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Номер 5, страница 172 - гдз по химии 10 класс учебник Еремин, Кузьменко
Авторы: Еремин В. В., Кузьменко Н. Е., Теренин В. И., Дроздов А. А., Лунин В. В.
Тип: Учебник
Издательство: Просвещение
Год издания: 2023 - 2026
Уровень обучения: углублённый
Цвет обложки: белый, зелёный с радугой
Допущено Министерством просвещения Российской Федерации
Популярные ГДЗ в 10 классе
Глава 3. Углеводороды. Параграф 29. Химические свойства алкенов - номер 5, страница 172.
App\Models\Task {#1003 // resources/views/models/task/default.blade.php #connection: "mysql" #table: "tasks" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:24 [ "id" => 663065 "created_at" => "2026-04-10 00:54:11" "updated_at" => null "field_page_start" => "172" "field_page_end" => null "field_url" => "/10-klass/himiya/eremin-uchebnik/29-5" "field_display_title" => "5" "field_outside_task" => null "field_task_type" => Illuminate\Database\Eloquent\Collection {#1009 #items: array:1 [ 0 => App\Models\Term {#1008 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:6 [ "id" => 26 "created_at" => "2026-04-10 00:54:11" "updated_at" => null "name" => "номер" "field_cases" => array:6 [ "field_accusative_case" => "номер" "field_creative_case" => "номером" "field_dative_case" => "номеру" "field_genitive_case" => "номера" "field_nominative_case" => "номер" "field_prepositional_case" => "номере" ] "field_short_name" => "№" ] #original: array:6 [ "id" => 26 "created_at" => "2026-04-10 00:54:11" "updated_at" => null "name" => "номер" "field_cases" => array:6 [ "field_accusative_case" => "номер" "field_creative_case" => "номером" "field_dative_case" => "номеру" "field_genitive_case" => "номера" "field_nominative_case" => "номер" "field_prepositional_case" => "номере" ] "field_short_name" => "№" ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "field_match" => null "breadcrumbs" => [] "edition_groups" => Illuminate\Database\Eloquent\Collection {#1007 #items: [] #escapeWhenCastingToString: false } "top_parent_branch" => Illuminate\Database\Eloquent\Collection {#1051 #items: array:1 [ 0 => App\Models\Branch {#1006 #connection: "mysql" #table: "branches" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:23 [ "id" => 662723 "created_at" => "2026-04-10 00:54:11" "updated_at" => null "field_display_title" => "Углеводороды" "field_branch_order" => "3" "field_url" => null "field_branch_type" => Illuminate\Database\Eloquent\Collection {#1011 #items: array:1 [ 0 => App\Models\Term {#1010 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:7 [ "id" => 29 "created_at" => "2026-04-10 00:54:11" "updated_at" => null "name" => "Глава" "field_cases" => array:6 [ …6] "field_page_check_not_needed" => null "field_short_name" => null ] #original: array:7 [ "id" => 29 "created_at" => "2026-04-10 00:54:11" "updated_at" => null "name" => "Глава" "field_cases" => array:6 [ …6] "field_page_check_not_needed" => null "field_short_name" => null ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "field_page_start" => "139" "field_branch_display" => "0" "field_branch_expanded" => "0" "field_display_branch_in_title" => "1" "field_display_task_interval" => "0" "field_display_branch_page" => "1" "field_branch_title_in_content" => "0" "field_navigation_title" => null "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "field_branch_cover" => [] "book" => Illuminate\Database\Eloquent\Collection {#1012 #items: array:1 [ 0 => App\Models\Book {#1013 #connection: "mysql" #table: "books" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:50 [ "id" => 1003 "created_at" => "2026-04-10 00:54:11" "updated_at" => null "field_tree_default_status" => "tasks" "field_pages_status" => null "field_subject" => Illuminate\Database\Eloquent\Collection {#1014 …2} "field_class" => Illuminate\Database\Eloquent\Collection {#1016 …2} "field_publisher" => Illuminate\Database\Eloquent\Collection {#1018 …2} "field_author" => Illuminate\Database\Eloquent\Collection {#1020 …2} "field_author_foreign" => Illuminate\Database\Eloquent\Collection {#1026 …2} "field_book_type" => Illuminate\Database\Eloquent\Collection {#1027 …2} "field_country" => Illuminate\Database\Eloquent\Collection {#1029 …2} "field_city" => Illuminate\Database\Eloquent\Collection {#1031 …2} "field_series" => Illuminate\Database\Eloquent\Collection {#1033 …2} "field_umk" => Illuminate\Database\Eloquent\Collection {#1034 …2} "field_level_of_education" => Illuminate\Database\Eloquent\Collection {#1035 …2} "field_standart_of_education" => Illuminate\Database\Eloquent\Collection {#1037 …2} "field_publication_number" => "10" "field_publication_type" => Illuminate\Database\Eloquent\Collection {#1039 …2} "field_under_the_edition" => Illuminate\Database\Eloquent\Collection {#1041 …2} "field_under_the_edition_degree" => "доктор химических наук, академика РАН" "field_cover_description" => "с радугой" "field_publication_year" => "2023" "field_publication_year_until" => null "field_part" => "" "field_part_writing" => "" "field_second_foreign_language" => null "field_for_whom" => null "field_allowed" => "Допущено Министерством просвещения Российской Федерации" "field_reserve_field" => null "field_link_to_source" => null "field_tasks_count" => "697" "field_priority" => "10" "field_default_folder" => "/himiya_10/eremin-u23/" "field_isbn" => null "field_cover" => array:1 [ …1] "field_cover_alts" => array:1 [ …1] "field_covers" => array:1 [ …1] "field_popular_book" => null "field_recommended_books" => Illuminate\Database\Eloquent\Collection {#1042 …2} "field_new_book" => Illuminate\Database\Eloquent\Collection {#1043 …2} "field_old_book" => Illuminate\Database\Eloquent\Collection {#1044 …2} "field_url" => "/10-klass/himiya/eremin-uchebnik" "field_cover_color" => Illuminate\Database\Eloquent\Collection {#1045 …2} "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "breadcrumbs" => array:3 [ …3] ] #original: array:50 [ "id" => 1003 "created_at" => "2026-04-10 00:54:11" "updated_at" => null "field_tree_default_status" => "tasks" "field_pages_status" => null "field_subject" => Illuminate\Database\Eloquent\Collection {#1014 …2} "field_class" => Illuminate\Database\Eloquent\Collection {#1016 …2} "field_publisher" => Illuminate\Database\Eloquent\Collection {#1018 …2} "field_author" => Illuminate\Database\Eloquent\Collection {#1020 …2} "field_author_foreign" => Illuminate\Database\Eloquent\Collection {#1026 …2} "field_book_type" => Illuminate\Database\Eloquent\Collection {#1027 …2} "field_country" => Illuminate\Database\Eloquent\Collection {#1029 …2} "field_city" => Illuminate\Database\Eloquent\Collection {#1031 …2} "field_series" => Illuminate\Database\Eloquent\Collection {#1033 …2} "field_umk" => Illuminate\Database\Eloquent\Collection {#1034 …2} "field_level_of_education" => Illuminate\Database\Eloquent\Collection {#1035 …2} "field_standart_of_education" => Illuminate\Database\Eloquent\Collection {#1037 …2} "field_publication_number" => "10" "field_publication_type" => Illuminate\Database\Eloquent\Collection {#1039 …2} "field_under_the_edition" => Illuminate\Database\Eloquent\Collection {#1041 …2} "field_under_the_edition_degree" => "доктор химических наук, академика РАН" "field_cover_description" => "с радугой" "field_publication_year" => "2023" "field_publication_year_until" => null "field_part" => "" "field_part_writing" => "" "field_second_foreign_language" => null "field_for_whom" => null "field_allowed" => "Допущено Министерством просвещения Российской Федерации" "field_reserve_field" => null "field_link_to_source" => null "field_tasks_count" => "697" "field_priority" => "10" "field_default_folder" => "/himiya_10/eremin-u23/" "field_isbn" => null "field_cover" => array:1 [ …1] "field_cover_alts" => array:1 [ …1] "field_covers" => array:1 [ …1] "field_popular_book" => null "field_recommended_books" => Illuminate\Database\Eloquent\Collection {#1042 …2} "field_new_book" => Illuminate\Database\Eloquent\Collection {#1043 …2} "field_old_book" => Illuminate\Database\Eloquent\Collection {#1044 …2} "field_url" => "/10-klass/himiya/eremin-uchebnik" "field_cover_color" => Illuminate\Database\Eloquent\Collection {#1045 …2} "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "breadcrumbs" => array:3 [ …3] ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "branch_parent" => Illuminate\Database\Eloquent\Collection {#1048 #items: [] #escapeWhenCastingToString: false } ] #original: array:23 [ "id" => 662723 "created_at" => "2026-04-10 00:54:11" "updated_at" => null "field_display_title" => "Углеводороды" "field_branch_order" => "3" "field_url" => null "field_branch_type" => Illuminate\Database\Eloquent\Collection {#1011} "field_page_start" => "139" "field_branch_display" => "0" "field_branch_expanded" => "0" "field_display_branch_in_title" => "1" "field_display_task_interval" => "0" "field_display_branch_page" => "1" "field_branch_title_in_content" => "0" "field_navigation_title" => null "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "field_branch_cover" => [] "book" => Illuminate\Database\Eloquent\Collection {#1012} "branch_parent" => Illuminate\Database\Eloquent\Collection {#1048} ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "parent_branches" => Illuminate\Database\Eloquent\Collection {#1092 #items: array:2 [ 0 => App\Models\Branch {#1100 #connection: "mysql" #table: "branches" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:23 [ "id" => 662723 "created_at" => "2026-04-10 00:54:11" "updated_at" => null "field_display_title" => "Углеводороды" "field_branch_order" => "3" "field_url" => null "field_branch_type" => Illuminate\Database\Eloquent\Collection {#1104 #items: array:1 [ 0 => App\Models\Term {#1101 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:7 [ "id" => 29 "created_at" => "2026-04-10 00:54:11" "updated_at" => null "name" => "Глава" "field_cases" => array:6 [ …6] "field_page_check_not_needed" => null "field_short_name" => null ] #original: array:7 [ "id" => 29 "created_at" => "2026-04-10 00:54:11" "updated_at" => null "name" => "Глава" "field_cases" => array:6 [ …6] "field_page_check_not_needed" => null "field_short_name" => null ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "field_page_start" => "139" "field_branch_display" => "0" "field_branch_expanded" => "0" "field_display_branch_in_title" => "1" "field_display_task_interval" => "0" "field_display_branch_page" => "1" "field_branch_title_in_content" => "0" "field_navigation_title" => null "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "field_branch_cover" => [] "book" => Illuminate\Database\Eloquent\Collection {#1140 #items: array:1 [ 0 => App\Models\Book {#1103 #connection: "mysql" #table: "books" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:50 [ "id" => 1003 "created_at" => "2026-04-10 00:54:11" "updated_at" => null "field_tree_default_status" => "tasks" "field_pages_status" => null "field_subject" => Illuminate\Database\Eloquent\Collection {#1105 #items: array:1 [ 0 => App\Models\Term {#1102 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:10 [ "id" => 6495 "created_at" => "2026-04-10 00:54:11" "updated_at" => null "name" => "Химия" "field_abbreviated_name" => null "field_cases" => array:6 [ …6] "field_foreign_lang_name" => null "field_short_name" => null "field_subject_type" => "technical_subject" "field_translit" => "himiya" ] #original: array:10 [ "id" => 6495 "created_at" => "2026-04-10 00:54:11" "updated_at" => null "name" => "Химия" "field_abbreviated_name" => null "field_cases" => array:6 [ …6] "field_foreign_lang_name" => null "field_short_name" => null "field_subject_type" => "technical_subject" "field_translit" => "himiya" ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "field_class" => Illuminate\Database\Eloquent\Collection {#1106 #items: array:1 [ 0 => App\Models\Term {#1107 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:6 [ "id" => 5459 "created_at" => "2026-04-10 00:54:11" "updated_at" => null "name" => "10" "field_cases" => array:6 [ …6] "field_translit" => "desjatyj" ] #original: array:6 [ "id" => 5459 "created_at" => "2026-04-10 00:54:11" "updated_at" => null "name" => "10" "field_cases" => array:6 [ …6] "field_translit" => "desjatyj" ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "field_publisher" => Illuminate\Database\Eloquent\Collection {#1108 #items: array:1 [ 0 => App\Models\Term {#1109 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:6 [ "id" => 5153 "created_at" => "2026-04-10 00:54:11" "updated_at" => null "name" => "Просвещение" "field_cases" => null "field_translit" => "prosveschenie" ] #original: array:6 [ "id" => 5153 "created_at" => "2026-04-10 00:54:11" "updated_at" => null "name" => "Просвещение" "field_cases" => null "field_translit" => "prosveschenie" ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "field_author" => Illuminate\Database\Eloquent\Collection {#1110 #items: array:5 [ 0 => App\Models\Term {#1111 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:12 [ "id" => 4330 "created_at" => "2026-04-10 00:54:11" "updated_at" => null "name" => "Еремин" "field_bio" => null "field_degree_rp" => null "field_foreign_lang_name" => null "field_foreign_lang_patronymic" => null "field_foreign_lang_surname" => null "field_name" => "Вадим" "field_patronymic" => "Владимирович" "field_surname_rp" => null ] #original: array:12 [ "id" => 4330 "created_at" => "2026-04-10 00:54:11" "updated_at" => null "name" => "Еремин" "field_bio" => null "field_degree_rp" => null "field_foreign_lang_name" => null "field_foreign_lang_patronymic" => null "field_foreign_lang_surname" => null "field_name" => "Вадим" "field_patronymic" => "Владимирович" "field_surname_rp" => null ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } 1 => App\Models\Term {#1112 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:12 [ "id" => 4876 "created_at" => "2026-04-10 00:54:11" "updated_at" => null "name" => "Кузьменко" "field_bio" => null "field_degree_rp" => null "field_foreign_lang_name" => null "field_foreign_lang_patronymic" => null "field_foreign_lang_surname" => null "field_name" => "Николай" "field_patronymic" => "Егорович" "field_surname_rp" => null ] #original: array:12 [ "id" => 4876 "created_at" => "2026-04-10 00:54:11" "updated_at" => null "name" => "Кузьменко" "field_bio" => null "field_degree_rp" => null "field_foreign_lang_name" => null "field_foreign_lang_patronymic" => null "field_foreign_lang_surname" => null "field_name" => "Николай" "field_patronymic" => "Егорович" "field_surname_rp" => null ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } 2 => App\Models\Term {#1113 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:12 [ "id" => 5912 "created_at" => "2026-04-10 00:54:11" "updated_at" => null "name" => "Теренин" "field_bio" => null "field_degree_rp" => null "field_foreign_lang_name" => null "field_foreign_lang_patronymic" => null "field_foreign_lang_surname" => null "field_name" => "Владимир" "field_patronymic" => "Ильич" "field_surname_rp" => null ] #original: array:12 [ "id" => 5912 "created_at" => "2026-04-10 00:54:11" "updated_at" => null "name" => "Теренин" "field_bio" => null "field_degree_rp" => null "field_foreign_lang_name" => null "field_foreign_lang_patronymic" => null "field_foreign_lang_surname" => null "field_name" => "Владимир" "field_patronymic" => "Ильич" "field_surname_rp" => null ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } 3 => App\Models\Term {#1114 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:12 [ "id" => 4290 "created_at" => "2026-04-10 00:54:11" "updated_at" => null "name" => "Дроздов" "field_bio" => null "field_degree_rp" => null "field_foreign_lang_name" => null "field_foreign_lang_patronymic" => null "field_foreign_lang_surname" => null "field_name" => "Андрей" "field_patronymic" => "Анатольевич" "field_surname_rp" => null ] #original: array:12 [ "id" => 4290 "created_at" => "2026-04-10 00:54:11" "updated_at" => null "name" => "Дроздов" "field_bio" => null "field_degree_rp" => null "field_foreign_lang_name" => null "field_foreign_lang_patronymic" => null "field_foreign_lang_surname" => null "field_name" => "Андрей" "field_patronymic" => "Анатольевич" "field_surname_rp" => null ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } 4 => App\Models\Term {#1115 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:12 [ "id" => 5031 "created_at" => "2026-04-10 00:54:11" "updated_at" => null "name" => "Лунин" "field_bio" => null "field_degree_rp" => "доктор химических наук, академика РАН" "field_foreign_lang_name" => null "field_foreign_lang_patronymic" => null "field_foreign_lang_surname" => null "field_name" => "Валерий" "field_patronymic" => "Васильевич" "field_surname_rp" => "Лунина" ] #original: array:12 [ "id" => 5031 "created_at" => "2026-04-10 00:54:11" "updated_at" => null "name" => "Лунин" "field_bio" => null "field_degree_rp" => "доктор химических наук, академика РАН" "field_foreign_lang_name" => null "field_foreign_lang_patronymic" => null "field_foreign_lang_surname" => null "field_name" => "Валерий" "field_patronymic" => "Васильевич" "field_surname_rp" => "Лунина" ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "field_author_foreign" => Illuminate\Database\Eloquent\Collection {#1116 #items: [] #escapeWhenCastingToString: false } "field_book_type" => Illuminate\Database\Eloquent\Collection {#1117 #items: array:1 [ 0 => App\Models\Term {#1118 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:10 [ "id" => 6671 "created_at" => "2026-04-10 00:54:11" "updated_at" => null "name" => "Учебник" "field_book_type_foreign" => null "field_cases" => array:6 [ …6] "field_plural_form" => null "field_short_name" => null "field_short_name_foreign" => null "field_translit" => "uchebnik" ] #original: array:10 [ "id" => 6671 "created_at" => "2026-04-10 00:54:11" "updated_at" => null "name" => "Учебник" "field_book_type_foreign" => null "field_cases" => array:6 [ …6] "field_plural_form" => null "field_short_name" => null "field_short_name_foreign" => null "field_translit" => "uchebnik" ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "field_country" => Illuminate\Database\Eloquent\Collection {#1119 #items: array:1 [ 0 => App\Models\Term {#1120 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:6 [ "id" => 9 "created_at" => "2026-04-10 00:54:11" "updated_at" => null "name" => "Россия" "field_cases" => array:6 [ …6] "field_translit" => "rossiya" ] #original: array:6 [ "id" => 9 "created_at" => "2026-04-10 00:54:11" "updated_at" => null "name" => "Россия" "field_cases" => array:6 [ …6] "field_translit" => "rossiya" ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } ] #escapeWhenCastingToString: false } "field_city" => Illuminate\Database\Eloquent\Collection {#1121 #items: array:1 [ 0 => App\Models\Term {#1122 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:6 [ …6] #original: array:6 [ …6] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } ] #escapeWhenCastingToString: false } "field_series" => Illuminate\Database\Eloquent\Collection {#1123 #items: [] #escapeWhenCastingToString: false } "field_umk" => Illuminate\Database\Eloquent\Collection {#1124 #items: [] #escapeWhenCastingToString: false } "field_level_of_education" => Illuminate\Database\Eloquent\Collection {#1125 #items: array:1 [ 0 => App\Models\Term {#1126 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:6 [ …6] #original: array:6 [ …6] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } ] #escapeWhenCastingToString: false } "field_standart_of_education" => Illuminate\Database\Eloquent\Collection {#1127 #items: array:1 [ 0 => App\Models\Term {#1128 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:10 [ …10] #original: array:10 [ …10] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } ] #escapeWhenCastingToString: false } "field_publication_number" => "10" "field_publication_type" => Illuminate\Database\Eloquent\Collection {#1129 #items: array:1 [ 0 => App\Models\Term {#1130 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:6 [ …6] #original: array:6 [ …6] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } ] #escapeWhenCastingToString: false } "field_under_the_edition" => Illuminate\Database\Eloquent\Collection {#1131 #items: array:1 [ 0 => App\Models\Term {#1115} ] #escapeWhenCastingToString: false } "field_under_the_edition_degree" => "доктор химических наук, академика РАН" "field_cover_description" => "с радугой" "field_publication_year" => "2023" "field_publication_year_until" => null "field_part" => "" "field_part_writing" => "" "field_second_foreign_language" => null "field_for_whom" => null "field_allowed" => "Допущено Министерством просвещения Российской Федерации" "field_reserve_field" => null "field_link_to_source" => null "field_tasks_count" => "697" "field_priority" => "10" "field_default_folder" => "/himiya_10/eremin-u23/" "field_isbn" => null "field_cover" => array:1 [ 0 => "/media/himiya_10/eremin-u23/covers/cover1.webp" ] "field_cover_alts" => array:1 [ 0 => "" ] "field_covers" => array:1 [ 0 => array:4 [ "path" => "/media/himiya_10/eremin-u23/covers/cover1.webp" "alt" => "" "width" => "1200" "height" => "1576" ] ] "field_popular_book" => null "field_recommended_books" => Illuminate\Database\Eloquent\Collection {#1132 #items: [] #escapeWhenCastingToString: false } "field_new_book" => Illuminate\Database\Eloquent\Collection {#1133 #items: [] #escapeWhenCastingToString: false } "field_old_book" => Illuminate\Database\Eloquent\Collection {#1134 #items: [] #escapeWhenCastingToString: false } "field_url" => "/10-klass/himiya/eremin-uchebnik" "field_cover_color" => Illuminate\Database\Eloquent\Collection {#1135 #items: array:2 [ 0 => App\Models\Term {#1136 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:6 [ …6] #original: array:6 [ …6] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } 1 => App\Models\Term {#1137 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:6 [ …6] #original: array:6 [ …6] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } ] #escapeWhenCastingToString: false } "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "breadcrumbs" => array:3 [ "class" => 381 "subject" => 558 "class_subject" => 500 ] ] #original: array:50 [ "id" => 1003 "created_at" => "2026-04-10 00:54:11" "updated_at" => null "field_tree_default_status" => "tasks" "field_pages_status" => null "field_subject" => Illuminate\Database\Eloquent\Collection {#1105} "field_class" => Illuminate\Database\Eloquent\Collection {#1106} "field_publisher" => Illuminate\Database\Eloquent\Collection {#1108} "field_author" => Illuminate\Database\Eloquent\Collection {#1110} "field_author_foreign" => Illuminate\Database\Eloquent\Collection {#1116} "field_book_type" => Illuminate\Database\Eloquent\Collection {#1117} "field_country" => Illuminate\Database\Eloquent\Collection {#1119} "field_city" => Illuminate\Database\Eloquent\Collection {#1121} "field_series" => Illuminate\Database\Eloquent\Collection {#1123} "field_umk" => Illuminate\Database\Eloquent\Collection {#1124} "field_level_of_education" => Illuminate\Database\Eloquent\Collection {#1125} "field_standart_of_education" => Illuminate\Database\Eloquent\Collection {#1127} "field_publication_number" => "10" "field_publication_type" => Illuminate\Database\Eloquent\Collection {#1129} "field_under_the_edition" => Illuminate\Database\Eloquent\Collection {#1131} "field_under_the_edition_degree" => "доктор химических наук, академика РАН" "field_cover_description" => "с радугой" "field_publication_year" => "2023" "field_publication_year_until" => null "field_part" => "" "field_part_writing" => "" "field_second_foreign_language" => null "field_for_whom" => null "field_allowed" => "Допущено Министерством просвещения Российской Федерации" "field_reserve_field" => null "field_link_to_source" => null "field_tasks_count" => "697" "field_priority" => "10" "field_default_folder" => "/himiya_10/eremin-u23/" "field_isbn" => null "field_cover" => array:1 [ 0 => "/media/himiya_10/eremin-u23/covers/cover1.webp" ] "field_cover_alts" => array:1 [ 0 => "" ] "field_covers" => array:1 [ 0 => array:4 [ "path" => "/media/himiya_10/eremin-u23/covers/cover1.webp" "alt" => "" "width" => "1200" "height" => "1576" ] ] "field_popular_book" => null "field_recommended_books" => Illuminate\Database\Eloquent\Collection {#1132} "field_new_book" => Illuminate\Database\Eloquent\Collection {#1133} "field_old_book" => Illuminate\Database\Eloquent\Collection {#1134} "field_url" => "/10-klass/himiya/eremin-uchebnik" "field_cover_color" => Illuminate\Database\Eloquent\Collection {#1135} "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "breadcrumbs" => array:3 [ "class" => 381 "subject" => 558 "class_subject" => 500 ] ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "branch_parent" => Illuminate\Database\Eloquent\Collection {#1138 #items: [] #escapeWhenCastingToString: false } ] #original: array:23 [ "id" => 662723 "created_at" => "2026-04-10 00:54:11" "updated_at" => null "field_display_title" => "Углеводороды" "field_branch_order" => "3" "field_url" => null "field_branch_type" => Illuminate\Database\Eloquent\Collection {#1104} "field_page_start" => "139" "field_branch_display" => "0" "field_branch_expanded" => "0" "field_display_branch_in_title" => "1" "field_display_task_interval" => "0" "field_display_branch_page" => "1" "field_branch_title_in_content" => "0" "field_navigation_title" => null "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "field_branch_cover" => [] "book" => Illuminate\Database\Eloquent\Collection {#1140} "branch_parent" => Illuminate\Database\Eloquent\Collection {#1138} ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } 1 => App\Models\Branch {#1139 #connection: "mysql" #table: "branches" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:23 [ "id" => 662729 "created_at" => "2026-04-10 00:54:11" "updated_at" => null "field_display_title" => "Химические свойства алкенов" "field_branch_order" => "29" "field_url" => null "field_branch_type" => Illuminate\Database\Eloquent\Collection {#1144 #items: array:1 [ 0 => App\Models\Term {#1141 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:7 [ "id" => 32 "created_at" => "2026-04-10 00:54:11" "updated_at" => null "name" => "Параграф" "field_cases" => array:6 [ …6] "field_page_check_not_needed" => null "field_short_name" => "§" ] #original: array:7 [ "id" => 32 "created_at" => "2026-04-10 00:54:11" "updated_at" => null "name" => "Параграф" "field_cases" => array:6 [ …6] "field_page_check_not_needed" => null "field_short_name" => "§" ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "field_page_start" => "166" "field_branch_display" => "0" "field_branch_expanded" => "0" "field_display_branch_in_title" => "1" "field_display_task_interval" => "0" "field_display_branch_page" => "1" "field_branch_title_in_content" => "0" "field_navigation_title" => null "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "field_branch_cover" => [] "book" => Illuminate\Database\Eloquent\Collection {#1143 #items: array:1 [ 0 => App\Models\Book {#1103} ] #escapeWhenCastingToString: false } "branch_parent" => Illuminate\Database\Eloquent\Collection {#1142 #items: array:1 [ 0 => App\Models\Branch {#1006} ] #escapeWhenCastingToString: false } ] #original: array:23 [ "id" => 662729 "created_at" => "2026-04-10 00:54:11" "updated_at" => null "field_display_title" => "Химические свойства алкенов" "field_branch_order" => "29" "field_url" => null "field_branch_type" => Illuminate\Database\Eloquent\Collection {#1144} "field_page_start" => "166" "field_branch_display" => "0" "field_branch_expanded" => "0" "field_display_branch_in_title" => "1" "field_display_task_interval" => "0" "field_display_branch_page" => "1" "field_branch_title_in_content" => "0" "field_navigation_title" => null "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "field_branch_cover" => [] "book" => Illuminate\Database\Eloquent\Collection {#1143} "branch_parent" => Illuminate\Database\Eloquent\Collection {#1142} ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "content" => Illuminate\Database\Eloquent\Collection {#1089 #items: array:3 [ 0 => App\Models\Element {#1082 #connection: "mysql" #table: "elements" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:7 [ "id" => 818662 "created_at" => "2026-04-10 00:54:11" "updated_at" => null "edition" => Illuminate\Database\Eloquent\Collection {#1074 #items: array:1 [ 0 => App\Models\Edition {#1066 #connection: "mysql" #table: "editions" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:21 [ "id" => 1829 "created_at" => "2026-04-10 00:54:11" "updated_at" => null "title" => "Условие" "field_order" => "1" "field_publisher" => Illuminate\Database\Eloquent\Collection {#1081 …2} "field_content_type" => "free" "field_content_mode" => "text, image" "field_page_content_mode" => "image" "field_content_text_checked" => null "field_page_content_text_checked" => "0" "field_solution_author" => "Автор" "field_moderator" => "vadim" "field_edition_type" => "statement" "field_root_dir" => "0-" "field_responsible" => Illuminate\Database\Eloquent\Collection {#1078 …2} "field_comment" => null "field_similar_book" => Illuminate\Database\Eloquent\Collection {#1079 …2} "field_process_formula" => "katex" "field_edition_group" => Illuminate\Database\Eloquent\Collection {#1076 …2} "field_content_source" => null ] #original: array:21 [ "id" => 1829 "created_at" => "2026-04-10 00:54:11" "updated_at" => null "title" => "Условие" "field_order" => "1" "field_publisher" => Illuminate\Database\Eloquent\Collection {#1081 …2} "field_content_type" => "free" "field_content_mode" => "text, image" "field_page_content_mode" => "image" "field_content_text_checked" => null "field_page_content_text_checked" => "0" "field_solution_author" => "Автор" "field_moderator" => "vadim" "field_edition_type" => "statement" "field_root_dir" => "0-" "field_responsible" => Illuminate\Database\Eloquent\Collection {#1078 …2} "field_comment" => null "field_similar_book" => Illuminate\Database\Eloquent\Collection {#1079 …2} "field_process_formula" => "katex" "field_edition_group" => Illuminate\Database\Eloquent\Collection {#1076 …2} "field_content_source" => null ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "task" => array:2 [ "refs" => "663065" "type" => "task" ] "text" => "<p><strong>5.</strong> Напишите уравнения реакций пропена:</p><p><strong>а)</strong> с водородом;</p><p><strong>б)</strong> с бромоводородом;</p><p><strong>в)</strong> с бромом;</p><p><strong>г)</strong> с водой.</p><p>В каких случаях наряду с главным продуктом реакции образуется побочный?</p>" "img" => array:1 [ 0 => array:5 [ "name" => "5-1.jpg" "alt" => null "width" => "852" "height" => 125 "path" => "/media/himiya_10/eremin-u23/0-29/5-1.webp?ts=1738779554" ] ] ] #original: array:7 [ "id" => 818662 "created_at" => "2026-04-10 00:54:11" "updated_at" => null "edition" => Illuminate\Database\Eloquent\Collection {#1074} "task" => array:2 [ "refs" => "663065" "type" => "task" ] "text" => "<p><strong>5.</strong> Напишите уравнения реакций пропена:</p><p><strong>а)</strong> с водородом;</p><p><strong>б)</strong> с бромоводородом;</p><p><strong>в)</strong> с бромом;</p><p><strong>г)</strong> с водой.</p><p>В каких случаях наряду с главным продуктом реакции образуется побочный?</p>" "img" => array:1 [ 0 => array:5 [ "name" => "5-1.jpg" "alt" => null "width" => "852" "height" => 125 "path" => "/media/himiya_10/eremin-u23/0-29/5-1.webp?ts=1738779554" ] ] ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } 1 => App\Models\Element {#1077 #connection: "mysql" #table: "elements" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:6 [ "id" => 818873 "created_at" => "2026-04-10 00:54:11" "updated_at" => null "edition" => Illuminate\Database\Eloquent\Collection {#1061 #items: array:1 [ 0 => App\Models\Edition {#1075 #connection: "mysql" #table: "editions" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:21 [ "id" => 1830 "created_at" => "2026-04-10 00:54:11" "updated_at" => null "title" => "Решение" "field_order" => "2" "field_publisher" => Illuminate\Database\Eloquent\Collection {#1073 …2} "field_content_type" => "free" "field_content_mode" => "image" "field_page_content_mode" => "" "field_content_text_checked" => "0" "field_page_content_text_checked" => "0" "field_solution_author" => "Ладыко (Торчило)" "field_moderator" => "vadim" "field_edition_type" => "solution" "field_root_dir" => "1-" "field_responsible" => Illuminate\Database\Eloquent\Collection {#1070 …2} "field_comment" => null "field_similar_book" => Illuminate\Database\Eloquent\Collection {#1071 …2} "field_process_formula" => "" "field_edition_group" => Illuminate\Database\Eloquent\Collection {#1068 …2} "field_content_source" => null ] #original: array:21 [ "id" => 1830 "created_at" => "2026-04-10 00:54:11" "updated_at" => null "title" => "Решение" "field_order" => "2" "field_publisher" => Illuminate\Database\Eloquent\Collection {#1073 …2} "field_content_type" => "free" "field_content_mode" => "image" "field_page_content_mode" => "" "field_content_text_checked" => "0" "field_page_content_text_checked" => "0" "field_solution_author" => "Ладыко (Торчило)" "field_moderator" => "vadim" "field_edition_type" => "solution" "field_root_dir" => "1-" "field_responsible" => Illuminate\Database\Eloquent\Collection {#1070 …2} "field_comment" => null "field_similar_book" => Illuminate\Database\Eloquent\Collection {#1071 …2} "field_process_formula" => "" "field_edition_group" => Illuminate\Database\Eloquent\Collection {#1068 …2} "field_content_source" => null ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "task" => array:2 [ "refs" => "663065" "type" => "task" ] "img" => array:1 [ 0 => array:5 [ "name" => "5-1.jpg" "alt" => null "width" => "1764" "height" => 747 "path" => "/media/himiya_10/eremin-u23/1-29/5-1.webp?ts=1738779623" ] ] ] #original: array:6 [ "id" => 818873 "created_at" => "2026-04-10 00:54:11" "updated_at" => null "edition" => Illuminate\Database\Eloquent\Collection {#1061} "task" => array:2 [ "refs" => "663065" "type" => "task" ] "img" => array:1 [ 0 => array:5 [ "name" => "5-1.jpg" "alt" => null "width" => "1764" "height" => 747 "path" => "/media/himiya_10/eremin-u23/1-29/5-1.webp?ts=1738779623" ] ] ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } 2 => App\Models\Element {#1069 #connection: "mysql" #table: "elements" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:6 [ "id" => 1515469 "created_at" => "2026-04-10 00:54:11" "updated_at" => null "edition" => Illuminate\Database\Eloquent\Collection {#1058 #items: array:1 [ 0 => App\Models\Edition {#1067 #connection: "mysql" #table: "editions" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:21 [ "id" => 5553 "created_at" => "2026-04-10 00:54:11" "updated_at" => null "title" => "Решение 2" "field_order" => "3" "field_publisher" => Illuminate\Database\Eloquent\Collection {#1064 …2} "field_content_type" => "free" "field_content_mode" => "text" "field_page_content_mode" => "" "field_content_text_checked" => null "field_page_content_text_checked" => "0" "field_solution_author" => "Gemini 2.5 Pro" "field_moderator" => "tolik" "field_edition_type" => "solution" "field_root_dir" => "2-" "field_responsible" => Illuminate\Database\Eloquent\Collection {#1063 …2} "field_comment" => null "field_similar_book" => Illuminate\Database\Eloquent\Collection {#1062 …2} "field_process_formula" => "katex" "field_edition_group" => Illuminate\Database\Eloquent\Collection {#1059 …2} "field_content_source" => null ] #original: array:21 [ "id" => 5553 "created_at" => "2026-04-10 00:54:11" "updated_at" => null "title" => "Решение 2" "field_order" => "3" "field_publisher" => Illuminate\Database\Eloquent\Collection {#1064 …2} "field_content_type" => "free" "field_content_mode" => "text" "field_page_content_mode" => "" "field_content_text_checked" => null "field_page_content_text_checked" => "0" "field_solution_author" => "Gemini 2.5 Pro" "field_moderator" => "tolik" "field_edition_type" => "solution" "field_root_dir" => "2-" "field_responsible" => Illuminate\Database\Eloquent\Collection {#1063 …2} "field_comment" => null "field_similar_book" => Illuminate\Database\Eloquent\Collection {#1062 …2} "field_process_formula" => "katex" "field_edition_group" => Illuminate\Database\Eloquent\Collection {#1059 …2} "field_content_source" => null ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "task" => array:2 [ "refs" => "663065" "type" => "task" ] "text" => "<p>Пропен ($CH_3-CH=CH_2$) является непредельным углеводородом из класса алкенов. Для него, как и для всех алкенов, характерны реакции присоединения по месту разрыва двойной связи.</p><p><strong>а) с водородом</strong></p><p>Реакция гидрирования (присоединения водорода) протекает в присутствии металлических катализаторов (например, Ni, Pt, Pd) при нагревании. В результате разрыва $\pi$-связи в молекуле пропена к каждому атому углерода, образующему двойную связь, присоединяется по одному атому водорода. Пропен превращается в соответствующий алкан — пропан. Побочные продукты в данной реакции не образуются.</p><p>$CH_3-CH=CH_2 + H_2 \xrightarrow{кат., t} CH_3-CH_2-CH_3$</p><p><strong>Ответ:</strong> Пропан.</p><p><strong>б) с бромоводородом</strong></p><p>Реакция гидрогалогенирования (присоединения галогеноводорода). Пропен является несимметричным алкеном, так как атомы углерода при двойной связи соединены с разным числом атомов водорода ($CH_2$ и $CH$). Бромоводород ($HBr$) также является несимметричным реагентом. Присоединение таких реагентов к несимметричным алкенам происходит в соответствии с правилом Марковникова: атом водорода присоединяется к наиболее гидрированному атому углерода при двойной связи (в данном случае к $CH_2$), а атом галогена (брома) — к наименее гидрированному (к $CH$).</p><p>$CH_3-CH=CH_2 + HBr \rightarrow CH_3-CH(Br)-CH_3$</p><p>Основным продуктом реакции является 2-бромпропан. Однако, поскольку механизм реакции включает образование карбокатиона, наряду с более стабильным вторичным карбокатионом, который ведет к основному продукту, в небольшом количестве может образовываться и менее стабильный первичный карбокатион. Это приводит к образованию побочного продукта — 1-бромпропана.</p><p><strong>Ответ:</strong> Основной продукт — 2-бромпропан, побочный продукт — 1-бромпропан.</p><p><strong>в) с бромом</strong></p><p>Реакция галогенирования (присоединения брома). Молекула брома ($Br_2$) является симметричным реагентом, поэтому ее присоединение к пропену происходит однозначно. Происходит разрыв двойной связи, и к каждому из атомов углерода присоединяется по одному атому брома. Эта реакция является качественной на двойную связь, так как приводит к обесцвечиванию бромной воды. Побочные продукты не образуются.</p><p>$CH_3-CH=CH_2 + Br_2 \rightarrow CH_3-CH(Br)-CH_2Br$</p><p><strong>Ответ:</strong> 1,2-дибромпропан.</p><p><strong>г) с водой</strong></p><p>Реакция гидратации (присоединения воды) протекает в кислой среде (катализатор — $H_2SO_4$ или $H_3PO_4$) при нагревании. Вода ($H_2O$) является несимметричным реагентом, поэтому ее присоединение к несимметричному пропену также подчиняется правилу Марковникова. Атом водорода из молекулы воды присоединяется к более гидрированному атому углерода ($CH_2$), а гидроксогруппа ($OH$) — к менее гидрированному ($CH$).</p><p>$CH_3-CH=CH_2 + H_2O \xrightarrow{H^+, t} CH_3-CH(OH)-CH_3$</p><p>Основным продуктом является вторичный спирт — пропанол-2. Как и в случае с бромоводородом, возможно образование побочного продукта в результате присоединения против правила Марковникова. Таким продуктом является первичный спирт — пропанол-1.</p><p><strong>Ответ:</strong> Основной продукт — пропанол-2, побочный продукт — пропанол-1.</p><p>Таким образом, образование побочного продукта наряду с главным происходит в случаях реакции пропена <strong>с бромоводородом (б)</strong> и <strong>с водой (г)</strong>. Причиной этого является то, что при присоединении несимметричного реагента к несимметричному алкену реакция может идти по двум разным путям, один из которых (согласно правилу Марковникова) является преобладающим, а другой — менее вероятным, но все же возможным.</p>" ] #original: array:6 [ "id" => 1515469 "created_at" => "2026-04-10 00:54:11" "updated_at" => null "edition" => Illuminate\Database\Eloquent\Collection {#1058} "task" => array:2 [ "refs" => "663065" "type" => "task" ] "text" => "<p>Пропен ($CH_3-CH=CH_2$) является непредельным углеводородом из класса алкенов. Для него, как и для всех алкенов, характерны реакции присоединения по месту разрыва двойной связи.</p><p><strong>а) с водородом</strong></p><p>Реакция гидрирования (присоединения водорода) протекает в присутствии металлических катализаторов (например, Ni, Pt, Pd) при нагревании. В результате разрыва $\pi$-связи в молекуле пропена к каждому атому углерода, образующему двойную связь, присоединяется по одному атому водорода. Пропен превращается в соответствующий алкан — пропан. Побочные продукты в данной реакции не образуются.</p><p>$CH_3-CH=CH_2 + H_2 \xrightarrow{кат., t} CH_3-CH_2-CH_3$</p><p><strong>Ответ:</strong> Пропан.</p><p><strong>б) с бромоводородом</strong></p><p>Реакция гидрогалогенирования (присоединения галогеноводорода). Пропен является несимметричным алкеном, так как атомы углерода при двойной связи соединены с разным числом атомов водорода ($CH_2$ и $CH$). Бромоводород ($HBr$) также является несимметричным реагентом. Присоединение таких реагентов к несимметричным алкенам происходит в соответствии с правилом Марковникова: атом водорода присоединяется к наиболее гидрированному атому углерода при двойной связи (в данном случае к $CH_2$), а атом галогена (брома) — к наименее гидрированному (к $CH$).</p><p>$CH_3-CH=CH_2 + HBr \rightarrow CH_3-CH(Br)-CH_3$</p><p>Основным продуктом реакции является 2-бромпропан. Однако, поскольку механизм реакции включает образование карбокатиона, наряду с более стабильным вторичным карбокатионом, который ведет к основному продукту, в небольшом количестве может образовываться и менее стабильный первичный карбокатион. Это приводит к образованию побочного продукта — 1-бромпропана.</p><p><strong>Ответ:</strong> Основной продукт — 2-бромпропан, побочный продукт — 1-бромпропан.</p><p><strong>в) с бромом</strong></p><p>Реакция галогенирования (присоединения брома). Молекула брома ($Br_2$) является симметричным реагентом, поэтому ее присоединение к пропену происходит однозначно. Происходит разрыв двойной связи, и к каждому из атомов углерода присоединяется по одному атому брома. Эта реакция является качественной на двойную связь, так как приводит к обесцвечиванию бромной воды. Побочные продукты не образуются.</p><p>$CH_3-CH=CH_2 + Br_2 \rightarrow CH_3-CH(Br)-CH_2Br$</p><p><strong>Ответ:</strong> 1,2-дибромпропан.</p><p><strong>г) с водой</strong></p><p>Реакция гидратации (присоединения воды) протекает в кислой среде (катализатор — $H_2SO_4$ или $H_3PO_4$) при нагревании. Вода ($H_2O$) является несимметричным реагентом, поэтому ее присоединение к несимметричному пропену также подчиняется правилу Марковникова. Атом водорода из молекулы воды присоединяется к более гидрированному атому углерода ($CH_2$), а гидроксогруппа ($OH$) — к менее гидрированному ($CH$).</p><p>$CH_3-CH=CH_2 + H_2O \xrightarrow{H^+, t} CH_3-CH(OH)-CH_3$</p><p>Основным продуктом является вторичный спирт — пропанол-2. Как и в случае с бромоводородом, возможно образование побочного продукта в результате присоединения против правила Марковникова. Таким продуктом является первичный спирт — пропанол-1.</p><p><strong>Ответ:</strong> Основной продукт — пропанол-2, побочный продукт — пропанол-1.</p><p>Таким образом, образование побочного продукта наряду с главным происходит в случаях реакции пропена <strong>с бромоводородом (б)</strong> и <strong>с водой (г)</strong>. Причиной этого является то, что при присоединении несимметричного реагента к несимметричному алкену реакция может идти по двум разным путям, один из которых (согласно правилу Марковникова) является преобладающим, а другой — менее вероятным, но все же возможным.</p>" ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "next" => array:2 [ "refs" => "663066" "type" => "task" ] "previous" => array:2 [ "refs" => "663064" "type" => "task" ] "book" => Illuminate\Database\Eloquent\Collection {#1085 #items: array:1 [ 0 => App\Models\Book {#1103} ] #escapeWhenCastingToString: false } "page" => Illuminate\Database\Eloquent\Collection {#1088 #items: array:1 [ 0 => App\Models\BookPage {#1053 #connection: "mysql" #table: "book_pages" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:21 [ "id" => 926068 "created_at" => "2026-04-10 00:54:11" "updated_at" => null "field_page_start" => "172" "field_url" => "/10-klass/himiya/eremin-uchebnik/page-172" "field_display_title" => "172" "field_folder" => "1" "field_image_name" => "172" "field_branch_parent" => Illuminate\Database\Eloquent\Collection {#1054 #items: [] #escapeWhenCastingToString: false } "field_weight" => "0" "field_book_parent" => Illuminate\Database\Eloquent\Collection {#1060 #items: array:1 [ 0 => App\Models\Book {#1103} ] #escapeWhenCastingToString: false } "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "edition_groups" => Illuminate\Database\Eloquent\Collection {#1057 #items: [] #escapeWhenCastingToString: false } "content" => Illuminate\Database\Eloquent\Collection {#1096 #items: array:1 [ 0 => App\Models\Element {#1093 #connection: "mysql" #table: "elements" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:6 [ …6] #original: array:6 [ …6] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } ] #escapeWhenCastingToString: false } "next" => array:2 [ "refs" => "926069" "type" => "book_page" ] "previous" => array:2 [ "refs" => "926067" "type" => "book_page" ] "tasks" => Illuminate\Database\Eloquent\Collection {#1257 #items: array:14 [ 0 => App\Models\Task {#1277 #connection: "mysql" #table: "tasks" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:24 [ …24] #original: array:24 [ …24] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } 1 => App\Models\Task {#1283 #connection: "mysql" #table: "tasks" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:24 [ …24] #original: array:24 [ …24] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } 2 => App\Models\Task {#1288 #connection: "mysql" #table: "tasks" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:24 [ …24] #original: array:24 [ …24] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } 3 => App\Models\Task {#1302 #connection: "mysql" #table: "tasks" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:24 [ …24] #original: array:24 [ …24] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } 4 => App\Models\Task {#1316 #connection: "mysql" #table: "tasks" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:24 [ …24] #original: array:24 [ …24] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } 5 => App\Models\Task {#1328 #connection: "mysql" #table: "tasks" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:24 [ …24] #original: array:24 [ …24] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } 6 => App\Models\Task {#1346 #connection: "mysql" #table: "tasks" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:24 [ …24] #original: array:24 [ …24] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } 7 => App\Models\Task {#1351 #connection: "mysql" #table: "tasks" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:24 [ …24] #original: array:24 [ …24] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } 8 => App\Models\Task {#1365 #connection: "mysql" #table: "tasks" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:24 [ …24] #original: array:24 [ …24] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } 9 => App\Models\Task {#1379 #connection: "mysql" #table: "tasks" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:24 [ …24] #original: array:24 [ …24] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } 10 => App\Models\Task {#1393 #connection: "mysql" #table: "tasks" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:24 [ …24] #original: array:24 [ …24] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } 11 => App\Models\Task {#1407 #connection: "mysql" #table: "tasks" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:24 [ …24] #original: array:24 [ …24] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } 12 => App\Models\Task {#1421 #connection: "mysql" #table: "tasks" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:24 [ …24] #original: array:24 [ …24] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } 13 => App\Models\Task {#1435 #connection: "mysql" #table: "tasks" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:24 [ …24] #original: array:24 [ …24] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } ] #escapeWhenCastingToString: false } ] #original: array:21 [ "id" => 926068 "created_at" => "2026-04-10 00:54:11" "updated_at" => null "field_page_start" => "172" "field_url" => "/10-klass/himiya/eremin-uchebnik/page-172" "field_display_title" => "172" "field_folder" => "1" "field_image_name" => "172" "field_branch_parent" => Illuminate\Database\Eloquent\Collection {#1054} "field_weight" => "0" "field_book_parent" => Illuminate\Database\Eloquent\Collection {#1060} "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "edition_groups" => Illuminate\Database\Eloquent\Collection {#1057} "content" => Illuminate\Database\Eloquent\Collection {#1096} "next" => array:2 [ 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№5 (с. 172)
Условие. №5 (с. 172)
скриншот условия
5. Напишите уравнения реакций пропена:
а) с водородом;
б) с бромоводородом;
в) с бромом;
г) с водой.
В каких случаях наряду с главным продуктом реакции образуется побочный?
Решение. №5 (с. 172)
Решение 2. №5 (с. 172)
Пропен ($CH_3-CH=CH_2$) является непредельным углеводородом из класса алкенов. Для него, как и для всех алкенов, характерны реакции присоединения по месту разрыва двойной связи.
а) с водородом
Реакция гидрирования (присоединения водорода) протекает в присутствии металлических катализаторов (например, Ni, Pt, Pd) при нагревании. В результате разрыва $\pi$-связи в молекуле пропена к каждому атому углерода, образующему двойную связь, присоединяется по одному атому водорода. Пропен превращается в соответствующий алкан — пропан. Побочные продукты в данной реакции не образуются.
$CH_3-CH=CH_2 + H_2 \xrightarrow{кат., t} CH_3-CH_2-CH_3$
Ответ: Пропан.
б) с бромоводородом
Реакция гидрогалогенирования (присоединения галогеноводорода). Пропен является несимметричным алкеном, так как атомы углерода при двойной связи соединены с разным числом атомов водорода ($CH_2$ и $CH$). Бромоводород ($HBr$) также является несимметричным реагентом. Присоединение таких реагентов к несимметричным алкенам происходит в соответствии с правилом Марковникова: атом водорода присоединяется к наиболее гидрированному атому углерода при двойной связи (в данном случае к $CH_2$), а атом галогена (брома) — к наименее гидрированному (к $CH$).
$CH_3-CH=CH_2 + HBr \rightarrow CH_3-CH(Br)-CH_3$
Основным продуктом реакции является 2-бромпропан. Однако, поскольку механизм реакции включает образование карбокатиона, наряду с более стабильным вторичным карбокатионом, который ведет к основному продукту, в небольшом количестве может образовываться и менее стабильный первичный карбокатион. Это приводит к образованию побочного продукта — 1-бромпропана.
Ответ: Основной продукт — 2-бромпропан, побочный продукт — 1-бромпропан.
в) с бромом
Реакция галогенирования (присоединения брома). Молекула брома ($Br_2$) является симметричным реагентом, поэтому ее присоединение к пропену происходит однозначно. Происходит разрыв двойной связи, и к каждому из атомов углерода присоединяется по одному атому брома. Эта реакция является качественной на двойную связь, так как приводит к обесцвечиванию бромной воды. Побочные продукты не образуются.
$CH_3-CH=CH_2 + Br_2 \rightarrow CH_3-CH(Br)-CH_2Br$
Ответ: 1,2-дибромпропан.
г) с водой
Реакция гидратации (присоединения воды) протекает в кислой среде (катализатор — $H_2SO_4$ или $H_3PO_4$) при нагревании. Вода ($H_2O$) является несимметричным реагентом, поэтому ее присоединение к несимметричному пропену также подчиняется правилу Марковникова. Атом водорода из молекулы воды присоединяется к более гидрированному атому углерода ($CH_2$), а гидроксогруппа ($OH$) — к менее гидрированному ($CH$).
$CH_3-CH=CH_2 + H_2O \xrightarrow{H^+, t} CH_3-CH(OH)-CH_3$
Основным продуктом является вторичный спирт — пропанол-2. Как и в случае с бромоводородом, возможно образование побочного продукта в результате присоединения против правила Марковникова. Таким продуктом является первичный спирт — пропанол-1.
Ответ: Основной продукт — пропанол-2, побочный продукт — пропанол-1.
Таким образом, образование побочного продукта наряду с главным происходит в случаях реакции пропена с бромоводородом (б) и с водой (г). Причиной этого является то, что при присоединении несимметричного реагента к несимметричному алкену реакция может идти по двум разным путям, один из которых (согласно правилу Марковникова) является преобладающим, а другой — менее вероятным, но все же возможным.
Другие задания:
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