Номер 4, страница 177 - гдз по химии 10 класс учебник Еремин, Кузьменко

Химия, 10 класс Учебник, авторы: Еремин Вадим Владимирович, Кузьменко Николай Егорович, Теренин Владимир Ильич, Дроздов Андрей Анатольевич, Лунин Валерий Васильевич, издательство Просвещение, Москва, 2023, белого цвета

Авторы: Еремин В. В., Кузьменко Н. Е., Теренин В. И., Дроздов А. А., Лунин В. В.

Тип: Учебник

Издательство: Просвещение

Год издания: 2023 - 2026

Уровень обучения: углублённый

Цвет обложки: белый, зелёный с радугой

Допущено Министерством просвещения Российской Федерации

Глава 3. Углеводороды. Параграф 30. Получение и применение алкенов - номер 4, страница 177.

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                    "field_publication_number" => "10"
                    "field_publication_type" => Illuminate\Database\Eloquent\Collection {#1108 …2}
                    "field_under_the_edition" => Illuminate\Database\Eloquent\Collection {#1110 …2}
                    "field_under_the_edition_degree" => "доктор химических наук, академика РАН"
                    "field_cover_description" => "с радугой"
                    "field_publication_year" => "2023"
                    "field_publication_year_until" => null
                    "field_part" => ""
                    "field_part_writing" => ""
                    "field_second_foreign_language" => null
                    "field_for_whom" => null
                    "field_allowed" => "Допущено Министерством просвещения Российской Федерации"
                    "field_reserve_field" => null
                    "field_link_to_source" => null
                    "field_tasks_count" => "697"
                    "field_priority" => "10"
                    "field_default_folder" => "/himiya_10/eremin-u23/"
                    "field_isbn" => null
                    "field_cover" => array:1 [ …1]
                    "field_cover_alts" => array:1 [ …1]
                    "field_covers" => array:1 [ …1]
                    "field_popular_book" => null
                    "field_recommended_books" => Illuminate\Database\Eloquent\Collection {#1111 …2}
                    "field_new_book" => Illuminate\Database\Eloquent\Collection {#1112 …2}
                    "field_old_book" => Illuminate\Database\Eloquent\Collection {#1113 …2}
                    "field_url" => "/10-klass/himiya/eremin-uchebnik"
                    "field_cover_color" => Illuminate\Database\Eloquent\Collection {#1114 …2}
                    "field_metatags_title" => null
                    "field_metatags_description" => null
                    "field_h1" => null
                    "field_description_top" => null
                    "field_description_bottom" => null
                    "breadcrumbs" => array:3 [ …3]
                  ]
                  #changes: []
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                  #classCastCache: []
                  #attributeCastCache: []
                  #dateFormat: null
                  #appends: []
                  #dispatchesEvents: []
                  #observables: []
                  #relations: []
                  #touches: []
                  +timestamps: true
                  +usesUniqueIds: false
                  #hidden: []
                  #visible: []
                  #fillable: []
                  #guarded: array:1 [
                    0 => "*"
                  ]
                }
              ]
              #escapeWhenCastingToString: false
            }
            "branch_parent" => Illuminate\Database\Eloquent\Collection {#1117
              #items: []
              #escapeWhenCastingToString: false
            }
          ]
          #original: array:24 [
            "id" => 662723
            "created_at" => "2026-04-10 13:58:26"
            "updated_at" => null
            "field_display_title" => "Углеводороды"
            "field_branch_order" => "3"
            "field_url" => null
            "field_branch_type" => Illuminate\Database\Eloquent\Collection {#1080}
            "field_page_start" => "139"
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            "field_branch_covers" => []
            "book" => Illuminate\Database\Eloquent\Collection {#1081}
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            0 => "*"
          ]
        }
        1 => App\Models\Branch {#1118
          #connection: "mysql"
          #table: "branches"
          #primaryKey: "id"
          #keyType: "int"
          +incrementing: true
          #with: []
          #withCount: []
          +preventsLazyLoading: false
          #perPage: 15
          +exists: true
          +wasRecentlyCreated: false
          #escapeWhenCastingToString: false
          #attributes: array:24 [
            "id" => 662730
            "created_at" => "2026-04-10 13:58:26"
            "updated_at" => null
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            "field_branch_order" => "30"
            "field_url" => null
            "field_branch_type" => Illuminate\Database\Eloquent\Collection {#1119
              #items: array:1 [
                0 => App\Models\Term {#1120
                  #connection: "mysql"
                  #table: "terms"
                  #primaryKey: "id"
                  #keyType: "int"
                  +incrementing: false
                  #with: []
                  #withCount: []
                  +preventsLazyLoading: false
                  #perPage: 15
                  +exists: true
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                  #escapeWhenCastingToString: false
                  #attributes: array:7 [
                    "id" => 32
                    "created_at" => "2026-04-10 13:58:26"
                    "updated_at" => null
                    "name" => "Параграф"
                    "field_cases" => array:6 [ …6]
                    "field_page_check_not_needed" => null
                    "field_short_name" => "§"
                  ]
                  #original: array:7 [
                    "id" => 32
                    "created_at" => "2026-04-10 13:58:26"
                    "updated_at" => null
                    "name" => "Параграф"
                    "field_cases" => array:6 [ …6]
                    "field_page_check_not_needed" => null
                    "field_short_name" => "§"
                  ]
                  #changes: []
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                  #classCastCache: []
                  #attributeCastCache: []
                  #dateFormat: null
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                  #visible: []
                  #fillable: []
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                    0 => "*"
                  ]
                }
              ]
              #escapeWhenCastingToString: false
            }
            "field_page_start" => "172"
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            "field_branch_covers" => []
            "book" => Illuminate\Database\Eloquent\Collection {#1121
              #items: array:1 [
                0 => App\Models\Book {#1122
                  #connection: "mysql"
                  #table: "books"
                  #primaryKey: "id"
                  #keyType: "int"
                  +incrementing: false
                  #with: []
                  #withCount: []
                  +preventsLazyLoading: false
                  #perPage: 15
                  +exists: true
                  +wasRecentlyCreated: false
                  #escapeWhenCastingToString: false
                  #attributes: array:50 [
                    "id" => 1003
                    "created_at" => "2026-04-10 13:58:26"
                    "updated_at" => null
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                    "field_subject" => Illuminate\Database\Eloquent\Collection {#1123 …2}
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                    "field_publisher" => Illuminate\Database\Eloquent\Collection {#1127 …2}
                    "field_author" => Illuminate\Database\Eloquent\Collection {#1129 …2}
                    "field_author_foreign" => Illuminate\Database\Eloquent\Collection {#1135 …2}
                    "field_book_type" => Illuminate\Database\Eloquent\Collection {#1136 …2}
                    "field_country" => Illuminate\Database\Eloquent\Collection {#1138 …2}
                    "field_city" => Illuminate\Database\Eloquent\Collection {#1140 …2}
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                    "field_level_of_education" => Illuminate\Database\Eloquent\Collection {#1144 …2}
                    "field_standart_of_education" => Illuminate\Database\Eloquent\Collection {#1146 …2}
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                    "field_under_the_edition" => Illuminate\Database\Eloquent\Collection {#1150 …2}
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                    "field_cover_description" => "с радугой"
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                    "field_cover" => array:1 [ …1]
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                    "field_cover_color" => Illuminate\Database\Eloquent\Collection {#1154 …2}
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                    "breadcrumbs" => array:3 [ …3]
                  ]
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                    "field_subject" => Illuminate\Database\Eloquent\Collection {#1123 …2}
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                    "field_author_foreign" => Illuminate\Database\Eloquent\Collection {#1135 …2}
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                    "field_country" => Illuminate\Database\Eloquent\Collection {#1138 …2}
                    "field_city" => Illuminate\Database\Eloquent\Collection {#1140 …2}
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                    "field_standart_of_education" => Illuminate\Database\Eloquent\Collection {#1146 …2}
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                    "field_part" => ""
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                    "field_allowed" => "Допущено Министерством просвещения Российской Федерации"
                    "field_reserve_field" => null
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                    "field_tasks_count" => "697"
                    "field_priority" => "10"
                    "field_default_folder" => "/himiya_10/eremin-u23/"
                    "field_isbn" => null
                    "field_cover" => array:1 [ …1]
                    "field_cover_alts" => array:1 [ …1]
                    "field_covers" => array:1 [ …1]
                    "field_popular_book" => null
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                    "field_metatags_title" => null
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                    "breadcrumbs" => array:3 [ …3]
                  ]
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                }
              ]
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            "branch_parent" => Illuminate\Database\Eloquent\Collection {#1157
              #items: array:1 [
                0 => App\Models\Branch {#1158
                  #connection: "mysql"
                  #table: "branches"
                  #primaryKey: "id"
                  #keyType: "int"
                  +incrementing: true
                  #with: []
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                  #attributes: array:24 [
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                    "field_branch_type" => Illuminate\Database\Eloquent\Collection {#1159 …2}
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                    "field_branch_cover" => []
                    "field_branch_covers" => []
                    "book" => Illuminate\Database\Eloquent\Collection {#1161 …2}
                    "branch_parent" => Illuminate\Database\Eloquent\Collection {#1197 …2}
                  ]
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                    "id" => 662723
                    "created_at" => "2026-04-10 13:58:26"
                    "updated_at" => null
                    "field_display_title" => "Углеводороды"
                    "field_branch_order" => "3"
                    "field_url" => null
                    "field_branch_type" => Illuminate\Database\Eloquent\Collection {#1159 …2}
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                    "book" => Illuminate\Database\Eloquent\Collection {#1161 …2}
                    "branch_parent" => Illuminate\Database\Eloquent\Collection {#1197 …2}
                  ]
                  #changes: []
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                  #attributeCastCache: []
                  #dateFormat: null
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                  #touches: []
                  +timestamps: true
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                  #hidden: []
                  #visible: []
                  #fillable: []
                  #guarded: array:1 [
                    0 => "*"
                  ]
                }
              ]
              #escapeWhenCastingToString: false
            }
          ]
          #original: array:24 [
            "id" => 662730
            "created_at" => "2026-04-10 13:58:26"
            "updated_at" => null
            "field_display_title" => "Получение и применение алкенов"
            "field_branch_order" => "30"
            "field_url" => null
            "field_branch_type" => Illuminate\Database\Eloquent\Collection {#1119}
            "field_page_start" => "172"
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            "field_h1" => null
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            "field_branch_covers" => []
            "book" => Illuminate\Database\Eloquent\Collection {#1121}
            "branch_parent" => Illuminate\Database\Eloquent\Collection {#1157}
          ]
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          +timestamps: true
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            0 => "*"
          ]
        }
      ]
      #escapeWhenCastingToString: false
    }
    "content" => Illuminate\Database\Eloquent\Collection {#1224
      #items: array:3 [
        0 => App\Models\Element {#1200
          #connection: "mysql"
          #table: "elements"
          #primaryKey: "id"
          #keyType: "int"
          +incrementing: true
          #with: []
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          #attributes: array:7 [
            "id" => 818687
            "created_at" => "2026-04-10 13:58:26"
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            "edition" => Illuminate\Database\Eloquent\Collection {#1201
              #items: array:1 [
                0 => App\Models\Edition {#1199
                  #connection: "mysql"
                  #table: "editions"
                  #primaryKey: "id"
                  #keyType: "int"
                  +incrementing: false
                  #with: []
                  #withCount: []
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                  #attributes: array:21 [
                    "id" => 1829
                    "created_at" => "2026-04-10 13:58:26"
                    "updated_at" => null
                    "title" => "Условие"
                    "field_order" => "1"
                    "field_publisher" => Illuminate\Database\Eloquent\Collection {#1202 …2}
                    "field_content_type" => "free"
                    "field_content_mode" => "text, image"
                    "field_page_content_mode" => "image"
                    "field_content_text_checked" => null
                    "field_page_content_text_checked" => "0"
                    "field_solution_author" => "Автор"
                    "field_moderator" => "vadim"
                    "field_edition_type" => "statement"
                    "field_root_dir" => "0-"
                    "field_responsible" => Illuminate\Database\Eloquent\Collection {#1204 …2}
                    "field_comment" => null
                    "field_similar_book" => Illuminate\Database\Eloquent\Collection {#1205 …2}
                    "field_process_formula" => "katex"
                    "field_edition_group" => Illuminate\Database\Eloquent\Collection {#1206 …2}
                    "field_content_source" => null
                  ]
                  #original: array:21 [
                    "id" => 1829
                    "created_at" => "2026-04-10 13:58:26"
                    "updated_at" => null
                    "title" => "Условие"
                    "field_order" => "1"
                    "field_publisher" => Illuminate\Database\Eloquent\Collection {#1202 …2}
                    "field_content_type" => "free"
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                    "field_edition_group" => Illuminate\Database\Eloquent\Collection {#1206 …2}
                    "field_content_source" => null
                  ]
                  #changes: []
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                    0 => "*"
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                }
              ]
              #escapeWhenCastingToString: false
            }
            "task" => array:2 [
              "refs" => "663078"
              "type" => "task"
            ]
            "text" => "<p><strong>4.</strong> Дегидрирование этана — обратимый эндотермический процесс.</p><p>Напишите уравнение этого процесса и объясните, как можно сместить равновесие в сторону образования этилена.</p>"
            "img" => array:1 [
              0 => array:5 [
                "name" => "4-1.jpg"
                "alt" => null
                "width" => "846"
                "height" => 128
                "path" => "/media/himiya_10/eremin-u23/0-30/4-1.webp?ts=1738779554"
              ]
            ]
          ]
          #original: array:7 [
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            "created_at" => "2026-04-10 13:58:26"
            "updated_at" => null
            "edition" => Illuminate\Database\Eloquent\Collection {#1201}
            "task" => array:2 [
              "refs" => "663078"
              "type" => "task"
            ]
            "text" => "<p><strong>4.</strong> Дегидрирование этана — обратимый эндотермический процесс.</p><p>Напишите уравнение этого процесса и объясните, как можно сместить равновесие в сторону образования этилена.</p>"
            "img" => array:1 [
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                "path" => "/media/himiya_10/eremin-u23/0-30/4-1.webp?ts=1738779554"
              ]
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          +timestamps: true
          +usesUniqueIds: false
          #hidden: []
          #visible: []
          #fillable: []
          #guarded: array:1 [
            0 => "*"
          ]
        }
        1 => App\Models\Element {#1207
          #connection: "mysql"
          #table: "elements"
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          #keyType: "int"
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          #with: []
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          #attributes: array:6 [
            "id" => 818901
            "created_at" => "2026-04-10 13:58:26"
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            "edition" => Illuminate\Database\Eloquent\Collection {#1208
              #items: array:1 [
                0 => App\Models\Edition {#1209
                  #connection: "mysql"
                  #table: "editions"
                  #primaryKey: "id"
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                  +exists: true
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                  #attributes: array:21 [
                    "id" => 1830
                    "created_at" => "2026-04-10 13:58:26"
                    "updated_at" => null
                    "title" => "Решение"
                    "field_order" => "2"
                    "field_publisher" => Illuminate\Database\Eloquent\Collection {#1210 …2}
                    "field_content_type" => "free"
                    "field_content_mode" => "image"
                    "field_page_content_mode" => ""
                    "field_content_text_checked" => "0"
                    "field_page_content_text_checked" => "0"
                    "field_solution_author" => "Ладыко (Торчило)"
                    "field_moderator" => "vadim"
                    "field_edition_type" => "solution"
                    "field_root_dir" => "1-"
                    "field_responsible" => Illuminate\Database\Eloquent\Collection {#1212 …2}
                    "field_comment" => null
                    "field_similar_book" => Illuminate\Database\Eloquent\Collection {#1213 …2}
                    "field_process_formula" => ""
                    "field_edition_group" => Illuminate\Database\Eloquent\Collection {#1214 …2}
                    "field_content_source" => null
                  ]
                  #original: array:21 [
                    "id" => 1830
                    "created_at" => "2026-04-10 13:58:26"
                    "updated_at" => null
                    "title" => "Решение"
                    "field_order" => "2"
                    "field_publisher" => Illuminate\Database\Eloquent\Collection {#1210 …2}
                    "field_content_type" => "free"
                    "field_content_mode" => "image"
                    "field_page_content_mode" => ""
                    "field_content_text_checked" => "0"
                    "field_page_content_text_checked" => "0"
                    "field_solution_author" => "Ладыко (Торчило)"
                    "field_moderator" => "vadim"
                    "field_edition_type" => "solution"
                    "field_root_dir" => "1-"
                    "field_responsible" => Illuminate\Database\Eloquent\Collection {#1212 …2}
                    "field_comment" => null
                     …4
                  ]
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                  +timestamps: true
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                  #hidden: []
                  #visible: []
                  #fillable: []
                  #guarded: array:1 [ …1]
                }
              ]
              #escapeWhenCastingToString: false
            }
            "task" => array:2 [
              "refs" => "663078"
              "type" => "task"
            ]
            "img" => array:1 [
              0 => array:5 [
                "name" => "4-1.jpg"
                "alt" => null
                "width" => "2042"
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                "path" => "/media/himiya_10/eremin-u23/1-30/4-1.webp?ts=1738779623"
              ]
            ]
          ]
          #original: array:6 [
            "id" => 818901
            "created_at" => "2026-04-10 13:58:26"
            "updated_at" => null
            "edition" => Illuminate\Database\Eloquent\Collection {#1208}
            "task" => array:2 [
              "refs" => "663078"
              "type" => "task"
            ]
            "img" => array:1 [
              0 => array:5 [
                "name" => "4-1.jpg"
                "alt" => null
                "width" => "2042"
                "height" => 449
                "path" => "/media/himiya_10/eremin-u23/1-30/4-1.webp?ts=1738779623"
              ]
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          ]
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          #guarded: array:1 [
            0 => "*"
          ]
        }
        2 => App\Models\Element {#1215
          #connection: "mysql"
          #table: "elements"
          #primaryKey: "id"
          #keyType: "int"
          +incrementing: true
          #with: []
          #withCount: []
          +preventsLazyLoading: false
          #perPage: 15
          +exists: true
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          #escapeWhenCastingToString: false
          #attributes: array:6 [
            "id" => 1515482
            "created_at" => "2026-04-10 13:58:26"
            "updated_at" => null
            "edition" => Illuminate\Database\Eloquent\Collection {#1216
              #items: array:1 [
                0 => App\Models\Edition {#1217
                  #connection: "mysql"
                  #table: "editions"
                  #primaryKey: "id"
                  #keyType: "int"
                  +incrementing: false
                  #with: []
                  #withCount: []
                  +preventsLazyLoading: false
                  #perPage: 15
                  +exists: true
                  +wasRecentlyCreated: false
                  #escapeWhenCastingToString: false
                  #attributes: array:21 [ …21]
                  #original: array:21 [ …21]
                  #changes: []
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                  +timestamps: true
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                  #hidden: []
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                  #guarded: array:1 [ …1]
                }
              ]
              #escapeWhenCastingToString: false
            }
            "task" => array:2 [
              "refs" => "663078"
              "type" => "task"
            ]
            "text" => "<p><strong>Решение</strong></p><p>Дегидрирование этана — это процесс отщепления молекулы водорода от молекулы этана с образованием этилена (этена). Это обратимый химический процесс.</p><p>Уравнение этого процесса выглядит следующим образом:<br>$C_2H_6(г) \rightleftarrows C_2H_4(г) + H_2(г)$</p><p>Смещение химического равновесия подчиняется принципу Ле Шателье: если на систему, находящуюся в состоянии равновесия, оказывается внешнее воздействие, то равновесие смещается в направлении, которое ослабляет это воздействие. Чтобы сместить равновесие в сторону образования этилена (вправо), необходимо изменить условия реакции.</p><p><strong>Повышение температуры.</strong> В условии сказано, что процесс является эндотермическим, то есть прямая реакция ($C_2H_6 \rightarrow C_2H_4 + H_2$) протекает с поглощением теплоты ($ \Delta H &gt; 0 $). Согласно принципу Ле Шателье, повышение температуры смещает равновесие в сторону эндотермической реакции. Таким образом, для увеличения выхода этилена необходимо повышать температуру.</p><p><strong>Понижение давления.</strong> Проанализируем изменение количества газообразных веществ. В левой части уравнения находится 1 моль газа ($C_2H_6$), а в правой — 2 моль газов ($C_2H_4$ и $H_2$). Прямая реакция идёт с увеличением числа молей газов. Понижение давления в системе смещает равновесие в сторону образования большего количества молей газов. Следовательно, понижение давления будет способствовать смещению равновесия вправо, в сторону образования этилена.</p><p><strong>Изменение концентраций.</strong> Для смещения равновесия в сторону продуктов реакции (вправо) можно:<br>- Увеличить концентрацию исходного вещества — этана ($C_2H_6$).<br>- Уменьшать концентрацию продуктов реакции — этилена ($C_2H_4$) и/или водорода ($H_2$), например, путем их постоянного отвода из реакционной зоны.</p><p>Использование катализатора (например, $Ni, Pt, Cr_2O_3$) не смещает равновесие, но ускоряет его достижение.</p><p><strong>Ответ:</strong> Уравнение процесса дегидрирования этана: $C_2H_6 \rightleftarrows C_2H_4 + H_2$. Для смещения равновесия в сторону образования этилена необходимо повышать температуру, понижать давление, а также увеличивать концентрацию исходного этана или удалять образующиеся этилен и водород из системы.</p>"
          ]
          #original: array:6 [
            "id" => 1515482
            "created_at" => "2026-04-10 13:58:26"
            "updated_at" => null
            "edition" => Illuminate\Database\Eloquent\Collection {#1216}
            "task" => array:2 [
              "refs" => "663078"
              "type" => "task"
            ]
            "text" => "<p><strong>Решение</strong></p><p>Дегидрирование этана — это процесс отщепления молекулы водорода от молекулы этана с образованием этилена (этена). Это обратимый химический процесс.</p><p>Уравнение этого процесса выглядит следующим образом:<br>$C_2H_6(г) \rightleftarrows C_2H_4(г) + H_2(г)$</p><p>Смещение химического равновесия подчиняется принципу Ле Шателье: если на систему, находящуюся в состоянии равновесия, оказывается внешнее воздействие, то равновесие смещается в направлении, которое ослабляет это воздействие. Чтобы сместить равновесие в сторону образования этилена (вправо), необходимо изменить условия реакции.</p><p><strong>Повышение температуры.</strong> В условии сказано, что процесс является эндотермическим, то есть прямая реакция ($C_2H_6 \rightarrow C_2H_4 + H_2$) протекает с поглощением теплоты ($ \Delta H &gt; 0 $). Согласно принципу Ле Шателье, повышение температуры смещает равновесие в сторону эндотермической реакции. Таким образом, для увеличения выхода этилена необходимо повышать температуру.</p><p><strong>Понижение давления.</strong> Проанализируем изменение количества газообразных веществ. В левой части уравнения находится 1 моль газа ($C_2H_6$), а в правой — 2 моль газов ($C_2H_4$ и $H_2$). Прямая реакция идёт с увеличением числа молей газов. Понижение давления в системе смещает равновесие в сторону образования большего количества молей газов. Следовательно, понижение давления будет способствовать смещению равновесия вправо, в сторону образования этилена.</p><p><strong>Изменение концентраций.</strong> Для смещения равновесия в сторону продуктов реакции (вправо) можно:<br>- Увеличить концентрацию исходного вещества — этана ($C_2H_6$).<br>- Уменьшать концентрацию продуктов реакции — этилена ($C_2H_4$) и/или водорода ($H_2$), например, путем их постоянного отвода из реакционной зоны.</p><p>Использование катализатора (например, $Ni, Pt, Cr_2O_3$) не смещает равновесие, но ускоряет его достижение.</p><p><strong>Ответ:</strong> Уравнение процесса дегидрирования этана: $C_2H_6 \rightleftarrows C_2H_4 + H_2$. Для смещения равновесия в сторону образования этилена необходимо повышать температуру, понижать давление, а также увеличивать концентрацию исходного этана или удалять образующиеся этилен и водород из системы.</p>"
          ]
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    "book" => Illuminate\Database\Eloquent\Collection {#1261
      #items: array:1 [
        0 => App\Models\Book {#1225
          #connection: "mysql"
          #table: "books"
          #primaryKey: "id"
          #keyType: "int"
          +incrementing: false
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          #perPage: 15
          +exists: true
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          #attributes: array:50 [
            "id" => 1003
            "created_at" => "2026-04-10 13:58:26"
            "updated_at" => null
            "field_tree_default_status" => "tasks"
            "field_pages_status" => null
            "field_subject" => Illuminate\Database\Eloquent\Collection {#1226
              #items: array:1 [
                0 => App\Models\Term {#1223
                  #connection: "mysql"
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                  #attributes: array:10 [ …10]
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                }
              ]
              #escapeWhenCastingToString: false
            }
            "field_class" => Illuminate\Database\Eloquent\Collection {#1227
              #items: array:1 [
                0 => App\Models\Term {#1228
                  #connection: "mysql"
                  #table: "terms"
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                  #keyType: "int"
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                  #withCount: []
                  +preventsLazyLoading: false
                  #perPage: 15
                  +exists: true
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                  #escapeWhenCastingToString: false
                  #attributes: array:6 [ …6]
                  #original: array:6 [ …6]
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                  +timestamps: true
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                  #hidden: []
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                  #guarded: array:1 [ …1]
                }
              ]
              #escapeWhenCastingToString: false
            }
            "field_publisher" => Illuminate\Database\Eloquent\Collection {#1229
              #items: array:1 [
                0 => App\Models\Term {#1230
                  #connection: "mysql"
                  #table: "terms"
                  #primaryKey: "id"
                  #keyType: "int"
                  +incrementing: false
                  #with: []
                  #withCount: []
                  +preventsLazyLoading: false
                  #perPage: 15
                  +exists: true
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                  #escapeWhenCastingToString: false
                  #attributes: array:6 [ …6]
                  #original: array:6 [ …6]
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                  #guarded: array:1 [ …1]
                }
              ]
              #escapeWhenCastingToString: false
            }
            "field_author" => Illuminate\Database\Eloquent\Collection {#1231
              #items: array:5 [
                0 => App\Models\Term {#1232
                  #connection: "mysql"
                  #table: "terms"
                  #primaryKey: "id"
                  #keyType: "int"
                  +incrementing: false
                  #with: []
                  #withCount: []
                  +preventsLazyLoading: false
                  #perPage: 15
                  +exists: true
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                  #escapeWhenCastingToString: false
                  #attributes: array:12 [ …12]
                  #original: array:12 [ …12]
                  #changes: []
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                  +timestamps: true
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                  #hidden: []
                  #visible: []
                  #fillable: []
                  #guarded: array:1 [ …1]
                }
                1 => App\Models\Term {#1233
                  #connection: "mysql"
                  #table: "terms"
                  #primaryKey: "id"
                  #keyType: "int"
                  +incrementing: false
                  #with: []
                  #withCount: []
                  +preventsLazyLoading: false
                  #perPage: 15
                  +exists: true
                  +wasRecentlyCreated: false
                  #escapeWhenCastingToString: false
                  #attributes: array:12 [ …12]
                  #original: array:12 [ …12]
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                  +timestamps: true
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                  #hidden: []
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                  #fillable: []
                  #guarded: array:1 [ …1]
                }
                2 => App\Models\Term {#1234
                  #connection: "mysql"
                  #table: "terms"
                  #primaryKey: "id"
                  #keyType: "int"
                  +incrementing: false
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                  #withCount: []
                  +preventsLazyLoading: false
                  #perPage: 15
                  +exists: true
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                  #escapeWhenCastingToString: false
                  #attributes: array:12 [ …12]
                  #original: array:12 [ …12]
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                  +timestamps: true
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                  #hidden: []
                  #visible: []
                  #fillable: []
                  #guarded: array:1 [ …1]
                }
                3 => App\Models\Term {#1235
                  #connection: "mysql"
                  #table: "terms"
                  #primaryKey: "id"
                  #keyType: "int"
                  +incrementing: false
                  #with: []
                  #withCount: []
                  +preventsLazyLoading: false
                  #perPage: 15
                  +exists: true
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                  #escapeWhenCastingToString: false
                  #attributes: array:12 [ …12]
                  #original: array:12 [ …12]
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                  +timestamps: true
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                  #hidden: []
                  #visible: []
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                  #guarded: array:1 [ …1]
                }
                4 => App\Models\Term {#1236
                  #connection: "mysql"
                  #table: "terms"
                  #primaryKey: "id"
                  #keyType: "int"
                  +incrementing: false
                  #with: []
                  #withCount: []
                  +preventsLazyLoading: false
                  #perPage: 15
                  +exists: true
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                  #attributes: array:12 [ …12]
                  #original: array:12 [ …12]
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                  #hidden: []
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                  #guarded: array:1 [ …1]
                }
              ]
              #escapeWhenCastingToString: false
            }
            "field_author_foreign" => Illuminate\Database\Eloquent\Collection {#1237
              #items: []
              #escapeWhenCastingToString: false
            }
            "field_book_type" => Illuminate\Database\Eloquent\Collection {#1238
              #items: array:1 [
                0 => App\Models\Term {#1239
                  #connection: "mysql"
                  #table: "terms"
                  #primaryKey: "id"
                  #keyType: "int"
                  +incrementing: false
                  #with: []
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                  #perPage: 15
                  +exists: true
                  +wasRecentlyCreated: false
                  #escapeWhenCastingToString: false
                  #attributes: array:10 [ …10]
                  #original: array:10 [ …10]
                  #changes: []
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                  #classCastCache: []
                  #attributeCastCache: []
                  #dateFormat: null
                  #appends: []
                  #dispatchesEvents: []
                  #observables: []
                  #relations: []
                  #touches: []
                  +timestamps: true
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                  #hidden: []
                  #visible: []
                  #fillable: []
                  #guarded: array:1 [ …1]
                }
              ]
              #escapeWhenCastingToString: false
            }
            "field_country" => Illuminate\Database\Eloquent\Collection {#1240
              #items: array:1 [
                0 => App\Models\Term {#1241
                  #connection: "mysql"
                  #table: "terms"
                  #primaryKey: "id"
                  #keyType: "int"
                  +incrementing: false
                  #with: []
                  #withCount: []
                  +preventsLazyLoading: false
                  #perPage: 15
                  +exists: true
                  +wasRecentlyCreated: false
                  #escapeWhenCastingToString: false
                  #attributes: array:6 [ …6]
                  #original: array:6 [ …6]
                  #changes: []
                  #casts: []
                  #classCastCache: []
                  #attributeCastCache: []
                  #dateFormat: null
                  #appends: []
                  #dispatchesEvents: []
                  #observables: []
                  #relations: []
                  #touches: []
                  +timestamps: true
                  +usesUniqueIds: false
                  #hidden: []
                  #visible: []
                  #fillable: []
                  #guarded: array:1 [ …1]
                }
              ]
              #escapeWhenCastingToString: false
            }
            "field_city" => Illuminate\Database\Eloquent\Collection {#1242
              #items: array:1 [
                0 => App\Models\Term {#1243
                  #connection: "mysql"
                  #table: "terms"
                  #primaryKey: "id"
                  #keyType: "int"
                  +incrementing: false
                  #with: []
                  #withCount: []
                  +preventsLazyLoading: false
                  #perPage: 15
                  +exists: true
                  +wasRecentlyCreated: false
                  #escapeWhenCastingToString: false
                  #attributes: array:6 [ …6]
                  #original: array:6 [ …6]
                  #changes: []
                  #casts: []
                  #classCastCache: []
                  #attributeCastCache: []
                  #dateFormat: null
                  #appends: []
                  #dispatchesEvents: []
                  #observables: []
                  #relations: []
                  #touches: []
                  +timestamps: true
                  +usesUniqueIds: false
                  #hidden: []
                  #visible: []
                  #fillable: []
                  #guarded: array:1 [ …1]
                }
              ]
              #escapeWhenCastingToString: false
            }
            "field_series" => Illuminate\Database\Eloquent\Collection {#1244
              #items: []
              #escapeWhenCastingToString: false
            }
            "field_umk" => Illuminate\Database\Eloquent\Collection {#1245
              #items: []
              #escapeWhenCastingToString: false
            }
            "field_level_of_education" => Illuminate\Database\Eloquent\Collection {#1246
              #items: array:1 [
                0 => App\Models\Term {#1247
                  #connection: "mysql"
                  #table: "terms"
                  #primaryKey: "id"
                  #keyType: "int"
                  +incrementing: false
                  #with: []
                  #withCount: []
                  +preventsLazyLoading: false
                  #perPage: 15
                  +exists: true
                  +wasRecentlyCreated: false
                  #escapeWhenCastingToString: false
                  #attributes: array:6 [ …6]
                  #original: array:6 [ …6]
                  #changes: []
                  #casts: []
                  #classCastCache: []
                  #attributeCastCache: []
                  #dateFormat: null
                  #appends: []
                  #dispatchesEvents: []
                  #observables: []
                  #relations: []
                  #touches: []
                  +timestamps: true
                  +usesUniqueIds: false
                  #hidden: []
                  #visible: []
                  #fillable: []
                  #guarded: array:1 [ …1]
                }
              ]
              #escapeWhenCastingToString: false
            }
            "field_standart_of_education" => Illuminate\Database\Eloquent\Collection {#1248
              #items: array:1 [
                0 => App\Models\Term {#1249
                  #connection: "mysql"
                  #table: "terms"
                  #primaryKey: "id"
                  #keyType: "int"
                  +incrementing: false
                  #with: []
                  #withCount: []
                  +preventsLazyLoading: false
                  #perPage: 15
                  +exists: true
                  +wasRecentlyCreated: false
                  #escapeWhenCastingToString: false
                  #attributes: array:10 [ …10]
                  #original: array:10 [ …10]
                  #changes: []
                  #casts: []
                  #classCastCache: []
                  #attributeCastCache: []
                  #dateFormat: null
                  #appends: []
                  #dispatchesEvents: []
                  #observables: []
                  #relations: []
                  #touches: []
                  +timestamps: true
                  +usesUniqueIds: false
                  #hidden: []
                  #visible: []
                  #fillable: []
                  #guarded: array:1 [ …1]
                }
              ]
              #escapeWhenCastingToString: false
            }
            "field_publication_number" => "10"
            "field_publication_type" => Illuminate\Database\Eloquent\Collection {#1250
              #items: array:1 [
                0 => App\Models\Term {#1251
                  #connection: "mysql"
                  #table: "terms"
                  #primaryKey: "id"
                  #keyType: "int"
                  +incrementing: false
                  #with: []
                  #withCount: []
                  +preventsLazyLoading: false
                  #perPage: 15
                  +exists: true
                  +wasRecentlyCreated: false
                  #escapeWhenCastingToString: false
                  #attributes: array:6 [ …6]
                  #original: array:6 [ …6]
                  #changes: []
                  #casts: []
                  #classCastCache: []
                  #attributeCastCache: []
                  #dateFormat: null
                  #appends: []
                  #dispatchesEvents: []
                  #observables: []
                  #relations: []
                  #touches: []
                  +timestamps: true
                  +usesUniqueIds: false
                  #hidden: []
                  #visible: []
                  #fillable: []
                  #guarded: array:1 [ …1]
                }
              ]
              #escapeWhenCastingToString: false
            }
            "field_under_the_edition" => Illuminate\Database\Eloquent\Collection {#1252
              #items: array:1 [
                0 => App\Models\Term {#1236}
              ]
              #escapeWhenCastingToString: false
            }
            "field_under_the_edition_degree" => "доктор химических наук, академика РАН"
            "field_cover_description" => "с радугой"
            "field_publication_year" => "2023"
            "field_publication_year_until" => null
            "field_part" => ""
            "field_part_writing" => ""
            "field_second_foreign_language" => null
            "field_for_whom" => null
            "field_allowed" => "Допущено Министерством просвещения Российской Федерации"
            "field_reserve_field" => null
            "field_link_to_source" => null
            "field_tasks_count" => "697"
            "field_priority" => "10"
            "field_default_folder" => "/himiya_10/eremin-u23/"
            "field_isbn" => null
            "field_cover" => array:1 [
              0 => "/media/himiya_10/eremin-u23/covers/cover1.webp?ts=1738768732"
            ]
            "field_cover_alts" => array:1 [
              0 => ""
            ]
            "field_covers" => array:1 [
              0 => array:4 [
                "path" => "/media/himiya_10/eremin-u23/covers/cover1.webp?ts=1738768732"
                "alt" => ""
                "width" => "1200"
                "height" => "1576"
              ]
            ]
            "field_popular_book" => null
            "field_recommended_books" => Illuminate\Database\Eloquent\Collection {#1253
              #items: []
              #escapeWhenCastingToString: false
            }
            "field_new_book" => Illuminate\Database\Eloquent\Collection {#1254
              #items: []
              #escapeWhenCastingToString: false
            }
            "field_old_book" => Illuminate\Database\Eloquent\Collection {#1255
              #items: []
              #escapeWhenCastingToString: false
            }
            "field_url" => "/10-klass/himiya/eremin-uchebnik"
            "field_cover_color" => Illuminate\Database\Eloquent\Collection {#1256
              #items: array:2 [
                0 => App\Models\Term {#1257
                  #connection: "mysql"
                  #table: "terms"
                  #primaryKey: "id"
                  #keyType: "int"
                  +incrementing: false
                  #with: []
                  #withCount: []
                  +preventsLazyLoading: false
                  #perPage: 15
                  +exists: true
                  +wasRecentlyCreated: false
                  #escapeWhenCastingToString: false
                  #attributes: array:6 [ …6]
                  #original: array:6 [ …6]
                  #changes: []
                  #casts: []
                  #classCastCache: []
                  #attributeCastCache: []
                  #dateFormat: null
                  #appends: []
                  #dispatchesEvents: []
                  #observables: []
                  #relations: []
                  #touches: []
                  +timestamps: true
                  +usesUniqueIds: false
                  #hidden: []
                  #visible: []
                  #fillable: []
                  #guarded: array:1 [ …1]
                }
                1 => App\Models\Term {#1258
                  #connection: "mysql"
                  #table: "terms"
                  #primaryKey: "id"
                  #keyType: "int"
                  +incrementing: false
                  #with: []
                  #withCount: []
                  +preventsLazyLoading: false
                  #perPage: 15
                  +exists: true
                  +wasRecentlyCreated: false
                  #escapeWhenCastingToString: false
                  #attributes: array:6 [ …6]
                  #original: array:6 [ …6]
                  #changes: []
                  #casts: []
                  #classCastCache: []
                  #attributeCastCache: []
                  #dateFormat: null
                  #appends: []
                  #dispatchesEvents: []
                  #observables: []
                  #relations: []
                  #touches: []
                  +timestamps: true
                  +usesUniqueIds: false
                  #hidden: []
                  #visible: []
                  #fillable: []
                  #guarded: array:1 [ …1]
                }
              ]
              #escapeWhenCastingToString: false
            }
            "field_metatags_title" => null
            "field_metatags_description" => null
            "field_h1" => null
            "field_description_top" => null
            "field_description_bottom" => null
            "breadcrumbs" => array:3 [
              "class" => 381
              "subject" => 558
              "class_subject" => 500
            ]
          ]
          #original: array:50 [
            "id" => 1003
            "created_at" => "2026-04-10 13:58:26"
            "updated_at" => null
            "field_tree_default_status" => "tasks"
            "field_pages_status" => null
            "field_subject" => Illuminate\Database\Eloquent\Collection {#1226}
            "field_class" => Illuminate\Database\Eloquent\Collection {#1227}
            "field_publisher" => Illuminate\Database\Eloquent\Collection {#1229}
            "field_author" => Illuminate\Database\Eloquent\Collection {#1231}
            "field_author_foreign" => Illuminate\Database\Eloquent\Collection {#1237}
            "field_book_type" => Illuminate\Database\Eloquent\Collection {#1238}
            "field_country" => Illuminate\Database\Eloquent\Collection {#1240}
            "field_city" => Illuminate\Database\Eloquent\Collection {#1242}
            "field_series" => Illuminate\Database\Eloquent\Collection {#1244}
            "field_umk" => Illuminate\Database\Eloquent\Collection {#1245}
            "field_level_of_education" => Illuminate\Database\Eloquent\Collection {#1246}
            "field_standart_of_education" => Illuminate\Database\Eloquent\Collection {#1248}
            "field_publication_number" => "10"
            "field_publication_type" => Illuminate\Database\Eloquent\Collection {#1250}
            "field_under_the_edition" => Illuminate\Database\Eloquent\Collection {#1252}
            "field_under_the_edition_degree" => "доктор химических наук, академика РАН"
            "field_cover_description" => "с радугой"
            "field_publication_year" => "2023"
            "field_publication_year_until" => null
            "field_part" => ""
            "field_part_writing" => ""
            "field_second_foreign_language" => null
            "field_for_whom" => null
            "field_allowed" => "Допущено Министерством просвещения Российской Федерации"
            "field_reserve_field" => null
            "field_link_to_source" => null
            "field_tasks_count" => "697"
            "field_priority" => "10"
            "field_default_folder" => "/himiya_10/eremin-u23/"
            "field_isbn" => null
            "field_cover" => array:1 [
              0 => "/media/himiya_10/eremin-u23/covers/cover1.webp?ts=1738768732"
            ]
            "field_cover_alts" => array:1 [
              0 => ""
            ]
            "field_covers" => array:1 [
              0 => array:4 [
                "path" => "/media/himiya_10/eremin-u23/covers/cover1.webp?ts=1738768732"
                "alt" => ""
                "width" => "1200"
                "height" => "1576"
              ]
            ]
            "field_popular_book" => null
            "field_recommended_books" => Illuminate\Database\Eloquent\Collection {#1253}
            "field_new_book" => Illuminate\Database\Eloquent\Collection {#1254}
            "field_old_book" => Illuminate\Database\Eloquent\Collection {#1255}
            "field_url" => "/10-klass/himiya/eremin-uchebnik"
            "field_cover_color" => Illuminate\Database\Eloquent\Collection {#1256}
            "field_metatags_title" => null
            "field_metatags_description" => null
            "field_h1" => null
            "field_description_top" => null
            "field_description_bottom" => null
            "breadcrumbs" => array:3 [
              "class" => 381
              "subject" => 558
              "class_subject" => 500
            ]
          ]
          #changes: []
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          #classCastCache: []
          #attributeCastCache: []
          #dateFormat: null
          #appends: []
          #dispatchesEvents: []
          #observables: []
          #relations: []
          #touches: []
          +timestamps: true
          +usesUniqueIds: false
          #hidden: []
          #visible: []
          #fillable: []
          #guarded: array:1 [
            0 => "*"
          ]
        }
      ]
      #escapeWhenCastingToString: false
    }
    "page" => Illuminate\Database\Eloquent\Collection {#1501
      #items: array:1 [
        0 => App\Models\BookPage {#1032
          #connection: "mysql"
          #table: "book_pages"
          #primaryKey: "id"
          #keyType: "int"
          +incrementing: true
          #with: []
          #withCount: []
          +preventsLazyLoading: false
          #perPage: 15
          +exists: true
          +wasRecentlyCreated: false
          #escapeWhenCastingToString: false
          #attributes: array:21 [
            "id" => 926073
            "created_at" => "2026-04-10 13:58:26"
            "updated_at" => null
            "field_page_start" => "177"
            "field_url" => "/10-klass/himiya/eremin-uchebnik/page-177"
            "field_display_title" => "177"
            "field_folder" => "1"
            "field_image_name" => "177"
            "field_branch_parent" => Illuminate\Database\Eloquent\Collection {#1023
              #items: []
              #escapeWhenCastingToString: false
            }
            "field_weight" => "0"
            "field_book_parent" => Illuminate\Database\Eloquent\Collection {#331
              #items: array:1 [
                0 => App\Models\Book {#1259
                  #connection: "mysql"
                  #table: "books"
                  #primaryKey: "id"
                  #keyType: "int"
                  +incrementing: false
                  #with: []
                  #withCount: []
                  +preventsLazyLoading: false
                  #perPage: 15
                  +exists: true
                  +wasRecentlyCreated: false
                  #escapeWhenCastingToString: false
                  #attributes: array:50 [ …50]
                  #original: array:50 [ …50]
                  #changes: []
                  #casts: []
                  #classCastCache: []
                  #attributeCastCache: []
                  #dateFormat: null
                  #appends: []
                  #dispatchesEvents: []
                  #observables: []
                  #relations: []
                  #touches: []
                  +timestamps: true
                  +usesUniqueIds: false
                  #hidden: []
                  #visible: []
                  #fillable: []
                  #guarded: array:1 [ …1]
                }
              ]
              #escapeWhenCastingToString: false
            }
            "field_metatags_title" => null
            "field_metatags_description" => null
            "field_h1" => null
            "field_description_top" => null
            "field_description_bottom" => null
            "edition_groups" => Illuminate\Database\Eloquent\Collection {#1295
              #items: []
              #escapeWhenCastingToString: false
            }
            "content" => Illuminate\Database\Eloquent\Collection {#1296
              #items: array:1 [
                0 => App\Models\Element {#1297
                  #connection: "mysql"
                  #table: "elements"
                  #primaryKey: "id"
                  #keyType: "int"
                  +incrementing: true
                  #with: []
                  #withCount: []
                  +preventsLazyLoading: false
                  #perPage: 15
                  +exists: true
                  +wasRecentlyCreated: false
                  #escapeWhenCastingToString: false
                  #attributes: array:6 [ …6]
                  #original: array:6 [ …6]
                  #changes: []
                  #casts: []
                  #classCastCache: []
                  #attributeCastCache: []
                  #dateFormat: null
                  #appends: []
                  #dispatchesEvents: []
                  #observables: []
                  #relations: []
                  #touches: []
                  +timestamps: true
                  +usesUniqueIds: false
                  #hidden: []
                  #visible: []
                  #fillable: []
                  #guarded: array:1 [ …1]
                }
              ]
              #escapeWhenCastingToString: false
            }
            "next" => array:2 [
              "refs" => "926074"
              "type" => "book_page"
            ]
            "previous" => array:2 [
              "refs" => "926072"
              "type" => "book_page"
            ]
            "tasks" => Illuminate\Database\Eloquent\Collection {#1305
              #items: array:10 [
                0 => App\Models\Task {#1306
                  #connection: "mysql"
                  #table: "tasks"
                  #primaryKey: "id"
                  #keyType: "int"
                  +incrementing: true
                  #with: []
                  #withCount: []
                  +preventsLazyLoading: false
                  #perPage: 15
                  +exists: true
                  +wasRecentlyCreated: false
                  #escapeWhenCastingToString: false
                  #attributes: array:24 [ …24]
                  #original: array:24 [ …24]
                  #changes: []
                  #casts: []
                  #classCastCache: []
                  #attributeCastCache: []
                  #dateFormat: null
                  #appends: []
                  #dispatchesEvents: []
                  #observables: []
                  #relations: []
                  #touches: []
                  +timestamps: true
                  +usesUniqueIds: false
                  #hidden: []
                  #visible: []
                  #fillable: []
                  #guarded: array:1 [ …1]
                }
                1 => App\Models\Task {#1382
                  #connection: "mysql"
                  #table: "tasks"
                  #primaryKey: "id"
                  #keyType: "int"
                  +incrementing: true
                  #with: []
                  #withCount: []
                  +preventsLazyLoading: false
                  #perPage: 15
                  +exists: true
                  +wasRecentlyCreated: false
                  #escapeWhenCastingToString: false
                  #attributes: array:24 [ …24]
                  #original: array:24 [ …24]
                  #changes: []
                  #casts: []
                  #classCastCache: []
                  #attributeCastCache: []
                  #dateFormat: null
                  #appends: []
                  #dispatchesEvents: []
                  #observables: []
                  #relations: []
                  #touches: []
                  +timestamps: true
                  +usesUniqueIds: false
                  #hidden: []
                  #visible: []
                  #fillable: []
                  #guarded: array:1 [ …1]
                }
                2 => App\Models\Task {#1395
                  #connection: "mysql"
                  #table: "tasks"
                  #primaryKey: "id"
                  #keyType: "int"
                  +incrementing: true
                  #with: []
                  #withCount: []
                  +preventsLazyLoading: false
                  #perPage: 15
                  +exists: true
                  +wasRecentlyCreated: false
                  #escapeWhenCastingToString: false
                  #attributes: array:24 [ …24]
                  #original: array:24 [ …24]
                  #changes: []
                  #casts: []
                  #classCastCache: []
                  #attributeCastCache: []
                  #dateFormat: null
                  #appends: []
                  #dispatchesEvents: []
                  #observables: []
                  #relations: []
                  #touches: []
                  +timestamps: true
                  +usesUniqueIds: false
                  #hidden: []
                  #visible: []
                  #fillable: []
                  #guarded: array:1 [ …1]
                }
                3 => App\Models\Task {#1408
                  #connection: "mysql"
                  #table: "tasks"
                  #primaryKey: "id"
                  #keyType: "int"
                  +incrementing: true
                  #with: []
                  #withCount: []
                  +preventsLazyLoading: false
                  #perPage: 15
                  +exists: true
                  +wasRecentlyCreated: false
                  #escapeWhenCastingToString: false
                  #attributes: array:24 [ …24]
                  #original: array:24 [ …24]
                  #changes: []
                  #casts: []
                  #classCastCache: []
                  #attributeCastCache: []
                  #dateFormat: null
                  #appends: []
                  #dispatchesEvents: []
                  #observables: []
                  #relations: []
                  #touches: []
                  +timestamps: true
                  +usesUniqueIds: false
                  #hidden: []
                  #visible: []
                  #fillable: []
                  #guarded: array:1 [ …1]
                }
                4 => App\Models\Task {#1421
                  #connection: "mysql"
                  #table: "tasks"
                  #primaryKey: "id"
                  #keyType: "int"
                  +incrementing: true
                  #with: []
                  #withCount: []
                  +preventsLazyLoading: false
                  #perPage: 15
                  +exists: true
                  +wasRecentlyCreated: false
                  #escapeWhenCastingToString: false
                  #attributes: array:24 [ …24]
                  #original: array:24 [ …24]
                  #changes: []
                  #casts: []
                  #classCastCache: []
                  #attributeCastCache: []
                  #dateFormat: null
                  #appends: []
                  #dispatchesEvents: []
                  #observables: []
                  #relations: []
                  #touches: []
                  +timestamps: true
                  +usesUniqueIds: false
                  #hidden: []
                  #visible: []
                  #fillable: []
                  #guarded: array:1 [ …1]
                }
                5 => App\Models\Task {#1434
                  #connection: "mysql"
                  #table: "tasks"
                  #primaryKey: "id"
                  #keyType: "int"
                  +incrementing: true
                  #with: []
                  #withCount: []
                  +preventsLazyLoading: false
                  #perPage: 15
                  +exists: true
                  +wasRecentlyCreated: false
                  #escapeWhenCastingToString: false
                  #attributes: array:24 [ …24]
                  #original: array:24 [ …24]
                  #changes: []
                  #casts: []
                  #classCastCache: []
                  #attributeCastCache: []
                  #dateFormat: null
                  #appends: []
                  #dispatchesEvents: []
                  #observables: []
                  #relations: []
                  #touches: []
                  +timestamps: true
                  +usesUniqueIds: false
                  #hidden: []
                  #visible: []
                  #fillable: []
                  #guarded: array:1 [ …1]
                }
                6 => App\Models\Task {#1447
                  #connection: "mysql"
                  #table: "tasks"
                  #primaryKey: "id"
                  #keyType: "int"
                  +incrementing: true
                  #with: []
                  #withCount: []
                  +preventsLazyLoading: false
                  #perPage: 15
                  +exists: true
                  +wasRecentlyCreated: false
                  #escapeWhenCastingToString: false
                  #attributes: array:24 [ …24]
                  #original: array:24 [ …24]
                  #changes: []
                  #casts: []
                  #classCastCache: []
                  #attributeCastCache: []
                  #dateFormat: null
                  #appends: []
                  #dispatchesEvents: []
                  #observables: []
                  #relations: []
                  #touches: []
                  +timestamps: true
                  +usesUniqueIds: false
                  #hidden: []
                  #visible: []
                  #fillable: []
                  #guarded: array:1 [ …1]
                }
                7 => App\Models\Task {#1460
                  #connection: "mysql"
                  #table: "tasks"
                  #primaryKey: "id"
                  #keyType: "int"
                  +incrementing: true
                  #with: []
                  #withCount: []
                  +preventsLazyLoading: false
                  #perPage: 15
                  +exists: true
                  +wasRecentlyCreated: false
                  #escapeWhenCastingToString: false
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№4 (с. 177)
Условие. №4 (с. 177)
скриншот условия
Химия, 10 класс Учебник, авторы: Еремин Вадим Владимирович, Кузьменко Николай Егорович, Теренин Владимир Ильич, Дроздов Андрей Анатольевич, Лунин Валерий Васильевич, издательство Просвещение, Москва, 2023, белого цвета, страница 177, номер 4, Условие

4. Дегидрирование этана — обратимый эндотермический процесс.

Напишите уравнение этого процесса и объясните, как можно сместить равновесие в сторону образования этилена.

Решение. №4 (с. 177)
Химия, 10 класс Учебник, авторы: Еремин Вадим Владимирович, Кузьменко Николай Егорович, Теренин Владимир Ильич, Дроздов Андрей Анатольевич, Лунин Валерий Васильевич, издательство Просвещение, Москва, 2023, белого цвета, страница 177, номер 4, Решение
Решение 2. №4 (с. 177)

Решение

Дегидрирование этана — это процесс отщепления молекулы водорода от молекулы этана с образованием этилена (этена). Это обратимый химический процесс.

Уравнение этого процесса выглядит следующим образом:
$C_2H_6(г) \rightleftarrows C_2H_4(г) + H_2(г)$

Смещение химического равновесия подчиняется принципу Ле Шателье: если на систему, находящуюся в состоянии равновесия, оказывается внешнее воздействие, то равновесие смещается в направлении, которое ослабляет это воздействие. Чтобы сместить равновесие в сторону образования этилена (вправо), необходимо изменить условия реакции.

Повышение температуры. В условии сказано, что процесс является эндотермическим, то есть прямая реакция ($C_2H_6 \rightarrow C_2H_4 + H_2$) протекает с поглощением теплоты ($ \Delta H > 0 $). Согласно принципу Ле Шателье, повышение температуры смещает равновесие в сторону эндотермической реакции. Таким образом, для увеличения выхода этилена необходимо повышать температуру.

Понижение давления. Проанализируем изменение количества газообразных веществ. В левой части уравнения находится 1 моль газа ($C_2H_6$), а в правой — 2 моль газов ($C_2H_4$ и $H_2$). Прямая реакция идёт с увеличением числа молей газов. Понижение давления в системе смещает равновесие в сторону образования большего количества молей газов. Следовательно, понижение давления будет способствовать смещению равновесия вправо, в сторону образования этилена.

Изменение концентраций. Для смещения равновесия в сторону продуктов реакции (вправо) можно:
- Увеличить концентрацию исходного вещества — этана ($C_2H_6$).
- Уменьшать концентрацию продуктов реакции — этилена ($C_2H_4$) и/или водорода ($H_2$), например, путем их постоянного отвода из реакционной зоны.

Использование катализатора (например, $Ni, Pt, Cr_2O_3$) не смещает равновесие, но ускоряет его достижение.

Ответ: Уравнение процесса дегидрирования этана: $C_2H_6 \rightleftarrows C_2H_4 + H_2$. Для смещения равновесия в сторону образования этилена необходимо повышать температуру, понижать давление, а также увеличивать концентрацию исходного этана или удалять образующиеся этилен и водород из системы.

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