => Illuminate\Database\Eloquent\Collection {#1065} "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "breadcrumbs" => array:3 [ "class" => 381 "subject" => 558 "class_subject" => 500 ] ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "branch_parent" => Illuminate\Database\Eloquent\Collection {#1068 #items: [] #escapeWhenCastingToString: false } ] #original: array:24 [ "id" => 662723 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_display_title" => "Углеводороды" "field_branch_order" => "3" "field_url" => null "field_branch_type" => Illuminate\Database\Eloquent\Collection {#333} "field_page_start" => "139" "field_branch_display" => "0" "field_branch_expanded" => "0" "field_display_branch_in_title" => "1" "field_display_task_interval" => "0" "field_display_branch_page" => "1" "field_branch_title_in_content" => "0" "field_navigation_title" => null "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "field_branch_cover" => [] "field_branch_covers" => [] "book" => Illuminate\Database\Eloquent\Collection {#1030} "branch_parent" => Illuminate\Database\Eloquent\Collection {#1068} ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "parent_branches" => Illuminate\Database\Eloquent\Collection {#1069 #items: array:2 [ 0 => App\Models\Branch {#1023} 1 => App\Models\Branch {#1070 #connection: "mysql" #table: "branches" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:24 [ "id" => 662742 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_display_title" => "Галогенопроизводные углеводородов" "field_branch_order" => "42" "field_url" => null "field_branch_type" => Illuminate\Database\Eloquent\Collection {#1071 #items: array:1 [ 0 => App\Models\Term {#1072 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:7 [ "id" => 32 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Параграф" "field_cases" => array:6 [ "field_accusative_case" => "Параграф" "field_creative_case" => "Параграфом" "field_dative_case" => "Параграфу" "field_genitive_case" => "Параграфа" "field_nominative_case" => "Параграф" "field_prepositional_case" => "Параграфе" ] "field_page_check_not_needed" => null "field_short_name" => "§" ] #original: array:7 [ "id" => 32 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Параграф" "field_cases" => array:6 [ "field_accusative_case" => "Параграф" "field_creative_case" => "Параграфом" "field_dative_case" => "Параграфу" "field_genitive_case" => "Параграфа" "field_nominative_case" => "Параграф" "field_prepositional_case" => "Параграфе" ] "field_page_check_not_needed" => null "field_short_name" => "§" ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "field_page_start" => "219" "field_branch_display" => "0" "field_branch_expanded" => "0" "field_display_branch_in_title" => "1" "field_display_task_interval" => "0" "field_display_branch_page" => "1" "field_branch_title_in_content" => "0" "field_navigation_title" => null "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "field_branch_cover" => [] "field_branch_covers" => [] "book" => Illuminate\Database\Eloquent\Collection {#1073 #items: array:1 [ 0 => App\Models\Book {#1032} ] #escapeWhenCastingToString: false } "branch_parent" => Illuminate\Database\Eloquent\Collection {#1074 #items: array:1 [ 0 => App\Models\Branch {#1075 #connection: "mysql" #table: "branches" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:24 [ "id" => 662723 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_display_title" => "Углеводороды" "field_branch_order" => "3" "field_url" => null "field_branch_type" => Illuminate\Database\Eloquent\Collection {#1076 #items: array:1 [ …1] #escapeWhenCastingToString: false } "field_page_start" => "139" "field_branch_display" => "0" "field_branch_expanded" => "0" "field_display_branch_in_title" => "1" "field_display_task_interval" => "0" "field_display_branch_page" => "1" "field_branch_title_in_content" => "0" "field_navigation_title" => null "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "field_branch_cover" => [] "field_branch_covers" => [] "book" => Illuminate\Database\Eloquent\Collection {#1078 #items: array:1 [ …1] #escapeWhenCastingToString: false } "branch_parent" => Illuminate\Database\Eloquent\Collection {#1114 #items: [] #escapeWhenCastingToString: false } ] #original: array:24 [ "id" => 662723 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_display_title" => "Углеводороды" "field_branch_order" => "3" "field_url" => null "field_branch_type" => Illuminate\Database\Eloquent\Collection {#1076} "field_page_start" => "139" "field_branch_display" => "0" "field_branch_expanded" => "0" "field_display_branch_in_title" => "1" "field_display_task_interval" => "0" "field_display_branch_page" => "1" "field_branch_title_in_content" => "0" "field_navigation_title" => null "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "field_branch_cover" => [] "field_branch_covers" => [] "book" => Illuminate\Database\Eloquent\Collection {#1078} "branch_parent" => Illuminate\Database\Eloquent\Collection {#1114} ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } ] #original: array:24 [ "id" => 662742 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_display_title" => "Галогенопроизводные углеводородов" "field_branch_order" => "42" "field_url" => null "field_branch_type" => Illuminate\Database\Eloquent\Collection {#1071} "field_page_start" => "219" "field_branch_display" => "0" "field_branch_expanded" => "0" "field_display_branch_in_title" => "1" "field_display_task_interval" => "0" "field_display_branch_page" => "1" "field_branch_title_in_content" => "0" "field_navigation_title" => null "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "field_branch_cover" => [] "field_branch_covers" => [] "book" => Illuminate\Database\Eloquent\Collection {#1073} "branch_parent" => Illuminate\Database\Eloquent\Collection {#1074} ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "content" => Illuminate\Database\Eloquent\Collection {#1115 #items: array:3 [ 0 => App\Models\Element {#1116 #connection: "mysql" #table: "elements" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:7 [ "id" => 818898 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "edition" => Illuminate\Database\Eloquent\Collection {#1117 #items: array:1 [ 0 => App\Models\Edition {#1118 #connection: "mysql" #table: "editions" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:21 [ "id" => 1829 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "title" => "Условие" "field_order" => "1" "field_publisher" => Illuminate\Database\Eloquent\Collection {#1119 #items: array:1 [ …1] #escapeWhenCastingToString: false } "field_content_type" => "free" "field_content_mode" => "text, image" "field_page_content_mode" => "image" "field_content_text_checked" => null "field_page_content_text_checked" => "0" "field_solution_author" => "Автор" "field_moderator" => "vadim" "field_edition_type" => "statement" "field_root_dir" => "0-" "field_responsible" => Illuminate\Database\Eloquent\Collection {#1121 #items: [] #escapeWhenCastingToString: false } "field_comment" => null "field_similar_book" => Illuminate\Database\Eloquent\Collection {#1122 #items: [] #escapeWhenCastingToString: false } "field_process_formula" => "katex" "field_edition_group" => Illuminate\Database\Eloquent\Collection {#1123 #items: [] #escapeWhenCastingToString: false } "field_content_source" => null ] #original: array:21 [ "id" => 1829 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "title" => "Условие" "field_order" => "1" "field_publisher" => Illuminate\Database\Eloquent\Collection {#1119} "field_content_type" => "free" "field_content_mode" => "text, image" "field_page_content_mode" => "image" "field_content_text_checked" => null "field_page_content_text_checked" => "0" "field_solution_author" => "Автор" "field_moderator" => "vadim" "field_edition_type" => "statement" "field_root_dir" => "0-" "field_responsible" => Illuminate\Database\Eloquent\Collection {#1121} "field_comment" => null "field_similar_book" => Illuminate\Database\Eloquent\Collection {#1122} "field_process_formula" => "katex" "field_edition_group" => Illuminate\Database\Eloquent\Collection {#1123} "field_content_source" => null ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "task" => array:2 [ "refs" => "663192" "type" => "task" ] "text" => "<p><strong>3.</strong> Напишите уравнения реакций бромэтана с цианидом калия, нитритом серебра, аммиаком, водным и спиртовым растворами гидроксида калия, металлическим натрием, магнием в эфире.</p>" "img" => array:1 [ 0 => array:5 [ "name" => "3-1.jpg" "alt" => null "width" => "853" "height" => 139 "path" => "/media/himiya_10/eremin-u23/0-42/3-1.webp?ts=1738779615" ] ] ] #original: array:7 [ "id" => 818898 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "edition" => Illuminate\Database\Eloquent\Collection {#1117} "task" => array:2 [ "refs" => "663192" "type" => "task" ] "text" => "<p><strong>3.</strong> Напишите уравнения реакций бромэтана с цианидом калия, нитритом серебра, аммиаком, водным и спиртовым растворами гидроксида калия, металлическим натрием, магнием в эфире.</p>" "img" => array:1 [ 0 => array:5 [ "name" => "3-1.jpg" "alt" => null "width" => "853" "height" => 139 "path" => "/media/himiya_10/eremin-u23/0-42/3-1.webp?ts=1738779615" ] ] ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } 1 => App\Models\Element {#1124 #connection: "mysql" #table: "elements" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:6 [ "id" => 819140 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "edition" => Illuminate\Database\Eloquent\Collection {#1125 #items: array:1 [ 0 => App\Models\Edition {#1126 #connection: "mysql" #table: "editions" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:21 [ "id" => 1830 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "title" => "Решение" "field_order" => "2" "field_publisher" => Illuminate\Database\Eloquent\Collection {#1127 #items: array:1 [ …1] #escapeWhenCastingToString: false } "field_content_type" => "free" "field_content_mode" => "image" "field_page_content_mode" => "" "field_content_text_checked" => "0" "field_page_content_text_checked" => "0" "field_solution_author" => "Ладыко (Торчило)" "field_moderator" => "vadim" "field_edition_type" => "solution" "field_root_dir" => "1-" "field_responsible" => Illuminate\Database\Eloquent\Collection {#1129 #items: [] #escapeWhenCastingToString: false } "field_comment" => null "field_similar_book" => Illuminate\Database\Eloquent\Collection {#1130 #items: [] #escapeWhenCastingToString: false } "field_process_formula" => "" "field_edition_group" => Illuminate\Database\Eloquent\Collection {#1131 #items: [] #escapeWhenCastingToString: false } "field_content_source" => null ] #original: array:21 [ "id" => 1830 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "title" => "Решение" "field_order" => "2" "field_publisher" => Illuminate\Database\Eloquent\Collection {#1127} "field_content_type" => "free" "field_content_mode" => "image" "field_page_content_mode" => "" "field_content_text_checked" => "0" "field_page_content_text_checked" => "0" "field_solution_author" => "Ладыко (Торчило)" "field_moderator" => "vadim" "field_edition_type" => "solution" "field_root_dir" => "1-" "field_responsible" => Illuminate\Database\Eloquent\Collection {#1129} "field_comment" => null "field_similar_book" => Illuminate\Database\Eloquent\Collection {#1130} "field_process_formula" => "" "field_edition_group" => Illuminate\Database\Eloquent\Collection {#1131} "field_content_source" => null ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "task" => array:2 [ "refs" => "663192" "type" => "task" ] "img" => array:1 [ 0 => array:5 [ "name" => "3-1.jpg" "alt" => null "width" => "1915" "height" => 801 "path" => "/media/himiya_10/eremin-u23/1-42/3-1.webp?ts=1738779689" ] ] ] #original: array:6 [ "id" => 819140 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "edition" => Illuminate\Database\Eloquent\Collection {#1125} "task" => array:2 [ "refs" => "663192" "type" => "task" ] "img" => array:1 [ 0 => array:5 [ "name" => "3-1.jpg" "alt" => null "width" => "1915" "height" => 801 "path" => "/media/himiya_10/eremin-u23/1-42/3-1.webp?ts=1738779689" ] ] ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } 2 => App\Models\Element {#1132 #connection: "mysql" #table: "elements" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:6 [ "id" => 1515596 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "edition" => Illuminate\Database\Eloquent\Collection {#1133 #items: array:1 [ 0 => App\Models\Edition {#1134 #connection: "mysql" #table: "editions" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:21 [ "id" => 5553 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "title" => "Решение 2" "field_order" => "3" "field_publisher" => Illuminate\Database\Eloquent\Collection {#1135 #items: array:1 [ …1] #escapeWhenCastingToString: false } "field_content_type" => "free" "field_content_mode" => "text" "field_page_content_mode" => "" "field_content_text_checked" => null "field_page_content_text_checked" => "0" "field_solution_author" => "Gemini 2.5 Pro" "field_moderator" => "tolik" "field_edition_type" => "solution" "field_root_dir" => "2-" "field_responsible" => Illuminate\Database\Eloquent\Collection {#1137 #items: [] #escapeWhenCastingToString: false } "field_comment" => null "field_similar_book" => Illuminate\Database\Eloquent\Collection {#1138 #items: [] #escapeWhenCastingToString: false } "field_process_formula" => "katex" "field_edition_group" => Illuminate\Database\Eloquent\Collection {#1139 #items: [] #escapeWhenCastingToString: false } "field_content_source" => null ] #original: array:21 [ "id" => 5553 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "title" => "Решение 2" "field_order" => "3" "field_publisher" => Illuminate\Database\Eloquent\Collection {#1135} "field_content_type" => "free" "field_content_mode" => "text" "field_page_content_mode" => "" "field_content_text_checked" => null "field_page_content_text_checked" => "0" "field_solution_author" => "Gemini 2.5 Pro" "field_moderator" => "tolik" "field_edition_type" => "solution" "field_root_dir" => "2-" "field_responsible" => Illuminate\Database\Eloquent\Collection {#1137} "field_comment" => null "field_similar_book" => Illuminate\Database\Eloquent\Collection {#1138} "field_process_formula" => "katex" "field_edition_group" => Illuminate\Database\Eloquent\Collection {#1139} "field_content_source" => null ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "task" => array:2 [ "refs" => "663192" "type" => "task" ] "text" => "<p>Бромэтан ($CH_3CH_2Br$) — это галогеналкан, для которого характерны реакции нуклеофильного замещения ($S_N$), элиминирования ($E$), а также реакции с металлами. Ниже приведены уравнения реакций бромэтана с указанными реагентами.</p><p><strong>с цианидом калия</strong></p><p>Взаимодействие бромэтана с цианидом калия ($KCN$) представляет собой реакцию нуклеофильного замещения. Цианид-ион ($CN^−$), являясь сильным нуклеофилом, замещает атом брома. Эта реакция приводит к удлинению углеродной цепи на один атом.</p><p>Уравнение реакции:</p><p>$CH_3CH_2Br + KCN \rightarrow CH_3CH_2CN + KBr$</p><p>Основными продуктами являются пропаннитрил (или этилцианид) и бромид калия.</p><p><strong>Ответ:</strong> $CH_3CH_2Br + KCN \rightarrow CH_3CH_2CN + KBr$</p><p><strong>с нитритом серебра</strong></p><p>Реакция с нитритом серебра ($AgNO_2$) также является нуклеофильным замещением. Нитрит-ион ($NO_2^−$) — амбидентный нуклеофил, он может реагировать через атом азота или кислорода. Из-за преимущественно ковалентного характера связи $Ag-O$ в $AgNO_2$ атака происходит неподеленной электронной парой атома азота, что ведёт к образованию нитросоединения (реакция Мейера).</p><p>Уравнение реакции:</p><p>$CH_3CH_2Br + AgNO_2 \rightarrow CH_3CH_2NO_2 + AgBr\downarrow$</p><p>В результате образуется нитроэтан и выпадает осадок бромида серебра. При использовании нитритов щелочных металлов (например, $KNO_2$) основным продуктом был бы алкилнитрит ($CH_3CH_2ONO$).</p><p><strong>Ответ:</strong> $CH_3CH_2Br + AgNO_2 \rightarrow CH_3CH_2NO_2 + AgBr$</p><p><strong>с аммиаком</strong></p><p>Реакция бромэтана с избытком аммиака ($NH_3$) — это реакция алкилирования по Гофману, приводящая к образованию первичного амина. Молекула аммиака выступает в роли нуклеофила. Избыток аммиака необходим для нейтрализации образующегося бромоводорода и предотвращения дальнейшего алкилирования амина.</p><p>Уравнение реакции:</p><p>$CH_3CH_2Br + 2NH_3 \rightarrow CH_3CH_2NH_2 + NH_4Br$</p><p>Продуктами реакции являются этиламин и бромид аммония.</p><p><strong>Ответ:</strong> $CH_3CH_2Br + 2NH_3 \rightarrow CH_3CH_2NH_2 + NH_4Br$</p><p><strong>с водным раствором гидроксида калия</strong></p><p>В водном растворе гидроксид калия ($KOH$) диссоциирует с образованием гидратированных гидроксид-ионов ($OH^−$), которые являются сильными нуклеофилами, но слабыми основаниями. Поэтому преимущественно протекает реакция нуклеофильного замещения (щелочной гидролиз) с образованием спирта.</p><p>Уравнение реакции:</p><p>$CH_3CH_2Br + KOH_{(водн.)} \rightarrow CH_3CH_2OH + KBr$</p><p>В результате реакции образуется этанол и бромид калия.</p><p><strong>Ответ:</strong> $CH_3CH_2Br + KOH_{(водн.)} \rightarrow CH_3CH_2OH + KBr$</p><p><strong>со спиртовым раствором гидроксида калия</strong></p><p>В спиртовом растворе основность гидроксид-иона (а точнее, образующегося в равновесии алкоксид-иона) значительно выше, чем в водном. Поэтому в этих условиях преобладает реакция отщепления (элиминирования, или дегидрогалогенирования). Отщепляется атом водорода от соседнего (β) атома углерода и атом галогена, что приводит к образованию двойной связи.</p><p>Уравнение реакции:</p><p>$CH_3CH_2Br + KOH_{(спирт.)} \xrightarrow{t} CH_2=CH_2\uparrow + KBr + H_2O$</p><p>Основными продуктами являются этен (газ), бромид калия и вода.</p><p><strong>Ответ:</strong> $CH_3CH_2Br + KOH_{(спирт.)} \rightarrow CH_2=CH_2 + KBr + H_2O$</p><p><strong>с металлическим натрием</strong></p><p>Реакция с металлическим натрием ($Na$) — это классический синтез Вюрца. В ходе реакции происходит удвоение углеродного скелета исходного галогеналкана с образованием симметричного алкана.</p><p>Уравнение реакции:</p><p>$2CH_3CH_2Br + 2Na \rightarrow CH_3CH_2CH_2CH_3 + 2NaBr$</p><p>Продукты реакции — н-бутан и бромид натрия.</p><p><strong>Ответ:</strong> $2CH_3CH_2Br + 2Na \rightarrow CH_3CH_2CH_2CH_3 + 2NaBr$</p><p><strong>с магнием в эфире</strong></p><p>Взаимодействие с металлическим магнием ($Mg$) в среде безводного (абсолютного) диэтилового эфира приводит к образованию металлоорганического соединения — реактива Гриньяра. Эфир необходим для стабилизации образующегося реактива.</p><p>Уравнение реакции:</p><p>$CH_3CH_2Br + Mg \xrightarrow{эфир} CH_3CH_2MgBr$</p><p>Образуется этилмагнийбромид, который является важным реагентом для создания новых углерод-углеродных связей в органическом синтезе.</p><p><strong>Ответ:</strong> $CH_3CH_2Br + Mg \xrightarrow{эфир} CH_3CH_2MgBr$</p>" ] #original: array:6 [ "id" => 1515596 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "edition" => Illuminate\Database\Eloquent\Collection {#1133} "task" => array:2 [ "refs" => "663192" "type" => "task" ] "text" => "<p>Бромэтан ($CH_3CH_2Br$) — это галогеналкан, для которого характерны реакции нуклеофильного замещения ($S_N$), элиминирования ($E$), а также реакции с металлами. Ниже приведены уравнения реакций бромэтана с указанными реагентами.</p><p><strong>с цианидом калия</strong></p><p>Взаимодействие бромэтана с цианидом калия ($KCN$) представляет собой реакцию нуклеофильного замещения. Цианид-ион ($CN^−$), являясь сильным нуклеофилом, замещает атом брома. Эта реакция приводит к удлинению углеродной цепи на один атом.</p><p>Уравнение реакции:</p><p>$CH_3CH_2Br + KCN \rightarrow CH_3CH_2CN + KBr$</p><p>Основными продуктами являются пропаннитрил (или этилцианид) и бромид калия.</p><p><strong>Ответ:</strong> $CH_3CH_2Br + KCN \rightarrow CH_3CH_2CN + KBr$</p><p><strong>с нитритом серебра</strong></p><p>Реакция с нитритом серебра ($AgNO_2$) также является нуклеофильным замещением. Нитрит-ион ($NO_2^−$) — амбидентный нуклеофил, он может реагировать через атом азота или кислорода. Из-за преимущественно ковалентного характера связи $Ag-O$ в $AgNO_2$ атака происходит неподеленной электронной парой атома азота, что ведёт к образованию нитросоединения (реакция Мейера).</p><p>Уравнение реакции:</p><p>$CH_3CH_2Br + AgNO_2 \rightarrow CH_3CH_2NO_2 + AgBr\downarrow$</p><p>В результате образуется нитроэтан и выпадает осадок бромида серебра. При использовании нитритов щелочных металлов (например, $KNO_2$) основным продуктом был бы алкилнитрит ($CH_3CH_2ONO$).</p><p><strong>Ответ:</strong> $CH_3CH_2Br + AgNO_2 \rightarrow CH_3CH_2NO_2 + AgBr$</p><p><strong>с аммиаком</strong></p><p>Реакция бромэтана с избытком аммиака ($NH_3$) — это реакция алкилирования по Гофману, приводящая к образованию первичного амина. Молекула аммиака выступает в роли нуклеофила. Избыток аммиака необходим для нейтрализации образующегося бромоводорода и предотвращения дальнейшего алкилирования амина.</p><p>Уравнение реакции:</p><p>$CH_3CH_2Br + 2NH_3 \rightarrow CH_3CH_2NH_2 + NH_4Br$</p><p>Продуктами реакции являются этиламин и бромид аммония.</p><p><strong>Ответ:</strong> $CH_3CH_2Br + 2NH_3 \rightarrow CH_3CH_2NH_2 + NH_4Br$</p><p><strong>с водным раствором гидроксида калия</strong></p><p>В водном растворе гидроксид калия ($KOH$) диссоциирует с образованием гидратированных гидроксид-ионов ($OH^−$), которые являются сильными нуклеофилами, но слабыми основаниями. Поэтому преимущественно протекает реакция нуклеофильного замещения (щелочной гидролиз) с образованием спирта.</p><p>Уравнение реакции:</p><p>$CH_3CH_2Br + KOH_{(водн.)} \rightarrow CH_3CH_2OH + KBr$</p><p>В результате реакции образуется этанол и бромид калия.</p><p><strong>Ответ:</strong> $CH_3CH_2Br + KOH_{(водн.)} \rightarrow CH_3CH_2OH + KBr$</p><p><strong>со спиртовым раствором гидроксида калия</strong></p><p>В спиртовом растворе основность гидроксид-иона (а точнее, образующегося в равновесии алкоксид-иона) значительно выше, чем в водном. Поэтому в этих условиях преобладает реакция отщепления (элиминирования, или дегидрогалогенирования). Отщепляется атом водорода от соседнего (β) атома углерода и атом галогена, что приводит к образованию двойной связи.</p><p>Уравнение реакции:</p><p>$CH_3CH_2Br + KOH_{(спирт.)} \xrightarrow{t} CH_2=CH_2\uparrow + KBr + H_2O$</p><p>Основными продуктами являются этен (газ), бромид калия и вода.</p><p><strong>Ответ:</strong> $CH_3CH_2Br + KOH_{(спирт.)} \rightarrow CH_2=CH_2 + KBr + H_2O$</p><p><strong>с металлическим натрием</strong></p><p>Реакция с металлическим натрием ($Na$) — это классический синтез Вюрца. В ходе реакции происходит удвоение углеродного скелета исходного галогеналкана с образованием симметричного алкана.</p><p>Уравнение реакции:</p><p>$2CH_3CH_2Br + 2Na \rightarrow CH_3CH_2CH_2CH_3 + 2NaBr$</p><p>Продукты реакции — н-бутан и бромид натрия.</p><p><strong>Ответ:</strong> $2CH_3CH_2Br + 2Na \rightarrow CH_3CH_2CH_2CH_3 + 2NaBr$</p><p><strong>с магнием в эфире</strong></p><p>Взаимодействие с металлическим магнием ($Mg$) в среде безводного (абсолютного) диэтилового эфира приводит к образованию металлоорганического соединения — реактива Гриньяра. Эфир необходим для стабилизации образующегося реактива.</p><p>Уравнение реакции:</p><p>$CH_3CH_2Br + Mg \xrightarrow{эфир} CH_3CH_2MgBr$</p><p>Образуется этилмагнийбромид, который является важным реагентом для создания новых углерод-углеродных связей в органическом синтезе.</p><p><strong>Ответ:</strong> $CH_3CH_2Br + Mg \xrightarrow{эфир} CH_3CH_2MgBr$</p>" ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "next" => array:2 [ "refs" => "663193" "type" => "task" ] "previous" => array:2 [ "refs" => "663191" "type" => "task" ] "book" => Illuminate\Database\Eloquent\Collection {#1140 #items: array:1 [ 0 => App\Models\Book {#1032} ] #escapeWhenCastingToString: false } "page" => Illuminate\Database\Eloquent\Collection {#1155 #items: array:1 [ 0 => App\Models\BookPage {#1154 #connection: "mysql" #table: "book_pages" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:21 [ "id" => 926121 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_page_start" => "225" "field_url" => "/10-klass/himiya/eremin-uchebnik/page-225" "field_display_title" => "225" "field_folder" => "1" "field_image_name" => "225" "field_branch_parent" => Illuminate\Database\Eloquent\Collection {#1156 #items: [] #escapeWhenCastingToString: false } "field_weight" => "0" "field_book_parent" => Illuminate\Database\Eloquent\Collection {#1194 #items: array:1 [ 0 => App\Models\Book {#1157 #connection: "mysql" #table: "books" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:50 [ "id" => 1003 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_tree_default_status" => "tasks" "field_pages_status" => null "field_subject" => Illuminate\Database\Eloquent\Collection {#1159 …2} "field_class" => Illuminate\Database\Eloquent\Collection {#1160 …2} "field_publisher" => Illuminate\Database\Eloquent\Collection {#1162 …2} "field_author" => Illuminate\Database\Eloquent\Collection {#1164 …2} "field_author_foreign" => Illuminate\Database\Eloquent\Collection {#1170 …2} "field_book_type" => Illuminate\Database\Eloquent\Collection {#1171 …2} "field_country" => Illuminate\Database\Eloquent\Collection {#1173 …2} "field_city" => Illuminate\Database\Eloquent\Collection {#1175 …2} "field_series" => Illuminate\Database\Eloquent\Collection {#1177 …2} "field_umk" => Illuminate\Database\Eloquent\Collection {#1178 …2} "field_level_of_education" => Illuminate\Database\Eloquent\Collection {#1179 …2} "field_standart_of_education" => Illuminate\Database\Eloquent\Collection {#1181 …2} "field_publication_number" => "10" "field_publication_type" => Illuminate\Database\Eloquent\Collection {#1183 …2} "field_under_the_edition" => Illuminate\Database\Eloquent\Collection {#1185 …2} "field_under_the_edition_degree" => "доктор химических наук, академика РАН" "field_cover_description" => "с радугой" "field_publication_year" => "2023" "field_publication_year_until" => null "field_part" => "" "field_part_writing" => "" "field_second_foreign_language" => null "field_for_whom" => null "field_allowed" => "Допущено Министерством просвещения Российской Федерации" "field_reserve_field" => null "field_link_to_source" => null "field_tasks_count" => "697" "field_priority" => "10" "field_default_folder" => "/himiya_10/eremin-u23/" "field_isbn" => null "field_cover" => array:1 [ …1] "field_cover_alts" => array:1 [ …1] "field_covers" => array:1 [ …1] "field_popular_book" => null "field_recommended_books" => Illuminate\Database\Eloquent\Collection {#1186 …2} "field_new_book" => Illuminate\Database\Eloquent\Collection {#1187 …2} "field_old_book" => Illuminate\Database\Eloquent\Collection {#1188 …2} "field_url" => "/10-klass/himiya/eremin-uchebnik" "field_cover_color" => Illuminate\Database\Eloquent\Collection {#1189 …2} "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "breadcrumbs" => array:3 [ …3] ] #original: array:50 [ "id" => 1003 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_tree_default_status" => "tasks" "field_pages_status" => null "field_subject" => Illuminate\Database\Eloquent\Collection {#1159 …2} "field_class" => Illuminate\Database\Eloquent\Collection {#1160 …2} "field_publisher" => Illuminate\Database\Eloquent\Collection {#1162 …2} "field_author" => Illuminate\Database\Eloquent\Collection {#1164 …2} "field_author_foreign" => Illuminate\Database\Eloquent\Collection {#1170 …2} "field_book_type" => Illuminate\Database\Eloquent\Collection {#1171 …2} "field_country" => Illuminate\Database\Eloquent\Collection {#1173 …2} "field_city" => Illuminate\Database\Eloquent\Collection {#1175 …2} "field_series" => Illuminate\Database\Eloquent\Collection {#1177 …2} "field_umk" => Illuminate\Database\Eloquent\Collection {#1178 …2} "field_level_of_education" => Illuminate\Database\Eloquent\Collection {#1179 …2} "field_standart_of_education" => Illuminate\Database\Eloquent\Collection {#1181 …2} "field_publication_number" => "10" "field_publication_type" => Illuminate\Database\Eloquent\Collection {#1183 …2} "field_under_the_edition" => Illuminate\Database\Eloquent\Collection {#1185 …2} "field_under_the_edition_degree" => "доктор химических наук, академика РАН" "field_cover_description" => "с радугой" "field_publication_year" => "2023" "field_publication_year_until" => null "field_part" => "" "field_part_writing" => "" "field_second_foreign_language" => null "field_for_whom" => null "field_allowed" => "Допущено Министерством просвещения Российской Федерации" "field_reserve_field" => null "field_link_to_source" => null "field_tasks_count" => "697" "field_priority" => "10" "field_default_folder" => "/himiya_10/eremin-u23/" "field_isbn" => null "field_cover" => array:1 [ …1] "field_cover_alts" => array:1 [ …1] "field_covers" => array:1 [ …1] "field_popular_book" => null "field_recommended_books" => Illuminate\Database\Eloquent\Collection {#1186 …2} "field_new_book" => Illuminate\Database\Eloquent\Collection {#1187 …2} "field_old_book" => Illuminate\Database\Eloquent\Collection {#1188 …2} "field_url" => "/10-klass/himiya/eremin-uchebnik" "field_cover_color" => Illuminate\Database\Eloquent\Collection {#1189 …2} "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "breadcrumbs" => array:3 [ …3] ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "edition_groups" => Illuminate\Database\Eloquent\Collection {#1192 #items: [] #escapeWhenCastingToString: false } "content" => Illuminate\Database\Eloquent\Collection {#1203 #items: array:1 [ 0 => App\Models\Element {#1202 #connection: "mysql" #table: "elements" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:6 [ "id" => 1100615 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "edition" => Illuminate\Database\Eloquent\Collection {#1212 …2} "book_page" => array:2 [ …2] "img" => array:1 [ …1] ] #original: array:6 [ "id" => 1100615 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "edition" => Illuminate\Database\Eloquent\Collection {#1212 …2} "book_page" => array:2 [ …2] "img" => array:1 [ …1] ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "next" => array:2 [ "refs" => "926122" "type" => "book_page" ] "previous" => array:2 [ "refs" => "926120" "type" => "book_page" ] "tasks" => Illuminate\Database\Eloquent\Collection {#1556 #items: array:3 [ 0 => App\Models\Task {#1195 #connection: "mysql" #table: "tasks" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:24 [ "id" => 663190 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_page_start" => "225" "field_page_end" => null "field_url" => "/10-klass/himiya/eremin-uchebnik/42-1" "field_display_title" => "1" "field_outside_task" => null "field_task_type" => Illuminate\Database\Eloquent\Collection {#1193 …2} "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "field_match" => null "breadcrumbs" => [] "edition_groups" => Illuminate\Database\Eloquent\Collection {#1199 …2} "top_parent_branch" => Illuminate\Database\Eloquent\Collection {#1197 …2} "parent_branches" => Illuminate\Database\Eloquent\Collection {#1249 …2} "content" => Illuminate\Database\Eloquent\Collection {#1295 …2} "next" => array:2 [ …2] "previous" => array:2 [ …2] "book" => Illuminate\Database\Eloquent\Collection {#1320 …2} "page" => array:2 [ …2] ] #original: array:24 [ "id" => 663190 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_page_start" => "225" "field_page_end" => null "field_url" => "/10-klass/himiya/eremin-uchebnik/42-1" "field_display_title" => "1" "field_outside_task" => null "field_task_type" => Illuminate\Database\Eloquent\Collection {#1193 …2} "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "field_match" => null "breadcrumbs" => [] "edition_groups" => Illuminate\Database\Eloquent\Collection {#1199 …2} "top_parent_branch" => Illuminate\Database\Eloquent\Collection {#1197 …2} "parent_branches" => Illuminate\Database\Eloquent\Collection {#1249 …2} "content" => Illuminate\Database\Eloquent\Collection {#1295 …2} "next" => array:2 [ …2] "previous" => array:2 [ …2] "book" => Illuminate\Database\Eloquent\Collection {#1320 …2} "page" => array:2 [ …2] ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } 1 => App\Models\Task {#1321 #connection: "mysql" #table: "tasks" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:24 [ "id" => 663191 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_page_start" => "225" "field_page_end" => null "field_url" => "/10-klass/himiya/eremin-uchebnik/42-2" "field_display_title" => "2" "field_outside_task" => null "field_task_type" => Illuminate\Database\Eloquent\Collection {#1322 …2} "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "field_match" => null "breadcrumbs" => [] "edition_groups" => Illuminate\Database\Eloquent\Collection {#1324 …2} "top_parent_branch" => Illuminate\Database\Eloquent\Collection {#1325 …2} "parent_branches" => Illuminate\Database\Eloquent\Collection {#1366 …2} "content" => Illuminate\Database\Eloquent\Collection {#1412 …2} "next" => array:2 [ …2] "previous" => array:2 [ …2] "book" => Illuminate\Database\Eloquent\Collection {#1437 …2} "page" => array:2 [ …2] ] #original: array:24 [ "id" => 663191 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_page_start" => "225" "field_page_end" => null "field_url" => "/10-klass/himiya/eremin-uchebnik/42-2" "field_display_title" => "2" "field_outside_task" => null "field_task_type" => Illuminate\Database\Eloquent\Collection {#1322 …2} "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "field_match" => null "breadcrumbs" => [] "edition_groups" => Illuminate\Database\Eloquent\Collection {#1324 …2} "top_parent_branch" => Illuminate\Database\Eloquent\Collection {#1325 …2} "parent_branches" => Illuminate\Database\Eloquent\Collection {#1366 …2} "content" => Illuminate\Database\Eloquent\Collection {#1412 …2} "next" => array:2 [ …2] "previous" => array:2 [ …2] "book" => Illuminate\Database\Eloquent\Collection {#1437 …2} "page" => array:2 [ …2] ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } 2 => App\Models\Task {#1438 #connection: "mysql" #table: "tasks" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:24 [ "id" => 663192 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_page_start" => "225" "field_page_end" => null "field_url" => "/10-klass/himiya/eremin-uchebnik/42-3" "field_display_title" => "3" "field_outside_task" => null "field_task_type" => Illuminate\Database\Eloquent\Collection {#1439 …2} "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "field_match" => null "breadcrumbs" => [] "edition_groups" => Illuminate\Database\Eloquent\Collection {#1441 …2} "top_parent_branch" => Illuminate\Database\Eloquent\Collection {#1442 …2} "parent_branches" => Illuminate\Database\Eloquent\Collection {#1483 …2} "content" => Illuminate\Database\Eloquent\Collection {#1529 …2} "next" => array:2 [ …2] "previous" => array:2 [ …2] "book" => Illuminate\Database\Eloquent\Collection {#1554 …2} "page" => array:2 [ …2] ] #original: array:24 [ "id" => 663192 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_page_start" => "225" "field_page_end" => null "field_url" => "/10-klass/himiya/eremin-uchebnik/42-3" "field_display_title" => "3" "field_outside_task" => null "field_task_type" => Illuminate\Database\Eloquent\Collection {#1439 …2} "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "field_match" => null "breadcrumbs" => [] "edition_groups" => Illuminate\Database\Eloquent\Collection {#1441 …2} "top_parent_branch" => Illuminate\Database\Eloquent\Collection {#1442 …2} "parent_branches" => Illuminate\Database\Eloquent\Collection {#1483 …2} "content" => Illuminate\Database\Eloquent\Collection {#1529 …2} "next" => array:2 [ …2] "previous" => array:2 [ …2] "book" => Illuminate\Database\Eloquent\Collection {#1554 …2} "page" => array:2 [ …2] ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } ] #original: array:21 [ "id" => 926121 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_page_start" => "225" "field_url" => "/10-klass/himiya/eremin-uchebnik/page-225" "field_display_title" => "225" "field_folder" => "1" "field_image_name" => "225" "field_branch_parent" => Illuminate\Database\Eloquent\Collection {#1156} "field_weight" => "0" "field_book_parent" => Illuminate\Database\Eloquent\Collection {#1194} "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "edition_groups" => Illuminate\Database\Eloquent\Collection {#1192} "content" => Illuminate\Database\Eloquent\Collection {#1203} "next" => array:2 [ "refs" => "926122" "type" => "book_page" ] "previous" => array:2 [ "refs" => "926120" "type" => "book_page" ] "tasks" => Illuminate\Database\Eloquent\Collection {#1556} ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } ] #original: array:24 [ "id" => 663192 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_page_start" => "225" "field_page_end" => null "field_url" => "/10-klass/himiya/eremin-uchebnik/42-3" "field_display_title" => "3" "field_outside_task" => null "field_task_type" => Illuminate\Database\Eloquent\Collection {#331} "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "field_match" => null "breadcrumbs" => [] "edition_groups" => Illuminate\Database\Eloquent\Collection {#1026} "top_parent_branch" => Illuminate\Database\Eloquent\Collection {#342} "parent_branches" => Illuminate\Database\Eloquent\Collection {#1069} "content" => Illuminate\Database\Eloquent\Collection {#1115} "next" => array:2 [ "refs" => "663193" "type" => "task" ] "previous" => array:2 [ "refs" => "663191" "type" => "task" ] "book" => Illuminate\Database\Eloquent\Collection {#1140} "page" => array:2 [ "refs" => "926121" "type" => "book_page" ] ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] }
№3 (с. 225)
Условие. №3 (с. 225)
скриншот условия
3. Напишите уравнения реакций бромэтана с цианидом калия, нитритом серебра, аммиаком, водным и спиртовым растворами гидроксида калия, металлическим натрием, магнием в эфире.
Решение. №3 (с. 225)
Решение 2. №3 (с. 225)
Бромэтан ($CH_3CH_2Br$) — это галогеналкан, для которого характерны реакции нуклеофильного замещения ($S_N$), элиминирования ($E$), а также реакции с металлами. Ниже приведены уравнения реакций бромэтана с указанными реагентами.
с цианидом калия
Взаимодействие бромэтана с цианидом калия ($KCN$) представляет собой реакцию нуклеофильного замещения. Цианид-ион ($CN^−$), являясь сильным нуклеофилом, замещает атом брома. Эта реакция приводит к удлинению углеродной цепи на один атом.
Уравнение реакции:
$CH_3CH_2Br + KCN \rightarrow CH_3CH_2CN + KBr$
Основными продуктами являются пропаннитрил (или этилцианид) и бромид калия.
Ответ: $CH_3CH_2Br + KCN \rightarrow CH_3CH_2CN + KBr$
с нитритом серебра
Реакция с нитритом серебра ($AgNO_2$) также является нуклеофильным замещением. Нитрит-ион ($NO_2^−$) — амбидентный нуклеофил, он может реагировать через атом азота или кислорода. Из-за преимущественно ковалентного характера связи $Ag-O$ в $AgNO_2$ атака происходит неподеленной электронной парой атома азота, что ведёт к образованию нитросоединения (реакция Мейера).
Уравнение реакции:
$CH_3CH_2Br + AgNO_2 \rightarrow CH_3CH_2NO_2 + AgBr\downarrow$
В результате образуется нитроэтан и выпадает осадок бромида серебра. При использовании нитритов щелочных металлов (например, $KNO_2$) основным продуктом был бы алкилнитрит ($CH_3CH_2ONO$).
Ответ: $CH_3CH_2Br + AgNO_2 \rightarrow CH_3CH_2NO_2 + AgBr$
с аммиаком
Реакция бромэтана с избытком аммиака ($NH_3$) — это реакция алкилирования по Гофману, приводящая к образованию первичного амина. Молекула аммиака выступает в роли нуклеофила. Избыток аммиака необходим для нейтрализации образующегося бромоводорода и предотвращения дальнейшего алкилирования амина.
Уравнение реакции:
$CH_3CH_2Br + 2NH_3 \rightarrow CH_3CH_2NH_2 + NH_4Br$
Продуктами реакции являются этиламин и бромид аммония.
Ответ: $CH_3CH_2Br + 2NH_3 \rightarrow CH_3CH_2NH_2 + NH_4Br$
с водным раствором гидроксида калия
В водном растворе гидроксид калия ($KOH$) диссоциирует с образованием гидратированных гидроксид-ионов ($OH^−$), которые являются сильными нуклеофилами, но слабыми основаниями. Поэтому преимущественно протекает реакция нуклеофильного замещения (щелочной гидролиз) с образованием спирта.
Уравнение реакции:
$CH_3CH_2Br + KOH_{(водн.)} \rightarrow CH_3CH_2OH + KBr$
В результате реакции образуется этанол и бромид калия.
Ответ: $CH_3CH_2Br + KOH_{(водн.)} \rightarrow CH_3CH_2OH + KBr$
со спиртовым раствором гидроксида калия
В спиртовом растворе основность гидроксид-иона (а точнее, образующегося в равновесии алкоксид-иона) значительно выше, чем в водном. Поэтому в этих условиях преобладает реакция отщепления (элиминирования, или дегидрогалогенирования). Отщепляется атом водорода от соседнего (β) атома углерода и атом галогена, что приводит к образованию двойной связи.
Уравнение реакции:
$CH_3CH_2Br + KOH_{(спирт.)} \xrightarrow{t} CH_2=CH_2\uparrow + KBr + H_2O$
Основными продуктами являются этен (газ), бромид калия и вода.
Ответ: $CH_3CH_2Br + KOH_{(спирт.)} \rightarrow CH_2=CH_2 + KBr + H_2O$
с металлическим натрием
Реакция с металлическим натрием ($Na$) — это классический синтез Вюрца. В ходе реакции происходит удвоение углеродного скелета исходного галогеналкана с образованием симметричного алкана.
Уравнение реакции:
$2CH_3CH_2Br + 2Na \rightarrow CH_3CH_2CH_2CH_3 + 2NaBr$
Продукты реакции — н-бутан и бромид натрия.
Ответ: $2CH_3CH_2Br + 2Na \rightarrow CH_3CH_2CH_2CH_3 + 2NaBr$
с магнием в эфире
Взаимодействие с металлическим магнием ($Mg$) в среде безводного (абсолютного) диэтилового эфира приводит к образованию металлоорганического соединения — реактива Гриньяра. Эфир необходим для стабилизации образующегося реактива.
Уравнение реакции:
$CH_3CH_2Br + Mg \xrightarrow{эфир} CH_3CH_2MgBr$
Образуется этилмагнийбромид, который является важным реагентом для создания новых углерод-углеродных связей в органическом синтезе.
Ответ: $CH_3CH_2Br + Mg \xrightarrow{эфир} CH_3CH_2MgBr$
Другие задания:
Помогло решение? Оставьте отзыв в комментариях ниже.
Присоединяйтесь к Телеграм-группе @top_gdz
ПрисоединитьсяМы подготовили для вас ответ c подробным объяснением домашего задания по химии за 10 класс, для упражнения номер 3 расположенного на странице 225 к учебнику 2023 года издания для учащихся школ и гимназий.
Теперь на нашем сайте ГДЗ.ТОП вы всегда легко и бесплатно найдёте условие с правильным ответом на вопрос «Как решить ДЗ» и «Как сделать» задание по химии к упражнению №3 (с. 225), авторов: Еремин (Вадим Владимирович), Кузьменко (Николай Егорович), Теренин (Владимир Ильич), Дроздов (Андрей Анатольевич), Лунин (Валерий Васильевич), ФГОС (старый) углублённый уровень обучения учебного пособия издательства Просвещение.