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Номер 11, страница 172 - гдз по химии 10 класс учебник Еремин, Кузьменко
Авторы: Еремин В. В., Кузьменко Н. Е., Теренин В. И., Дроздов А. А., Лунин В. В.
Тип: Учебник
Издательство: Просвещение
Год издания: 2023 - 2026
Уровень обучения: углублённый
Цвет обложки: белый, зелёный с радугой
Допущено Министерством просвещения Российской Федерации
Популярные ГДЗ в 10 классе
Глава 3. Углеводороды. Параграф 29. Химические свойства алкенов - номер 11, страница 172.
App\Models\Task {#1024 // resources/views/models/task/default.blade.php #connection: "mysql" #table: "tasks" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:24 [ "id" => 663071 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_page_start" => "172" "field_page_end" => null "field_url" => "/10-klass/himiya/eremin-uchebnik/29-11" "field_display_title" => "11" "field_outside_task" => null "field_task_type" => Illuminate\Database\Eloquent\Collection {#331 #items: array:1 [ 0 => App\Models\Term {#1029 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:6 [ "id" => 26 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "номер" "field_cases" => array:6 [ "field_accusative_case" => "номер" "field_creative_case" => "номером" "field_dative_case" => "номеру" "field_genitive_case" => "номера" "field_nominative_case" => "номер" "field_prepositional_case" => "номере" ] "field_short_name" => "№" ] #original: array:6 [ "id" => 26 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "номер" "field_cases" => array:6 [ "field_accusative_case" => "номер" "field_creative_case" => "номером" "field_dative_case" => "номеру" "field_genitive_case" => "номера" "field_nominative_case" => "номер" "field_prepositional_case" => "номере" ] "field_short_name" => "№" ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "field_match" => null "breadcrumbs" => [] "edition_groups" => Illuminate\Database\Eloquent\Collection {#1026 #items: [] #escapeWhenCastingToString: false } "top_parent_branch" => Illuminate\Database\Eloquent\Collection {#342 #items: array:1 [ 0 => App\Models\Branch {#1023 #connection: "mysql" #table: "branches" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:24 [ "id" => 662723 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_display_title" => "Углеводороды" "field_branch_order" => "3" "field_url" => null "field_branch_type" => Illuminate\Database\Eloquent\Collection {#333 #items: array:1 [ 0 => App\Models\Term {#1033 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:7 [ "id" => 29 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Глава" "field_cases" => array:6 [ …6] "field_page_check_not_needed" => null "field_short_name" => null ] #original: array:7 [ "id" => 29 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Глава" "field_cases" => array:6 [ …6] "field_page_check_not_needed" => null "field_short_name" => null ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "field_page_start" => "139" "field_branch_display" => "0" "field_branch_expanded" => "0" "field_display_branch_in_title" => "1" "field_display_task_interval" => "0" "field_display_branch_page" => "1" "field_branch_title_in_content" => "0" "field_navigation_title" => null "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "field_branch_cover" => [] "field_branch_covers" => [] "book" => Illuminate\Database\Eloquent\Collection {#1030 #items: array:1 [ 0 => App\Models\Book {#1032 #connection: "mysql" #table: "books" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:50 [ "id" => 1003 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_tree_default_status" => "tasks" "field_pages_status" => null "field_subject" => Illuminate\Database\Eloquent\Collection {#1034 …2} "field_class" => Illuminate\Database\Eloquent\Collection {#1036 …2} "field_publisher" => Illuminate\Database\Eloquent\Collection {#1038 …2} "field_author" => Illuminate\Database\Eloquent\Collection {#1040 …2} "field_author_foreign" => Illuminate\Database\Eloquent\Collection {#1046 …2} "field_book_type" => Illuminate\Database\Eloquent\Collection {#1047 …2} "field_country" => Illuminate\Database\Eloquent\Collection {#1049 …2} "field_city" => Illuminate\Database\Eloquent\Collection {#1051 …2} "field_series" => Illuminate\Database\Eloquent\Collection {#1053 …2} "field_umk" => Illuminate\Database\Eloquent\Collection {#1054 …2} "field_level_of_education" => Illuminate\Database\Eloquent\Collection {#1055 …2} "field_standart_of_education" => Illuminate\Database\Eloquent\Collection {#1057 …2} "field_publication_number" => "10" "field_publication_type" => Illuminate\Database\Eloquent\Collection {#1059 …2} "field_under_the_edition" => Illuminate\Database\Eloquent\Collection {#1061 …2} "field_under_the_edition_degree" => "доктор химических наук, академика РАН" "field_cover_description" => "с радугой" "field_publication_year" => "2023" "field_publication_year_until" => null "field_part" => "" "field_part_writing" => "" "field_second_foreign_language" => null "field_for_whom" => null "field_allowed" => "Допущено Министерством просвещения Российской Федерации" "field_reserve_field" => null "field_link_to_source" => null "field_tasks_count" => "697" "field_priority" => "10" "field_default_folder" => "/himiya_10/eremin-u23/" "field_isbn" => null "field_cover" => array:1 [ …1] "field_cover_alts" => array:1 [ …1] "field_covers" => array:1 [ …1] "field_popular_book" => null "field_recommended_books" => Illuminate\Database\Eloquent\Collection {#1062 …2} "field_new_book" => Illuminate\Database\Eloquent\Collection {#1063 …2} "field_old_book" => Illuminate\Database\Eloquent\Collection {#1064 …2} "field_url" => "/10-klass/himiya/eremin-uchebnik" "field_cover_color" => Illuminate\Database\Eloquent\Collection {#1065 …2} "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "breadcrumbs" => array:3 [ …3] ] #original: array:50 [ "id" => 1003 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_tree_default_status" => "tasks" "field_pages_status" => null "field_subject" => Illuminate\Database\Eloquent\Collection {#1034 …2} "field_class" => Illuminate\Database\Eloquent\Collection {#1036 …2} "field_publisher" => Illuminate\Database\Eloquent\Collection {#1038 …2} "field_author" => Illuminate\Database\Eloquent\Collection {#1040 …2} "field_author_foreign" => Illuminate\Database\Eloquent\Collection {#1046 …2} "field_book_type" => Illuminate\Database\Eloquent\Collection {#1047 …2} "field_country" => Illuminate\Database\Eloquent\Collection {#1049 …2} "field_city" => Illuminate\Database\Eloquent\Collection {#1051 …2} "field_series" => Illuminate\Database\Eloquent\Collection {#1053 …2} "field_umk" => Illuminate\Database\Eloquent\Collection {#1054 …2} "field_level_of_education" => Illuminate\Database\Eloquent\Collection {#1055 …2} "field_standart_of_education" => Illuminate\Database\Eloquent\Collection {#1057 …2} "field_publication_number" => "10" "field_publication_type" => Illuminate\Database\Eloquent\Collection {#1059 …2} "field_under_the_edition" => Illuminate\Database\Eloquent\Collection {#1061 …2} "field_under_the_edition_degree" => "доктор химических наук, академика РАН" "field_cover_description" => "с радугой" "field_publication_year" => "2023" "field_publication_year_until" => null "field_part" => "" "field_part_writing" => "" "field_second_foreign_language" => null "field_for_whom" => null "field_allowed" => "Допущено Министерством просвещения Российской Федерации" "field_reserve_field" => null "field_link_to_source" => null "field_tasks_count" => "697" "field_priority" => "10" "field_default_folder" => "/himiya_10/eremin-u23/" "field_isbn" => null "field_cover" => array:1 [ …1] "field_cover_alts" => array:1 [ …1] "field_covers" => array:1 [ …1] "field_popular_book" => null "field_recommended_books" => Illuminate\Database\Eloquent\Collection {#1062 …2} "field_new_book" => Illuminate\Database\Eloquent\Collection {#1063 …2} "field_old_book" => Illuminate\Database\Eloquent\Collection {#1064 …2} "field_url" => "/10-klass/himiya/eremin-uchebnik" "field_cover_color" => Illuminate\Database\Eloquent\Collection {#1065 …2} "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "breadcrumbs" => array:3 [ …3] ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "branch_parent" => Illuminate\Database\Eloquent\Collection {#1068 #items: [] #escapeWhenCastingToString: false } ] #original: array:24 [ "id" => 662723 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_display_title" => "Углеводороды" "field_branch_order" => "3" "field_url" => null "field_branch_type" => Illuminate\Database\Eloquent\Collection {#333} "field_page_start" => "139" "field_branch_display" => "0" "field_branch_expanded" => "0" "field_display_branch_in_title" => "1" "field_display_task_interval" => "0" "field_display_branch_page" => "1" "field_branch_title_in_content" => "0" "field_navigation_title" => null "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "field_branch_cover" => [] "field_branch_covers" => [] "book" => Illuminate\Database\Eloquent\Collection {#1030} "branch_parent" => Illuminate\Database\Eloquent\Collection {#1068} ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "parent_branches" => Illuminate\Database\Eloquent\Collection {#1069 #items: array:2 [ 0 => App\Models\Branch {#1023} 1 => App\Models\Branch {#1070 #connection: "mysql" #table: "branches" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:24 [ "id" => 662729 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_display_title" => "Химические свойства алкенов" "field_branch_order" => "29" "field_url" => null "field_branch_type" => Illuminate\Database\Eloquent\Collection {#1071 #items: array:1 [ 0 => App\Models\Term {#1072 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:7 [ "id" => 32 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Параграф" "field_cases" => array:6 [ …6] "field_page_check_not_needed" => null "field_short_name" => "§" ] #original: array:7 [ "id" => 32 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Параграф" "field_cases" => array:6 [ …6] "field_page_check_not_needed" => null "field_short_name" => "§" ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "field_page_start" => "166" "field_branch_display" => "0" "field_branch_expanded" => "0" "field_display_branch_in_title" => "1" "field_display_task_interval" => "0" "field_display_branch_page" => "1" "field_branch_title_in_content" => "0" "field_navigation_title" => null "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "field_branch_cover" => [] "field_branch_covers" => [] "book" => Illuminate\Database\Eloquent\Collection {#1073 #items: array:1 [ 0 => App\Models\Book {#1074 #connection: "mysql" #table: "books" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:50 [ "id" => 1003 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_tree_default_status" => "tasks" "field_pages_status" => null "field_subject" => Illuminate\Database\Eloquent\Collection {#1075 …2} "field_class" => Illuminate\Database\Eloquent\Collection {#1077 …2} "field_publisher" => Illuminate\Database\Eloquent\Collection {#1079 …2} "field_author" => Illuminate\Database\Eloquent\Collection {#1081 …2} "field_author_foreign" => Illuminate\Database\Eloquent\Collection {#1087 …2} "field_book_type" => Illuminate\Database\Eloquent\Collection {#1088 …2} "field_country" => Illuminate\Database\Eloquent\Collection {#1090 …2} "field_city" => Illuminate\Database\Eloquent\Collection {#1092 …2} "field_series" => Illuminate\Database\Eloquent\Collection {#1094 …2} "field_umk" => Illuminate\Database\Eloquent\Collection {#1095 …2} "field_level_of_education" => Illuminate\Database\Eloquent\Collection {#1096 …2} "field_standart_of_education" => Illuminate\Database\Eloquent\Collection {#1098 …2} "field_publication_number" => "10" "field_publication_type" => Illuminate\Database\Eloquent\Collection {#1100 …2} "field_under_the_edition" => Illuminate\Database\Eloquent\Collection {#1102 …2} "field_under_the_edition_degree" => "доктор химических наук, академика РАН" "field_cover_description" => "с радугой" "field_publication_year" => "2023" "field_publication_year_until" => null "field_part" => "" "field_part_writing" => "" "field_second_foreign_language" => null "field_for_whom" => null "field_allowed" => "Допущено Министерством просвещения Российской Федерации" "field_reserve_field" => null "field_link_to_source" => null "field_tasks_count" => "697" "field_priority" => "10" "field_default_folder" => "/himiya_10/eremin-u23/" "field_isbn" => null "field_cover" => array:1 [ …1] "field_cover_alts" => array:1 [ …1] "field_covers" => array:1 [ …1] "field_popular_book" => null "field_recommended_books" => Illuminate\Database\Eloquent\Collection {#1103 …2} "field_new_book" => Illuminate\Database\Eloquent\Collection {#1104 …2} "field_old_book" => Illuminate\Database\Eloquent\Collection {#1105 …2} "field_url" => "/10-klass/himiya/eremin-uchebnik" "field_cover_color" => Illuminate\Database\Eloquent\Collection {#1106 …2} "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "breadcrumbs" => array:3 [ …3] ] #original: array:50 [ "id" => 1003 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_tree_default_status" => "tasks" "field_pages_status" => null "field_subject" => Illuminate\Database\Eloquent\Collection {#1075 …2} "field_class" => Illuminate\Database\Eloquent\Collection {#1077 …2} "field_publisher" => Illuminate\Database\Eloquent\Collection {#1079 …2} "field_author" => Illuminate\Database\Eloquent\Collection {#1081 …2} "field_author_foreign" => Illuminate\Database\Eloquent\Collection {#1087 …2} "field_book_type" => Illuminate\Database\Eloquent\Collection {#1088 …2} "field_country" => Illuminate\Database\Eloquent\Collection {#1090 …2} "field_city" => Illuminate\Database\Eloquent\Collection {#1092 …2} "field_series" => Illuminate\Database\Eloquent\Collection {#1094 …2} "field_umk" => Illuminate\Database\Eloquent\Collection {#1095 …2} "field_level_of_education" => Illuminate\Database\Eloquent\Collection {#1096 …2} "field_standart_of_education" => Illuminate\Database\Eloquent\Collection {#1098 …2} "field_publication_number" => "10" "field_publication_type" => Illuminate\Database\Eloquent\Collection {#1100 …2} "field_under_the_edition" => Illuminate\Database\Eloquent\Collection {#1102 …2} "field_under_the_edition_degree" => "доктор химических наук, академика РАН" "field_cover_description" => "с радугой" "field_publication_year" => "2023" "field_publication_year_until" => null "field_part" => "" "field_part_writing" => "" "field_second_foreign_language" => null "field_for_whom" => null "field_allowed" => "Допущено Министерством просвещения Российской Федерации" "field_reserve_field" => null "field_link_to_source" => null "field_tasks_count" => "697" "field_priority" => "10" "field_default_folder" => "/himiya_10/eremin-u23/" "field_isbn" => null "field_cover" => array:1 [ …1] "field_cover_alts" => array:1 [ …1] "field_covers" => array:1 [ …1] "field_popular_book" => null "field_recommended_books" => Illuminate\Database\Eloquent\Collection {#1103 …2} "field_new_book" => Illuminate\Database\Eloquent\Collection {#1104 …2} "field_old_book" => Illuminate\Database\Eloquent\Collection {#1105 …2} "field_url" => "/10-klass/himiya/eremin-uchebnik" "field_cover_color" => Illuminate\Database\Eloquent\Collection {#1106 …2} "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "breadcrumbs" => array:3 [ …3] ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "branch_parent" => Illuminate\Database\Eloquent\Collection {#1109 #items: array:1 [ 0 => App\Models\Branch {#1110 #connection: "mysql" #table: "branches" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:24 [ "id" => 662723 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_display_title" => "Углеводороды" "field_branch_order" => "3" "field_url" => null "field_branch_type" => Illuminate\Database\Eloquent\Collection {#1111 …2} "field_page_start" => "139" "field_branch_display" => "0" "field_branch_expanded" => "0" "field_display_branch_in_title" => "1" "field_display_task_interval" => "0" "field_display_branch_page" => "1" "field_branch_title_in_content" => "0" "field_navigation_title" => null "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "field_branch_cover" => [] "field_branch_covers" => [] "book" => Illuminate\Database\Eloquent\Collection {#1113 …2} "branch_parent" => Illuminate\Database\Eloquent\Collection {#1114 …2} ] #original: array:24 [ "id" => 662723 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_display_title" => "Углеводороды" "field_branch_order" => "3" "field_url" => null "field_branch_type" => Illuminate\Database\Eloquent\Collection {#1111 …2} "field_page_start" => "139" "field_branch_display" => "0" "field_branch_expanded" => "0" "field_display_branch_in_title" => "1" "field_display_task_interval" => "0" "field_display_branch_page" => "1" "field_branch_title_in_content" => "0" "field_navigation_title" => null "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "field_branch_cover" => [] "field_branch_covers" => [] "book" => Illuminate\Database\Eloquent\Collection {#1113 …2} "branch_parent" => Illuminate\Database\Eloquent\Collection {#1114 …2} ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } ] #original: array:24 [ "id" => 662729 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_display_title" => "Химические свойства алкенов" "field_branch_order" => "29" "field_url" => null "field_branch_type" => Illuminate\Database\Eloquent\Collection {#1071} "field_page_start" => "166" "field_branch_display" => "0" "field_branch_expanded" => "0" "field_display_branch_in_title" => "1" "field_display_task_interval" => "0" "field_display_branch_page" => "1" "field_branch_title_in_content" => "0" "field_navigation_title" => null "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "field_branch_cover" => [] "field_branch_covers" => [] "book" => Illuminate\Database\Eloquent\Collection {#1073} "branch_parent" => Illuminate\Database\Eloquent\Collection {#1109} ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "content" => Illuminate\Database\Eloquent\Collection {#1115 #items: array:3 [ 0 => App\Models\Element {#1116 #connection: "mysql" #table: "elements" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:7 [ "id" => 818672 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "edition" => Illuminate\Database\Eloquent\Collection {#1117 #items: array:1 [ 0 => App\Models\Edition {#1118 #connection: "mysql" #table: "editions" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:21 [ "id" => 1829 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "title" => "Условие" "field_order" => "1" "field_publisher" => Illuminate\Database\Eloquent\Collection {#1119 …2} "field_content_type" => "free" "field_content_mode" => "text, image" "field_page_content_mode" => "image" "field_content_text_checked" => null "field_page_content_text_checked" => "0" "field_solution_author" => "Автор" "field_moderator" => "vadim" "field_edition_type" => "statement" "field_root_dir" => "0-" "field_responsible" => Illuminate\Database\Eloquent\Collection {#1121 …2} "field_comment" => null "field_similar_book" => Illuminate\Database\Eloquent\Collection {#1122 …2} "field_process_formula" => "katex" "field_edition_group" => Illuminate\Database\Eloquent\Collection {#1123 …2} "field_content_source" => null ] #original: array:21 [ "id" => 1829 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "title" => "Условие" "field_order" => "1" "field_publisher" => Illuminate\Database\Eloquent\Collection {#1119 …2} "field_content_type" => "free" "field_content_mode" => "text, image" "field_page_content_mode" => "image" "field_content_text_checked" => null "field_page_content_text_checked" => "0" "field_solution_author" => "Автор" "field_moderator" => "vadim" "field_edition_type" => "statement" "field_root_dir" => "0-" "field_responsible" => Illuminate\Database\Eloquent\Collection {#1121 …2} "field_comment" => null "field_similar_book" => Illuminate\Database\Eloquent\Collection {#1122 …2} "field_process_formula" => "katex" "field_edition_group" => Illuminate\Database\Eloquent\Collection {#1123 …2} "field_content_source" => null ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "task" => array:2 [ "refs" => "663071" "type" => "task" ] "text" => "<p><strong>11.</strong> Запишите полные уравнения реакций окисления бутена-1 и бутена-2 горячим подкисленным раствором перманганата калия.</p>" "img" => array:1 [ 0 => array:5 [ "name" => "11-1.jpg" "alt" => null "width" => "852" "height" => 99 "path" => "/media/himiya_10/eremin-u23/0-29/11-1.webp?ts=1738779554" ] ] ] #original: array:7 [ "id" => 818672 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "edition" => Illuminate\Database\Eloquent\Collection {#1117} "task" => array:2 [ "refs" => "663071" "type" => "task" ] "text" => "<p><strong>11.</strong> Запишите полные уравнения реакций окисления бутена-1 и бутена-2 горячим подкисленным раствором перманганата калия.</p>" "img" => array:1 [ 0 => array:5 [ "name" => "11-1.jpg" "alt" => null "width" => "852" "height" => 99 "path" => "/media/himiya_10/eremin-u23/0-29/11-1.webp?ts=1738779554" ] ] ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } 1 => App\Models\Element {#1124 #connection: "mysql" #table: "elements" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:6 [ "id" => 818886 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "edition" => Illuminate\Database\Eloquent\Collection {#1125 #items: array:1 [ 0 => App\Models\Edition {#1126 #connection: "mysql" #table: "editions" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:21 [ "id" => 1830 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "title" => "Решение" "field_order" => "2" "field_publisher" => Illuminate\Database\Eloquent\Collection {#1127 …2} "field_content_type" => "free" "field_content_mode" => "image" "field_page_content_mode" => "" "field_content_text_checked" => "0" "field_page_content_text_checked" => "0" "field_solution_author" => "Ладыко (Торчило)" "field_moderator" => "vadim" "field_edition_type" => "solution" "field_root_dir" => "1-" "field_responsible" => Illuminate\Database\Eloquent\Collection {#1129 …2} "field_comment" => null "field_similar_book" => Illuminate\Database\Eloquent\Collection {#1130 …2} "field_process_formula" => "" "field_edition_group" => Illuminate\Database\Eloquent\Collection {#1131 …2} "field_content_source" => null ] #original: array:21 [ "id" => 1830 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "title" => "Решение" "field_order" => "2" "field_publisher" => Illuminate\Database\Eloquent\Collection {#1127 …2} "field_content_type" => "free" "field_content_mode" => "image" "field_page_content_mode" => "" "field_content_text_checked" => "0" "field_page_content_text_checked" => "0" "field_solution_author" => "Ладыко (Торчило)" "field_moderator" => "vadim" "field_edition_type" => "solution" "field_root_dir" => "1-" "field_responsible" => Illuminate\Database\Eloquent\Collection {#1129 …2} "field_comment" => null "field_similar_book" => Illuminate\Database\Eloquent\Collection {#1130 …2} "field_process_formula" => "" "field_edition_group" => Illuminate\Database\Eloquent\Collection {#1131 …2} "field_content_source" => null ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "task" => array:2 [ "refs" => "663071" "type" => "task" ] "img" => array:1 [ 0 => array:5 [ "name" => "11-1.jpg" "alt" => null "width" => "2046" "height" => 580 "path" => "/media/himiya_10/eremin-u23/1-29/11-1.webp?ts=1738779623" ] ] ] #original: array:6 [ "id" => 818886 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "edition" => Illuminate\Database\Eloquent\Collection {#1125} "task" => array:2 [ "refs" => "663071" "type" => "task" ] "img" => array:1 [ 0 => array:5 [ "name" => "11-1.jpg" "alt" => null "width" => "2046" "height" => 580 "path" => "/media/himiya_10/eremin-u23/1-29/11-1.webp?ts=1738779623" ] ] ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } 2 => App\Models\Element {#1132 #connection: "mysql" #table: "elements" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:6 [ "id" => 1515475 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "edition" => Illuminate\Database\Eloquent\Collection {#1133 #items: array:1 [ 0 => App\Models\Edition {#1134 #connection: "mysql" #table: "editions" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:21 [ "id" => 5553 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "title" => "Решение 2" "field_order" => "3" "field_publisher" => Illuminate\Database\Eloquent\Collection {#1135 …2} "field_content_type" => "free" "field_content_mode" => "text" "field_page_content_mode" => "" "field_content_text_checked" => null "field_page_content_text_checked" => "0" "field_solution_author" => "Gemini 2.5 Pro" "field_moderator" => "tolik" "field_edition_type" => "solution" "field_root_dir" => "2-" "field_responsible" => Illuminate\Database\Eloquent\Collection {#1137 …2} "field_comment" => null "field_similar_book" => Illuminate\Database\Eloquent\Collection {#1138 …2} "field_process_formula" => "katex" "field_edition_group" => Illuminate\Database\Eloquent\Collection {#1139 …2} "field_content_source" => null ] #original: array:21 [ "id" => 5553 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "title" => "Решение 2" "field_order" => "3" "field_publisher" => Illuminate\Database\Eloquent\Collection {#1135 …2} "field_content_type" => "free" "field_content_mode" => "text" "field_page_content_mode" => "" "field_content_text_checked" => null "field_page_content_text_checked" => "0" "field_solution_author" => "Gemini 2.5 Pro" "field_moderator" => "tolik" "field_edition_type" => "solution" "field_root_dir" => "2-" "field_responsible" => Illuminate\Database\Eloquent\Collection {#1137 …2} "field_comment" => null "field_similar_book" => Illuminate\Database\Eloquent\Collection {#1138 …2} "field_process_formula" => "katex" "field_edition_group" => Illuminate\Database\Eloquent\Collection {#1139 …2} "field_content_source" => null ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "task" => array:2 [ "refs" => "663071" "type" => "task" ] "text" => "<p><strong>Окисление бутена-1</strong></p><p><strong>Решение</strong></p><p>Окисление алкенов горячим подкисленным раствором перманганата калия ($KMnO_4$) является реакцией жёсткого окисления, которая приводит к разрыву двойной углерод-углеродной связи. Характер продуктов зависит от строения алкена.</p><p>Бутен-1 имеет структурную формулу $CH_2=CH-CH_2-CH_3$. Двойная связь находится у первого атома углерода. При разрыве этой связи концевой фрагмент $=CH_2$ (первичный атом углерода при двойной связи) окисляется до углекислого газа $CO_2$, а фрагмент $=CH-CH_2-CH_3$ (вторичный атом углерода при двойной связи) окисляется по месту разрыва до карбоксильной группы $-COOH$, образуя пропановую (пропионовую) кислоту $CH_3-CH_2-COOH$.</p><p>В качестве подкисляющей среды обычно используют серную кислоту ($H_2SO_4$). В кислой среде перманганат-ион ($MnO_4^-$), в котором марганец имеет степень окисления +7, восстанавливается до иона марганца(II) ($Mn^{2+}$).</p><p>Для нахождения коэффициентов в уравнении реакции используем метод электронного баланса:<br>Восстановитель (бутен-1):<br>$C^{-2}H_2=C^{-1}H-R \rightarrow C^{+4}O_2 + R-C^{+3}OOH$<br>$C^{-2} - 6e^- \rightarrow C^{+4}$<br>$C^{-1} - 4e^- \rightarrow C^{+3}$<br>Суммарно молекула бутена-1 отдает 10 электронов.<br>Окислитель (перманганат калия):<br>$Mn^{+7} + 5e^- \rightarrow Mn^{+2}$<br>Наименьшее общее кратное для 10 и 5 равно 10. Таким образом, на 1 моль бутена-1 требуется 2 моля перманганата калия. Исходя из этого и уравнивая остальные элементы (K, S, H, O), получаем полное уравнение реакции.</p><p><strong>Ответ:</strong> $CH_2=CH-CH_2-CH_3 + 2KMnO_4 + 3H_2SO_4 \rightarrow CH_3CH_2COOH + CO_2 \uparrow + K_2SO_4 + 2MnSO_4 + 4H_2O$.</p><p><strong>Окисление бутена-2</strong></p><p><strong>Решение</strong></p><p>Бутен-2 имеет структурную формулу $CH_3-CH=CH-CH_3$. Это симметричный алкен, у которого двойная связь находится в середине цепи. Оба атома углерода при двойной связи являются вторичными.</p><p>При жёстком окислении происходит разрыв двойной связи, и каждый из двух фрагментов $CH_3-CH=$ окисляется до уксусной (этановой) кислоты $CH_3-COOH$. Таким образом, из одной молекулы бутена-2 образуются две молекулы уксусной кислоты.</p><p>Используем метод электронного баланса для расстановки коэффициентов:<br>Восстановитель (бутен-2):<br>$R-C^{-1}H=C^{-1}H-R \rightarrow 2 R-C^{+3}OOH$<br>Каждый из двух атомов углерода при двойной связи отдает 4 электрона ($C^{-1} - 4e^- \rightarrow C^{+3}$). Суммарно молекула бутена-2 отдает $2 \times 4 = 8$ электронов.<br>Окислитель (перманганат калия):<br>$Mn^{+7} + 5e^- \rightarrow Mn^{+2}$<br>Наименьшее общее кратное для 8 и 5 равно 40. Коэффициент перед бутеном-2 будет $40/8=5$, а перед перманганатом калия — $40/5=8$. Уравниваем остальные вещества в уравнении.</p><p><strong>Ответ:</strong> $5CH_3-CH=CH-CH_3 + 8KMnO_4 + 12H_2SO_4 \rightarrow 10CH_3COOH + 4K_2SO_4 + 8MnSO_4 + 12H_2O$.</p>" ] #original: array:6 [ "id" => 1515475 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "edition" => Illuminate\Database\Eloquent\Collection {#1133} "task" => array:2 [ "refs" => "663071" "type" => "task" ] "text" => "<p><strong>Окисление бутена-1</strong></p><p><strong>Решение</strong></p><p>Окисление алкенов горячим подкисленным раствором перманганата калия ($KMnO_4$) является реакцией жёсткого окисления, которая приводит к разрыву двойной углерод-углеродной связи. Характер продуктов зависит от строения алкена.</p><p>Бутен-1 имеет структурную формулу $CH_2=CH-CH_2-CH_3$. Двойная связь находится у первого атома углерода. При разрыве этой связи концевой фрагмент $=CH_2$ (первичный атом углерода при двойной связи) окисляется до углекислого газа $CO_2$, а фрагмент $=CH-CH_2-CH_3$ (вторичный атом углерода при двойной связи) окисляется по месту разрыва до карбоксильной группы $-COOH$, образуя пропановую (пропионовую) кислоту $CH_3-CH_2-COOH$.</p><p>В качестве подкисляющей среды обычно используют серную кислоту ($H_2SO_4$). В кислой среде перманганат-ион ($MnO_4^-$), в котором марганец имеет степень окисления +7, восстанавливается до иона марганца(II) ($Mn^{2+}$).</p><p>Для нахождения коэффициентов в уравнении реакции используем метод электронного баланса:<br>Восстановитель (бутен-1):<br>$C^{-2}H_2=C^{-1}H-R \rightarrow C^{+4}O_2 + R-C^{+3}OOH$<br>$C^{-2} - 6e^- \rightarrow C^{+4}$<br>$C^{-1} - 4e^- \rightarrow C^{+3}$<br>Суммарно молекула бутена-1 отдает 10 электронов.<br>Окислитель (перманганат калия):<br>$Mn^{+7} + 5e^- \rightarrow Mn^{+2}$<br>Наименьшее общее кратное для 10 и 5 равно 10. Таким образом, на 1 моль бутена-1 требуется 2 моля перманганата калия. Исходя из этого и уравнивая остальные элементы (K, S, H, O), получаем полное уравнение реакции.</p><p><strong>Ответ:</strong> $CH_2=CH-CH_2-CH_3 + 2KMnO_4 + 3H_2SO_4 \rightarrow CH_3CH_2COOH + CO_2 \uparrow + K_2SO_4 + 2MnSO_4 + 4H_2O$.</p><p><strong>Окисление бутена-2</strong></p><p><strong>Решение</strong></p><p>Бутен-2 имеет структурную формулу $CH_3-CH=CH-CH_3$. Это симметричный алкен, у которого двойная связь находится в середине цепи. Оба атома углерода при двойной связи являются вторичными.</p><p>При жёстком окислении происходит разрыв двойной связи, и каждый из двух фрагментов $CH_3-CH=$ окисляется до уксусной (этановой) кислоты $CH_3-COOH$. Таким образом, из одной молекулы бутена-2 образуются две молекулы уксусной кислоты.</p><p>Используем метод электронного баланса для расстановки коэффициентов:<br>Восстановитель (бутен-2):<br>$R-C^{-1}H=C^{-1}H-R \rightarrow 2 R-C^{+3}OOH$<br>Каждый из двух атомов углерода при двойной связи отдает 4 электрона ($C^{-1} - 4e^- \rightarrow C^{+3}$). Суммарно молекула бутена-2 отдает $2 \times 4 = 8$ электронов.<br>Окислитель (перманганат калия):<br>$Mn^{+7} + 5e^- \rightarrow Mn^{+2}$<br>Наименьшее общее кратное для 8 и 5 равно 40. Коэффициент перед бутеном-2 будет $40/8=5$, а перед перманганатом калия — $40/5=8$. Уравниваем остальные вещества в уравнении.</p><p><strong>Ответ:</strong> $5CH_3-CH=CH-CH_3 + 8KMnO_4 + 12H_2SO_4 \rightarrow 10CH_3COOH + 4K_2SO_4 + 8MnSO_4 + 12H_2O$.</p>" ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "next" => array:2 [ "refs" => "663072" "type" => "task" ] "previous" => array:2 [ "refs" => "663070" "type" => "task" ] "book" => Illuminate\Database\Eloquent\Collection {#1140 #items: array:1 [ 0 => App\Models\Book {#1141 #connection: "mysql" #table: "books" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:50 [ "id" => 1003 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_tree_default_status" => "tasks" "field_pages_status" => null "field_subject" => Illuminate\Database\Eloquent\Collection {#1142 #items: array:1 [ 0 => App\Models\Term {#1143 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:10 [ "id" => 6495 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Химия" "field_abbreviated_name" => null "field_cases" => array:6 [ …6] "field_foreign_lang_name" => null "field_short_name" => null "field_subject_type" => "technical_subject" "field_translit" => "himiya" ] #original: array:10 [ "id" => 6495 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Химия" "field_abbreviated_name" => null "field_cases" => array:6 [ …6] "field_foreign_lang_name" => null "field_short_name" => null "field_subject_type" => "technical_subject" "field_translit" => "himiya" ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "field_class" => Illuminate\Database\Eloquent\Collection {#1144 #items: array:1 [ 0 => App\Models\Term {#1145 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:6 [ "id" => 5459 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "10" "field_cases" => array:6 [ …6] "field_translit" => "desjatyj" ] #original: array:6 [ "id" => 5459 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "10" "field_cases" => array:6 [ …6] "field_translit" => "desjatyj" ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "field_publisher" => Illuminate\Database\Eloquent\Collection {#1146 #items: array:1 [ 0 => App\Models\Term {#1147 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:6 [ "id" => 5153 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Просвещение" "field_cases" => null "field_translit" => "prosveschenie" ] #original: array:6 [ "id" => 5153 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Просвещение" "field_cases" => null "field_translit" => "prosveschenie" ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "field_author" => Illuminate\Database\Eloquent\Collection {#1148 #items: array:5 [ 0 => App\Models\Term {#1149 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:12 [ "id" => 4330 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Еремин" "field_bio" => null "field_degree_rp" => null "field_foreign_lang_name" => null "field_foreign_lang_patronymic" => null "field_foreign_lang_surname" => null "field_name" => "Вадим" "field_patronymic" => "Владимирович" "field_surname_rp" => null ] #original: array:12 [ "id" => 4330 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Еремин" "field_bio" => null "field_degree_rp" => null "field_foreign_lang_name" => null "field_foreign_lang_patronymic" => null "field_foreign_lang_surname" => null "field_name" => "Вадим" "field_patronymic" => "Владимирович" "field_surname_rp" => null ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } 1 => App\Models\Term {#1150 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:12 [ "id" => 4876 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Кузьменко" "field_bio" => null "field_degree_rp" => null "field_foreign_lang_name" => null "field_foreign_lang_patronymic" => null "field_foreign_lang_surname" => null "field_name" => "Николай" "field_patronymic" => "Егорович" "field_surname_rp" => null ] #original: array:12 [ "id" => 4876 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Кузьменко" "field_bio" => null "field_degree_rp" => null "field_foreign_lang_name" => null …5 ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } 2 => App\Models\Term {#1151 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:12 [ …12] #original: array:12 [ …12] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } 3 => App\Models\Term {#1152 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:12 [ …12] #original: array:12 [ …12] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } 4 => App\Models\Term {#1153 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:12 [ …12] #original: array:12 [ …12] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } ] #escapeWhenCastingToString: false } "field_author_foreign" => Illuminate\Database\Eloquent\Collection {#1154 #items: [] #escapeWhenCastingToString: false } "field_book_type" => Illuminate\Database\Eloquent\Collection {#1155 #items: array:1 [ 0 => App\Models\Term {#1156 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:10 [ …10] #original: array:10 [ …10] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } ] #escapeWhenCastingToString: false } "field_country" => Illuminate\Database\Eloquent\Collection {#1157 #items: array:1 [ 0 => App\Models\Term {#1158 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:6 [ …6] #original: array:6 [ …6] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } ] #escapeWhenCastingToString: false } "field_city" => Illuminate\Database\Eloquent\Collection {#1159 #items: array:1 [ 0 => App\Models\Term {#1160 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:6 [ …6] #original: array:6 [ …6] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } ] #escapeWhenCastingToString: false } "field_series" => Illuminate\Database\Eloquent\Collection {#1161 #items: [] #escapeWhenCastingToString: false } "field_umk" => Illuminate\Database\Eloquent\Collection {#1162 #items: [] #escapeWhenCastingToString: false } "field_level_of_education" => Illuminate\Database\Eloquent\Collection {#1163 #items: array:1 [ 0 => App\Models\Term {#1164 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:6 [ …6] #original: array:6 [ …6] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } ] #escapeWhenCastingToString: false } "field_standart_of_education" => Illuminate\Database\Eloquent\Collection {#1165 #items: array:1 [ 0 => App\Models\Term {#1166 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:10 [ …10] #original: array:10 [ …10] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } ] #escapeWhenCastingToString: false } "field_publication_number" => "10" "field_publication_type" => Illuminate\Database\Eloquent\Collection {#1167 #items: array:1 [ 0 => App\Models\Term {#1168 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:6 [ …6] #original: array:6 [ …6] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } ] #escapeWhenCastingToString: false } "field_under_the_edition" => Illuminate\Database\Eloquent\Collection {#1169 #items: array:1 [ 0 => App\Models\Term {#1153} ] #escapeWhenCastingToString: false } "field_under_the_edition_degree" => "доктор химических наук, академика РАН" "field_cover_description" => "с радугой" "field_publication_year" => "2023" "field_publication_year_until" => null "field_part" => "" "field_part_writing" => "" "field_second_foreign_language" => null "field_for_whom" => null "field_allowed" => "Допущено Министерством просвещения Российской Федерации" "field_reserve_field" => null "field_link_to_source" => null "field_tasks_count" => "697" "field_priority" => "10" "field_default_folder" => "/himiya_10/eremin-u23/" "field_isbn" => null "field_cover" => array:1 [ 0 => "/media/himiya_10/eremin-u23/covers/cover1.webp?ts=1738768732" ] "field_cover_alts" => array:1 [ 0 => "" ] "field_covers" => array:1 [ 0 => array:4 [ "path" => "/media/himiya_10/eremin-u23/covers/cover1.webp?ts=1738768732" "alt" => "" "width" => "1200" "height" => "1576" ] ] "field_popular_book" => null "field_recommended_books" => Illuminate\Database\Eloquent\Collection {#1170 #items: [] #escapeWhenCastingToString: false } "field_new_book" => Illuminate\Database\Eloquent\Collection {#1171 #items: [] #escapeWhenCastingToString: false } "field_old_book" => Illuminate\Database\Eloquent\Collection {#1172 #items: [] #escapeWhenCastingToString: false } "field_url" => "/10-klass/himiya/eremin-uchebnik" "field_cover_color" => Illuminate\Database\Eloquent\Collection {#1173 #items: array:2 [ 0 => App\Models\Term {#1174 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:6 [ …6] #original: array:6 [ …6] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } 1 => App\Models\Term {#1175 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:6 [ …6] #original: array:6 [ …6] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } ] #escapeWhenCastingToString: false } "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "breadcrumbs" => array:3 [ "class" => 381 "subject" => 558 "class_subject" => 500 ] ] #original: array:50 [ "id" => 1003 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_tree_default_status" => "tasks" "field_pages_status" => null "field_subject" => Illuminate\Database\Eloquent\Collection {#1142} "field_class" => Illuminate\Database\Eloquent\Collection {#1144} "field_publisher" => Illuminate\Database\Eloquent\Collection {#1146} "field_author" => Illuminate\Database\Eloquent\Collection {#1148} "field_author_foreign" => Illuminate\Database\Eloquent\Collection {#1154} "field_book_type" => Illuminate\Database\Eloquent\Collection {#1155} "field_country" => Illuminate\Database\Eloquent\Collection {#1157} "field_city" => Illuminate\Database\Eloquent\Collection {#1159} "field_series" => Illuminate\Database\Eloquent\Collection {#1161} "field_umk" => Illuminate\Database\Eloquent\Collection {#1162} "field_level_of_education" => Illuminate\Database\Eloquent\Collection {#1163} "field_standart_of_education" => Illuminate\Database\Eloquent\Collection {#1165} "field_publication_number" => "10" "field_publication_type" => Illuminate\Database\Eloquent\Collection {#1167} "field_under_the_edition" => Illuminate\Database\Eloquent\Collection {#1169} "field_under_the_edition_degree" => "доктор химических наук, академика РАН" "field_cover_description" => "с радугой" "field_publication_year" => "2023" "field_publication_year_until" => null "field_part" => "" "field_part_writing" => "" "field_second_foreign_language" => null "field_for_whom" => null "field_allowed" => "Допущено Министерством просвещения Российской Федерации" "field_reserve_field" => null "field_link_to_source" => null "field_tasks_count" => "697" "field_priority" => "10" "field_default_folder" => "/himiya_10/eremin-u23/" "field_isbn" => null "field_cover" => array:1 [ 0 => "/media/himiya_10/eremin-u23/covers/cover1.webp?ts=1738768732" ] "field_cover_alts" => array:1 [ 0 => "" ] "field_covers" => array:1 [ 0 => array:4 [ "path" => "/media/himiya_10/eremin-u23/covers/cover1.webp?ts=1738768732" "alt" => "" "width" => "1200" "height" => "1576" ] ] "field_popular_book" => null "field_recommended_books" => Illuminate\Database\Eloquent\Collection {#1170} "field_new_book" => Illuminate\Database\Eloquent\Collection {#1171} "field_old_book" => Illuminate\Database\Eloquent\Collection {#1172} "field_url" => "/10-klass/himiya/eremin-uchebnik" "field_cover_color" => Illuminate\Database\Eloquent\Collection {#1173} "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "breadcrumbs" => array:3 [ "class" => 381 "subject" => 558 "class_subject" => 500 ] ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "page" => Illuminate\Database\Eloquent\Collection {#1190 #items: array:1 [ 0 => App\Models\BookPage {#1189 #connection: "mysql" #table: "book_pages" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:21 [ "id" => 926068 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_page_start" => "172" "field_url" => "/10-klass/himiya/eremin-uchebnik/page-172" "field_display_title" => "172" "field_folder" => "1" "field_image_name" => "172" "field_branch_parent" => Illuminate\Database\Eloquent\Collection {#1191 #items: [] #escapeWhenCastingToString: false } "field_weight" => "0" "field_book_parent" => Illuminate\Database\Eloquent\Collection {#1229 #items: array:1 [ 0 => App\Models\Book {#1192 #connection: "mysql" #table: "books" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:50 [ …50] #original: array:50 [ …50] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } ] #escapeWhenCastingToString: false } "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "edition_groups" => Illuminate\Database\Eloquent\Collection {#1227 #items: [] #escapeWhenCastingToString: false } "content" => Illuminate\Database\Eloquent\Collection {#1238 #items: array:1 [ 0 => App\Models\Element {#1237 #connection: "mysql" #table: "elements" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:6 [ …6] #original: array:6 [ …6] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } ] #escapeWhenCastingToString: false } "next" => array:2 [ "refs" => "926069" "type" => "book_page" ] "previous" => array:2 [ "refs" => "926067" "type" => "book_page" ] "tasks" => Illuminate\Database\Eloquent\Collection {#1737 #items: array:14 [ 0 => App\Models\Task {#1757 #connection: "mysql" #table: "tasks" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:24 [ …24] #original: array:24 [ …24] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } 1 => App\Models\Task {#1888 #connection: "mysql" #table: "tasks" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:24 [ …24] #original: array:24 [ …24] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } 2 => App\Models\Task {#1894 #connection: "mysql" #table: "tasks" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:24 [ …24] #original: array:24 [ …24] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } 3 => App\Models\Task {#1920 #connection: "mysql" #table: "tasks" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:24 [ …24] #original: array:24 [ …24] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } 4 => App\Models\Task {#1934 #connection: "mysql" #table: "tasks" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:24 [ …24] #original: array:24 [ …24] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } 5 => App\Models\Task {#1945 #connection: "mysql" #table: "tasks" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:24 [ …24] #original: array:24 [ …24] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } 6 => App\Models\Task {#1959 #connection: "mysql" #table: "tasks" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:24 [ …24] #original: array:24 [ …24] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } 7 => App\Models\Task {#1973 #connection: "mysql" #table: "tasks" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:24 [ …24] #original: array:24 [ …24] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } 8 => App\Models\Task {#1990 #connection: "mysql" #table: "tasks" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:24 [ …24] #original: array:24 [ …24] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } 9 => App\Models\Task {#2004 #connection: "mysql" #table: "tasks" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:24 [ …24] #original: array:24 [ …24] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } 10 => App\Models\Task {#2018 #connection: "mysql" #table: "tasks" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:24 [ …24] #original: array:24 [ …24] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } 11 => App\Models\Task {#2029 #connection: "mysql" #table: "tasks" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:24 [ …24] #original: array:24 [ …24] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } 12 => App\Models\Task {#2051 #connection: "mysql" #table: "tasks" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:24 [ …24] #original: array:24 [ …24] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } 13 => App\Models\Task {#2055 #connection: "mysql" #table: "tasks" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:24 [ …24] #original: array:24 [ …24] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } ] #escapeWhenCastingToString: false } ] #original: array:21 [ "id" => 926068 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_page_start" => "172" "field_url" => "/10-klass/himiya/eremin-uchebnik/page-172" "field_display_title" => "172" "field_folder" => "1" "field_image_name" => "172" "field_branch_parent" => Illuminate\Database\Eloquent\Collection {#1191} "field_weight" => "0" "field_book_parent" => Illuminate\Database\Eloquent\Collection {#1229} "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "edition_groups" => Illuminate\Database\Eloquent\Collection {#1227} "content" => Illuminate\Database\Eloquent\Collection {#1238} "next" => array:2 [ "refs" => "926069" "type" => "book_page" ] "previous" => array:2 [ "refs" => "926067" "type" => "book_page" ] "tasks" => Illuminate\Database\Eloquent\Collection {#1737} ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } ] #original: array:24 [ "id" => 663071 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_page_start" => "172" "field_page_end" => null "field_url" => "/10-klass/himiya/eremin-uchebnik/29-11" "field_display_title" => "11" "field_outside_task" => null "field_task_type" => Illuminate\Database\Eloquent\Collection {#331} "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "field_match" => null "breadcrumbs" => [] "edition_groups" => Illuminate\Database\Eloquent\Collection {#1026} "top_parent_branch" => Illuminate\Database\Eloquent\Collection {#342} "parent_branches" => Illuminate\Database\Eloquent\Collection {#1069} "content" => Illuminate\Database\Eloquent\Collection {#1115} "next" => array:2 [ "refs" => "663072" "type" => "task" ] "previous" => array:2 [ "refs" => "663070" "type" => "task" ] "book" => Illuminate\Database\Eloquent\Collection {#1140} "page" => array:2 [ "refs" => "926068" "type" => "book_page" ] ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] }
№11 (с. 172)
Условие. №11 (с. 172)
скриншот условия
11. Запишите полные уравнения реакций окисления бутена-1 и бутена-2 горячим подкисленным раствором перманганата калия.
Решение. №11 (с. 172)
Решение 2. №11 (с. 172)
Окисление бутена-1
Решение
Окисление алкенов горячим подкисленным раствором перманганата калия ($KMnO_4$) является реакцией жёсткого окисления, которая приводит к разрыву двойной углерод-углеродной связи. Характер продуктов зависит от строения алкена.
Бутен-1 имеет структурную формулу $CH_2=CH-CH_2-CH_3$. Двойная связь находится у первого атома углерода. При разрыве этой связи концевой фрагмент $=CH_2$ (первичный атом углерода при двойной связи) окисляется до углекислого газа $CO_2$, а фрагмент $=CH-CH_2-CH_3$ (вторичный атом углерода при двойной связи) окисляется по месту разрыва до карбоксильной группы $-COOH$, образуя пропановую (пропионовую) кислоту $CH_3-CH_2-COOH$.
В качестве подкисляющей среды обычно используют серную кислоту ($H_2SO_4$). В кислой среде перманганат-ион ($MnO_4^-$), в котором марганец имеет степень окисления +7, восстанавливается до иона марганца(II) ($Mn^{2+}$).
Для нахождения коэффициентов в уравнении реакции используем метод электронного баланса:
Восстановитель (бутен-1):
$C^{-2}H_2=C^{-1}H-R \rightarrow C^{+4}O_2 + R-C^{+3}OOH$
$C^{-2} - 6e^- \rightarrow C^{+4}$
$C^{-1} - 4e^- \rightarrow C^{+3}$
Суммарно молекула бутена-1 отдает 10 электронов.
Окислитель (перманганат калия):
$Mn^{+7} + 5e^- \rightarrow Mn^{+2}$
Наименьшее общее кратное для 10 и 5 равно 10. Таким образом, на 1 моль бутена-1 требуется 2 моля перманганата калия. Исходя из этого и уравнивая остальные элементы (K, S, H, O), получаем полное уравнение реакции.
Ответ: $CH_2=CH-CH_2-CH_3 + 2KMnO_4 + 3H_2SO_4 \rightarrow CH_3CH_2COOH + CO_2 \uparrow + K_2SO_4 + 2MnSO_4 + 4H_2O$.
Окисление бутена-2
Решение
Бутен-2 имеет структурную формулу $CH_3-CH=CH-CH_3$. Это симметричный алкен, у которого двойная связь находится в середине цепи. Оба атома углерода при двойной связи являются вторичными.
При жёстком окислении происходит разрыв двойной связи, и каждый из двух фрагментов $CH_3-CH=$ окисляется до уксусной (этановой) кислоты $CH_3-COOH$. Таким образом, из одной молекулы бутена-2 образуются две молекулы уксусной кислоты.
Используем метод электронного баланса для расстановки коэффициентов:
Восстановитель (бутен-2):
$R-C^{-1}H=C^{-1}H-R \rightarrow 2 R-C^{+3}OOH$
Каждый из двух атомов углерода при двойной связи отдает 4 электрона ($C^{-1} - 4e^- \rightarrow C^{+3}$). Суммарно молекула бутена-2 отдает $2 \times 4 = 8$ электронов.
Окислитель (перманганат калия):
$Mn^{+7} + 5e^- \rightarrow Mn^{+2}$
Наименьшее общее кратное для 8 и 5 равно 40. Коэффициент перед бутеном-2 будет $40/8=5$, а перед перманганатом калия — $40/5=8$. Уравниваем остальные вещества в уравнении.
Ответ: $5CH_3-CH=CH-CH_3 + 8KMnO_4 + 12H_2SO_4 \rightarrow 10CH_3COOH + 4K_2SO_4 + 8MnSO_4 + 12H_2O$.
Другие задания:
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