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Номер 4, страница 309 - гдз по химии 10 класс учебник Еремин, Кузьменко
Авторы: Еремин В. В., Кузьменко Н. Е., Теренин В. И., Дроздов А. А., Лунин В. В.
Тип: Учебник
Издательство: Просвещение
Год издания: 2023 - 2026
Уровень обучения: углублённый
Цвет обложки: белый, зелёный с радугой
Допущено Министерством просвещения Российской Федерации
Популярные ГДЗ в 10 классе
Глава 5. Азот- и серосодержащие органические соединения. Параграф 53. Амины - номер 4, страница 309.
App\Models\Task {#1030 // resources/views/models/task/default.blade.php #connection: "mysql" #table: "tasks" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:24 [ "id" => 663305 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_page_start" => "309" "field_page_end" => null "field_url" => "/10-klass/himiya/eremin-uchebnik/53-4" "field_display_title" => "4" "field_outside_task" => null "field_task_type" => Illuminate\Database\Eloquent\Collection {#1037 #items: array:1 [ 0 => App\Models\Term {#1036 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:6 [ "id" => 26 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "номер" "field_cases" => array:6 [ "field_accusative_case" => "номер" "field_creative_case" => "номером" "field_dative_case" => "номеру" "field_genitive_case" => "номера" "field_nominative_case" => "номер" "field_prepositional_case" => "номере" ] "field_short_name" => "№" ] #original: array:6 [ "id" => 26 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "номер" "field_cases" => array:6 [ "field_accusative_case" => "номер" "field_creative_case" => "номером" "field_dative_case" => "номеру" "field_genitive_case" => "номера" "field_nominative_case" => "номер" "field_prepositional_case" => "номере" ] "field_short_name" => "№" ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "field_match" => null "breadcrumbs" => [] "edition_groups" => Illuminate\Database\Eloquent\Collection {#1035 #items: [] #escapeWhenCastingToString: false } "top_parent_branch" => Illuminate\Database\Eloquent\Collection {#1046 #items: array:1 [ 0 => App\Models\Branch {#1045 #connection: "mysql" #table: "branches" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:24 [ "id" => 662753 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_display_title" => "Азот- и серосодержащие органические соединения" "field_branch_order" => "5" "field_url" => null "field_branch_type" => Illuminate\Database\Eloquent\Collection {#1050 #items: array:1 [ 0 => App\Models\Term {#1047 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:7 [ "id" => 29 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Глава" "field_cases" => array:6 [ "field_accusative_case" => "Главу" "field_creative_case" => "Главой" "field_dative_case" => "Главе" "field_genitive_case" => "Главы" "field_nominative_case" => "Глава" "field_prepositional_case" => "Главе" ] "field_page_check_not_needed" => null "field_short_name" => null ] #original: array:7 [ "id" => 29 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Глава" "field_cases" => array:6 [ "field_accusative_case" => "Главу" "field_creative_case" => "Главой" "field_dative_case" => "Главе" "field_genitive_case" => "Главы" "field_nominative_case" => "Глава" "field_prepositional_case" => "Главе" ] "field_page_check_not_needed" => null "field_short_name" => null ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "field_page_start" => "300" "field_branch_display" => "0" "field_branch_expanded" => "0" "field_display_branch_in_title" => "1" "field_display_task_interval" => "0" "field_display_branch_page" => "1" "field_branch_title_in_content" => "0" "field_navigation_title" => null "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "field_branch_cover" => [] "field_branch_covers" => [] "book" => Illuminate\Database\Eloquent\Collection {#1086 #items: array:1 [ 0 => App\Models\Book {#1049 #connection: "mysql" #table: "books" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:50 [ "id" => 1003 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_tree_default_status" => "tasks" "field_pages_status" => null "field_subject" => Illuminate\Database\Eloquent\Collection {#1051 #items: array:1 [ 0 => App\Models\Term {#1048 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:10 [ "id" => 6495 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Химия" "field_abbreviated_name" => null "field_cases" => array:6 [ "field_accusative_case" => "химию" "field_creative_case" => "химией" "field_dative_case" => "химии" "field_genitive_case" => "химии" "field_nominative_case" => "химия" "field_prepositional_case" => "химии" ] "field_foreign_lang_name" => null "field_short_name" => null "field_subject_type" => "technical_subject" "field_translit" => "himiya" ] #original: array:10 [ "id" => 6495 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Химия" "field_abbreviated_name" => null "field_cases" => array:6 [ "field_accusative_case" => "химию" "field_creative_case" => "химией" "field_dative_case" => "химии" "field_genitive_case" => "химии" "field_nominative_case" => "химия" "field_prepositional_case" => "химии" ] "field_foreign_lang_name" => null "field_short_name" => null "field_subject_type" => "technical_subject" "field_translit" => "himiya" ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "field_class" => Illuminate\Database\Eloquent\Collection {#1052 #items: array:1 [ 0 => App\Models\Term {#1053 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:6 [ "id" => 5459 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "10" "field_cases" => array:6 [ "field_accusative_case" => "десятый" "field_creative_case" => "десятым" "field_dative_case" => "десятому" "field_genitive_case" => "десятого" "field_nominative_case" => "десятый" "field_prepositional_case" => "десятом" ] "field_translit" => "desjatyj" ] #original: array:6 [ "id" => 5459 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "10" "field_cases" => array:6 [ "field_accusative_case" => "десятый" "field_creative_case" => "десятым" "field_dative_case" => "десятому" "field_genitive_case" => "десятого" "field_nominative_case" => "десятый" "field_prepositional_case" => "десятом" ] "field_translit" => "desjatyj" ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "field_publisher" => Illuminate\Database\Eloquent\Collection {#1054 #items: array:1 [ 0 => App\Models\Term {#1055 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:6 [ "id" => 5153 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Просвещение" "field_cases" => null "field_translit" => "prosveschenie" ] #original: array:6 [ "id" => 5153 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Просвещение" "field_cases" => null "field_translit" => "prosveschenie" ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "field_author" => Illuminate\Database\Eloquent\Collection {#1056 #items: array:5 [ 0 => App\Models\Term {#1057 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:12 [ "id" => 4330 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Еремин" "field_bio" => null "field_degree_rp" => null "field_foreign_lang_name" => null "field_foreign_lang_patronymic" => null "field_foreign_lang_surname" => null "field_name" => "Вадим" "field_patronymic" => "Владимирович" "field_surname_rp" => null ] #original: array:12 [ "id" => 4330 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Еремин" "field_bio" => null "field_degree_rp" => null "field_foreign_lang_name" => null "field_foreign_lang_patronymic" => null "field_foreign_lang_surname" => null "field_name" => "Вадим" "field_patronymic" => "Владимирович" "field_surname_rp" => null ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } 1 => App\Models\Term {#1058 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:12 [ "id" => 4876 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Кузьменко" "field_bio" => null "field_degree_rp" => null "field_foreign_lang_name" => null "field_foreign_lang_patronymic" => null "field_foreign_lang_surname" => null "field_name" => "Николай" "field_patronymic" => "Егорович" "field_surname_rp" => null ] #original: array:12 [ "id" => 4876 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Кузьменко" "field_bio" => null "field_degree_rp" => null "field_foreign_lang_name" => null "field_foreign_lang_patronymic" => null "field_foreign_lang_surname" => null "field_name" => "Николай" "field_patronymic" => "Егорович" "field_surname_rp" => null ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } 2 => App\Models\Term {#1059 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:12 [ "id" => 5912 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Теренин" "field_bio" => null "field_degree_rp" => null "field_foreign_lang_name" => null "field_foreign_lang_patronymic" => null "field_foreign_lang_surname" => null "field_name" => "Владимир" "field_patronymic" => "Ильич" "field_surname_rp" => null ] #original: array:12 [ "id" => 5912 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Теренин" "field_bio" => null "field_degree_rp" => null "field_foreign_lang_name" => null "field_foreign_lang_patronymic" => null "field_foreign_lang_surname" => null "field_name" => "Владимир" "field_patronymic" => "Ильич" "field_surname_rp" => null ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } 3 => App\Models\Term {#1060 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:12 [ "id" => 4290 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Дроздов" "field_bio" => null "field_degree_rp" => null "field_foreign_lang_name" => null "field_foreign_lang_patronymic" => null "field_foreign_lang_surname" => null "field_name" => "Андрей" "field_patronymic" => "Анатольевич" "field_surname_rp" => null ] #original: array:12 [ "id" => 4290 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Дроздов" "field_bio" => null "field_degree_rp" => null "field_foreign_lang_name" => null "field_foreign_lang_patronymic" => null "field_foreign_lang_surname" => null "field_name" => "Андрей" "field_patronymic" => "Анатольевич" "field_surname_rp" => null ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } 4 => App\Models\Term {#1061 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:12 [ "id" => 5031 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Лунин" "field_bio" => null "field_degree_rp" => "доктор химических наук, академика РАН" "field_foreign_lang_name" => null "field_foreign_lang_patronymic" => null "field_foreign_lang_surname" => null "field_name" => "Валерий" "field_patronymic" => "Васильевич" "field_surname_rp" => "Лунина" ] #original: array:12 [ "id" => 5031 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Лунин" "field_bio" => null "field_degree_rp" => "доктор химических наук, академика РАН" "field_foreign_lang_name" => null "field_foreign_lang_patronymic" => null "field_foreign_lang_surname" => null "field_name" => "Валерий" "field_patronymic" => "Васильевич" "field_surname_rp" => "Лунина" ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "field_author_foreign" => Illuminate\Database\Eloquent\Collection {#1062 #items: [] #escapeWhenCastingToString: false } "field_book_type" => Illuminate\Database\Eloquent\Collection {#1063 #items: array:1 [ 0 => App\Models\Term {#1064 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:10 [ "id" => 6671 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Учебник" "field_book_type_foreign" => null "field_cases" => array:6 [ "field_accusative_case" => "учебник" "field_creative_case" => "учебником" "field_dative_case" => "учебнику" "field_genitive_case" => "учебника" "field_nominative_case" => "учебник" "field_prepositional_case" => "учебнике" ] "field_plural_form" => null "field_short_name" => null "field_short_name_foreign" => null "field_translit" => "uchebnik" ] #original: array:10 [ "id" => 6671 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Учебник" "field_book_type_foreign" => null "field_cases" => array:6 [ "field_accusative_case" => "учебник" "field_creative_case" => "учебником" "field_dative_case" => "учебнику" "field_genitive_case" => "учебника" "field_nominative_case" => "учебник" "field_prepositional_case" => "учебнике" ] "field_plural_form" => null "field_short_name" => null "field_short_name_foreign" => null "field_translit" => "uchebnik" ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "field_country" => Illuminate\Database\Eloquent\Collection {#1065 #items: array:1 [ 0 => App\Models\Term {#1066 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:6 [ "id" => 9 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Россия" "field_cases" => array:6 [ "field_accusative_case" => null "field_creative_case" => null "field_dative_case" => null "field_genitive_case" => null "field_nominative_case" => null "field_prepositional_case" => null ] "field_translit" => "rossiya" ] #original: array:6 [ "id" => 9 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Россия" "field_cases" => array:6 [ "field_accusative_case" => null "field_creative_case" => null "field_dative_case" => null "field_genitive_case" => null "field_nominative_case" => null "field_prepositional_case" => null ] "field_translit" => "rossiya" ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "field_city" => Illuminate\Database\Eloquent\Collection {#1067 #items: array:1 [ 0 => App\Models\Term {#1068 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:6 [ "id" => 15 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Москва" "field_cases" => array:6 [ "field_accusative_case" => null "field_creative_case" => null "field_dative_case" => null "field_genitive_case" => null "field_nominative_case" => null "field_prepositional_case" => null ] "field_translit" => "moskva" ] #original: array:6 [ "id" => 15 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Москва" "field_cases" => array:6 [ "field_accusative_case" => null "field_creative_case" => null …4 ] "field_translit" => "moskva" ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "field_series" => Illuminate\Database\Eloquent\Collection {#1069 #items: [] #escapeWhenCastingToString: false } "field_umk" => Illuminate\Database\Eloquent\Collection {#1070 #items: [] #escapeWhenCastingToString: false } "field_level_of_education" => Illuminate\Database\Eloquent\Collection {#1071 #items: array:1 [ 0 => App\Models\Term {#1072 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:6 [ "id" => 39 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "углублённый" "field_cases" => array:6 [ …6] "field_translit" => "uglublennyy" ] #original: array:6 [ "id" => 39 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "углублённый" "field_cases" => array:6 [ …6] "field_translit" => "uglublennyy" ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "field_standart_of_education" => Illuminate\Database\Eloquent\Collection {#1073 #items: array:1 [ 0 => App\Models\Term {#1074 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:10 [ "id" => 6706 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "ФГОС (старый)" "field_cases" => array:6 [ …6] "field_color" => null "field_end_year" => "2022" "field_start_year" => "2019" "field_translit" => "fgos-old" "field_type" => null ] #original: array:10 [ "id" => 6706 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "ФГОС (старый)" "field_cases" => array:6 [ …6] "field_color" => null "field_end_year" => "2022" "field_start_year" => "2019" "field_translit" => "fgos-old" "field_type" => null ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "field_publication_number" => "10" "field_publication_type" => Illuminate\Database\Eloquent\Collection {#1075 #items: array:1 [ 0 => App\Models\Term {#1076 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:6 [ "id" => 33 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "стереотипное" "field_cases" => array:6 [ …6] "field_translit" => "stereotipnoe" ] #original: array:6 [ "id" => 33 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "стереотипное" "field_cases" => array:6 [ …6] "field_translit" => "stereotipnoe" ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "field_under_the_edition" => Illuminate\Database\Eloquent\Collection {#1077 #items: array:1 [ 0 => App\Models\Term {#1061} ] #escapeWhenCastingToString: false } "field_under_the_edition_degree" => "доктор химических наук, академика РАН" "field_cover_description" => "с радугой" "field_publication_year" => "2023" "field_publication_year_until" => null "field_part" => "" "field_part_writing" => "" "field_second_foreign_language" => null "field_for_whom" => null "field_allowed" => "Допущено Министерством просвещения Российской Федерации" "field_reserve_field" => null "field_link_to_source" => null "field_tasks_count" => "697" "field_priority" => "10" "field_default_folder" => "/himiya_10/eremin-u23/" "field_isbn" => null "field_cover" => array:1 [ 0 => "/media/himiya_10/eremin-u23/covers/cover1.webp?ts=1738768732" ] "field_cover_alts" => array:1 [ 0 => "" ] "field_covers" => array:1 [ 0 => array:4 [ "path" => "/media/himiya_10/eremin-u23/covers/cover1.webp?ts=1738768732" "alt" => "" "width" => "1200" "height" => "1576" ] ] "field_popular_book" => null "field_recommended_books" => Illuminate\Database\Eloquent\Collection {#1078 #items: [] #escapeWhenCastingToString: false } "field_new_book" => Illuminate\Database\Eloquent\Collection {#1079 #items: [] #escapeWhenCastingToString: false } "field_old_book" => Illuminate\Database\Eloquent\Collection {#1080 #items: [] #escapeWhenCastingToString: false } "field_url" => "/10-klass/himiya/eremin-uchebnik" "field_cover_color" => Illuminate\Database\Eloquent\Collection {#1081 #items: array:2 [ 0 => App\Models\Term {#1082 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:6 [ "id" => 45 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "белый" "field_cases" => array:6 [ …6] "field_translit" => "belyy" ] #original: array:6 [ "id" => 45 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "белый" "field_cases" => array:6 [ …6] "field_translit" => "belyy" ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } 1 => App\Models\Term {#1083 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:6 [ "id" => 47 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "зелёный" "field_cases" => array:6 [ …6] "field_translit" => "zelyonyy" ] #original: array:6 [ "id" => 47 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "зелёный" "field_cases" => array:6 [ …6] "field_translit" => "zelyonyy" ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "breadcrumbs" => array:3 [ "class" => 381 "subject" => 558 "class_subject" => 500 ] ] #original: array:50 [ "id" => 1003 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_tree_default_status" => "tasks" "field_pages_status" => null "field_subject" => Illuminate\Database\Eloquent\Collection {#1051} "field_class" => Illuminate\Database\Eloquent\Collection {#1052} "field_publisher" => Illuminate\Database\Eloquent\Collection {#1054} "field_author" => Illuminate\Database\Eloquent\Collection {#1056} "field_author_foreign" => Illuminate\Database\Eloquent\Collection {#1062} "field_book_type" => Illuminate\Database\Eloquent\Collection {#1063} "field_country" => Illuminate\Database\Eloquent\Collection {#1065} "field_city" => Illuminate\Database\Eloquent\Collection {#1067} "field_series" => Illuminate\Database\Eloquent\Collection {#1069} "field_umk" => Illuminate\Database\Eloquent\Collection {#1070} "field_level_of_education" => Illuminate\Database\Eloquent\Collection {#1071} "field_standart_of_education" => Illuminate\Database\Eloquent\Collection {#1073} "field_publication_number" => "10" "field_publication_type" => Illuminate\Database\Eloquent\Collection {#1075} "field_under_the_edition" => Illuminate\Database\Eloquent\Collection {#1077} "field_under_the_edition_degree" => "доктор химических наук, академика РАН" "field_cover_description" => "с радугой" "field_publication_year" => "2023" "field_publication_year_until" => null "field_part" => "" "field_part_writing" => "" "field_second_foreign_language" => null "field_for_whom" => null "field_allowed" => "Допущено Министерством просвещения Российской Федерации" "field_reserve_field" => null "field_link_to_source" => null "field_tasks_count" => "697" "field_priority" => "10" "field_default_folder" => "/himiya_10/eremin-u23/" "field_isbn" => null "field_cover" => array:1 [ 0 => "/media/himiya_10/eremin-u23/covers/cover1.webp?ts=1738768732" ] "field_cover_alts" => array:1 [ 0 => "" ] "field_covers" => array:1 [ 0 => array:4 [ "path" => "/media/himiya_10/eremin-u23/covers/cover1.webp?ts=1738768732" "alt" => "" "width" => "1200" "height" => "1576" ] ] "field_popular_book" => null "field_recommended_books" => Illuminate\Database\Eloquent\Collection {#1078} "field_new_book" => Illuminate\Database\Eloquent\Collection {#1079} "field_old_book" => Illuminate\Database\Eloquent\Collection {#1080} "field_url" => "/10-klass/himiya/eremin-uchebnik" "field_cover_color" => Illuminate\Database\Eloquent\Collection {#1081} "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "breadcrumbs" => array:3 [ "class" => 381 "subject" => 558 "class_subject" => 500 ] ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "branch_parent" => Illuminate\Database\Eloquent\Collection {#1084 #items: [] #escapeWhenCastingToString: false } ] #original: array:24 [ "id" => 662753 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_display_title" => "Азот- и серосодержащие органические соединения" "field_branch_order" => "5" "field_url" => null "field_branch_type" => Illuminate\Database\Eloquent\Collection {#1050} "field_page_start" => "300" "field_branch_display" => "0" "field_branch_expanded" => "0" "field_display_branch_in_title" => "1" "field_display_task_interval" => "0" "field_display_branch_page" => "1" "field_branch_title_in_content" => "0" "field_navigation_title" => null "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "field_branch_cover" => [] "field_branch_covers" => [] "book" => Illuminate\Database\Eloquent\Collection {#1086} "branch_parent" => Illuminate\Database\Eloquent\Collection {#1084} ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "parent_branches" => Illuminate\Database\Eloquent\Collection {#1121 #items: array:2 [ 0 => App\Models\Branch {#1129 #connection: "mysql" #table: "branches" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:24 [ "id" => 662753 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_display_title" => "Азот- и серосодержащие органические соединения" "field_branch_order" => "5" "field_url" => null "field_branch_type" => Illuminate\Database\Eloquent\Collection {#1130 #items: array:1 [ 0 => App\Models\Term {#1047} ] #escapeWhenCastingToString: false } "field_page_start" => "300" "field_branch_display" => "0" "field_branch_expanded" => "0" "field_display_branch_in_title" => "1" "field_display_task_interval" => "0" "field_display_branch_page" => "1" "field_branch_title_in_content" => "0" "field_navigation_title" => null "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "field_branch_cover" => [] "field_branch_covers" => [] "book" => Illuminate\Database\Eloquent\Collection {#1131 #items: array:1 [ 0 => App\Models\Book {#1049} ] #escapeWhenCastingToString: false } "branch_parent" => Illuminate\Database\Eloquent\Collection {#1132 #items: [] #escapeWhenCastingToString: false } ] #original: array:24 [ "id" => 662753 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_display_title" => "Азот- и серосодержащие органические соединения" "field_branch_order" => "5" "field_url" => null "field_branch_type" => Illuminate\Database\Eloquent\Collection {#1130} "field_page_start" => "300" "field_branch_display" => "0" "field_branch_expanded" => "0" "field_display_branch_in_title" => "1" "field_display_task_interval" => "0" "field_display_branch_page" => "1" "field_branch_title_in_content" => "0" "field_navigation_title" => null "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "field_branch_cover" => [] "field_branch_covers" => [] "book" => Illuminate\Database\Eloquent\Collection {#1131} "branch_parent" => Illuminate\Database\Eloquent\Collection {#1132} ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } 1 => App\Models\Branch {#1133 #connection: "mysql" #table: "branches" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:24 [ "id" => 662755 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_display_title" => "Амины" "field_branch_order" => "53" "field_url" => null "field_branch_type" => Illuminate\Database\Eloquent\Collection {#1137 #items: array:1 [ 0 => App\Models\Term {#1134 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:7 [ "id" => 32 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Параграф" "field_cases" => array:6 [ "field_accusative_case" => "Параграф" "field_creative_case" => "Параграфом" "field_dative_case" => "Параграфу" "field_genitive_case" => "Параграфа" "field_nominative_case" => "Параграф" "field_prepositional_case" => "Параграфе" ] "field_page_check_not_needed" => null "field_short_name" => "§" ] #original: array:7 [ "id" => 32 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Параграф" "field_cases" => array:6 [ "field_accusative_case" => "Параграф" "field_creative_case" => "Параграфом" "field_dative_case" => "Параграфу" "field_genitive_case" => "Параграфа" "field_nominative_case" => "Параграф" "field_prepositional_case" => "Параграфе" ] "field_page_check_not_needed" => null "field_short_name" => "§" ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "field_page_start" => "303" "field_branch_display" => "0" "field_branch_expanded" => "0" "field_display_branch_in_title" => "1" "field_display_task_interval" => "0" "field_display_branch_page" => "1" "field_branch_title_in_content" => "0" "field_navigation_title" => null "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "field_branch_cover" => [] "field_branch_covers" => [] "book" => Illuminate\Database\Eloquent\Collection {#1136 #items: array:1 [ 0 => App\Models\Book {#1049} ] #escapeWhenCastingToString: false } "branch_parent" => Illuminate\Database\Eloquent\Collection {#1135 #items: array:1 [ 0 => App\Models\Branch {#1045} ] #escapeWhenCastingToString: false } ] #original: array:24 [ "id" => 662755 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_display_title" => "Амины" "field_branch_order" => "53" "field_url" => null "field_branch_type" => Illuminate\Database\Eloquent\Collection {#1137} "field_page_start" => "303" "field_branch_display" => "0" "field_branch_expanded" => "0" "field_display_branch_in_title" => "1" "field_display_task_interval" => "0" "field_display_branch_page" => "1" "field_branch_title_in_content" => "0" "field_navigation_title" => null "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "field_branch_cover" => [] "field_branch_covers" => [] "book" => Illuminate\Database\Eloquent\Collection {#1136} "branch_parent" => Illuminate\Database\Eloquent\Collection {#1135} ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "content" => Illuminate\Database\Eloquent\Collection {#1118 #items: array:3 [ 0 => App\Models\Element {#1111 #connection: "mysql" #table: "elements" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:7 [ "id" => 819105 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "edition" => Illuminate\Database\Eloquent\Collection {#1103 #items: array:1 [ 0 => App\Models\Edition {#1095 #connection: "mysql" #table: "editions" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:21 [ "id" => 1829 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "title" => "Условие" "field_order" => "1" "field_publisher" => Illuminate\Database\Eloquent\Collection {#1110 #items: array:1 [ …1] #escapeWhenCastingToString: false } "field_content_type" => "free" "field_content_mode" => "text, image" "field_page_content_mode" => "image" "field_content_text_checked" => null "field_page_content_text_checked" => "0" "field_solution_author" => "Автор" "field_moderator" => "vadim" "field_edition_type" => "statement" "field_root_dir" => "0-" "field_responsible" => Illuminate\Database\Eloquent\Collection {#1107 #items: [] #escapeWhenCastingToString: false } "field_comment" => null "field_similar_book" => Illuminate\Database\Eloquent\Collection {#1108 #items: [] #escapeWhenCastingToString: false } "field_process_formula" => "katex" "field_edition_group" => Illuminate\Database\Eloquent\Collection {#1105 #items: [] #escapeWhenCastingToString: false } "field_content_source" => null ] #original: array:21 [ "id" => 1829 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "title" => "Условие" "field_order" => "1" "field_publisher" => Illuminate\Database\Eloquent\Collection {#1110} "field_content_type" => "free" "field_content_mode" => "text, image" "field_page_content_mode" => "image" "field_content_text_checked" => null "field_page_content_text_checked" => "0" "field_solution_author" => "Автор" "field_moderator" => "vadim" "field_edition_type" => "statement" "field_root_dir" => "0-" "field_responsible" => Illuminate\Database\Eloquent\Collection {#1107} "field_comment" => null "field_similar_book" => Illuminate\Database\Eloquent\Collection {#1108} "field_process_formula" => "katex" "field_edition_group" => Illuminate\Database\Eloquent\Collection {#1105} "field_content_source" => null ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "task" => array:2 [ "refs" => "663305" "type" => "task" ] "text" => "<p><strong>4.</strong> Изобразите схему реакции получения лактама 4-аминомасляной кислоты.</p>" "img" => array:1 [ 0 => array:5 [ "name" => "4-1.jpg" "alt" => null "width" => "844" "height" => 108 "path" => "/media/himiya_10/eremin-u23/0-53/4-1.webp?ts=1738779663" ] ] ] #original: array:7 [ "id" => 819105 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "edition" => Illuminate\Database\Eloquent\Collection {#1103} "task" => array:2 [ "refs" => "663305" "type" => "task" ] "text" => "<p><strong>4.</strong> Изобразите схему реакции получения лактама 4-аминомасляной кислоты.</p>" "img" => array:1 [ 0 => array:5 [ "name" => "4-1.jpg" "alt" => null "width" => "844" "height" => 108 "path" => "/media/himiya_10/eremin-u23/0-53/4-1.webp?ts=1738779663" ] ] ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } 1 => App\Models\Element {#1106 #connection: "mysql" #table: "elements" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:6 [ "id" => 819374 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "edition" => Illuminate\Database\Eloquent\Collection {#1090 #items: array:1 [ 0 => App\Models\Edition {#1104 #connection: "mysql" #table: "editions" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:21 [ "id" => 1830 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "title" => "Решение" "field_order" => "2" "field_publisher" => Illuminate\Database\Eloquent\Collection {#1102 #items: array:1 [ …1] #escapeWhenCastingToString: false } "field_content_type" => "free" "field_content_mode" => "image" "field_page_content_mode" => "" "field_content_text_checked" => "0" "field_page_content_text_checked" => "0" "field_solution_author" => "Ладыко (Торчило)" "field_moderator" => "vadim" "field_edition_type" => "solution" "field_root_dir" => "1-" "field_responsible" => Illuminate\Database\Eloquent\Collection {#1099 #items: [] #escapeWhenCastingToString: false } "field_comment" => null "field_similar_book" => Illuminate\Database\Eloquent\Collection {#1100 #items: [] #escapeWhenCastingToString: false } "field_process_formula" => "" "field_edition_group" => Illuminate\Database\Eloquent\Collection {#1097 #items: [] #escapeWhenCastingToString: false } "field_content_source" => null ] #original: array:21 [ "id" => 1830 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "title" => "Решение" "field_order" => "2" "field_publisher" => Illuminate\Database\Eloquent\Collection {#1102} "field_content_type" => "free" "field_content_mode" => "image" "field_page_content_mode" => "" "field_content_text_checked" => "0" "field_page_content_text_checked" => "0" "field_solution_author" => "Ладыко (Торчило)" "field_moderator" => "vadim" "field_edition_type" => "solution" "field_root_dir" => "1-" "field_responsible" => Illuminate\Database\Eloquent\Collection {#1099} "field_comment" => null "field_similar_book" => Illuminate\Database\Eloquent\Collection {#1100} "field_process_formula" => "" "field_edition_group" => Illuminate\Database\Eloquent\Collection {#1097} "field_content_source" => null ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "task" => array:2 [ "refs" => "663305" "type" => "task" ] "img" => array:1 [ 0 => array:5 [ "name" => "4-1.jpg" "alt" => null "width" => "1422" "height" => 403 "path" => "/media/himiya_10/eremin-u23/1-53/4-1.webp?ts=1738779750" ] ] ] #original: array:6 [ "id" => 819374 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "edition" => Illuminate\Database\Eloquent\Collection {#1090} "task" => array:2 [ "refs" => "663305" "type" => "task" ] "img" => array:1 [ 0 => array:5 [ "name" => "4-1.jpg" "alt" => null "width" => "1422" "height" => 403 "path" => "/media/himiya_10/eremin-u23/1-53/4-1.webp?ts=1738779750" ] ] ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } 2 => App\Models\Element {#1098 #connection: "mysql" #table: "elements" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:6 [ "id" => 1515703 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "edition" => Illuminate\Database\Eloquent\Collection {#1087 #items: array:1 [ 0 => App\Models\Edition {#1096 #connection: "mysql" #table: "editions" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:21 [ "id" => 5553 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "title" => "Решение 2" "field_order" => "3" "field_publisher" => Illuminate\Database\Eloquent\Collection {#1093 #items: array:1 [ …1] #escapeWhenCastingToString: false } "field_content_type" => "free" "field_content_mode" => "text" "field_page_content_mode" => "" "field_content_text_checked" => null "field_page_content_text_checked" => "0" "field_solution_author" => "Gemini 2.5 Pro" "field_moderator" => "tolik" "field_edition_type" => "solution" "field_root_dir" => "2-" "field_responsible" => Illuminate\Database\Eloquent\Collection {#1092 #items: [] #escapeWhenCastingToString: false } "field_comment" => null "field_similar_book" => Illuminate\Database\Eloquent\Collection {#1091 #items: [] #escapeWhenCastingToString: false } "field_process_formula" => "katex" "field_edition_group" => Illuminate\Database\Eloquent\Collection {#1088 #items: [] #escapeWhenCastingToString: false } "field_content_source" => null ] #original: array:21 [ "id" => 5553 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "title" => "Решение 2" "field_order" => "3" "field_publisher" => Illuminate\Database\Eloquent\Collection {#1093} "field_content_type" => "free" "field_content_mode" => "text" "field_page_content_mode" => "" "field_content_text_checked" => null "field_page_content_text_checked" => "0" "field_solution_author" => "Gemini 2.5 Pro" "field_moderator" => "tolik" "field_edition_type" => "solution" "field_root_dir" => "2-" "field_responsible" => Illuminate\Database\Eloquent\Collection {#1092} "field_comment" => null "field_similar_book" => Illuminate\Database\Eloquent\Collection {#1091} "field_process_formula" => "katex" "field_edition_group" => Illuminate\Database\Eloquent\Collection {#1088} "field_content_source" => null ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "task" => array:2 [ "refs" => "663305" "type" => "task" ] "text" => "<p><strong>Решение</strong></p><p>Получение лактама из 4-аминомасляной кислоты — это реакция внутримолекулярной конденсации. Лактамы представляют собой циклические амиды, которые образуются из аминокислот, содержащих амино- и карбоксильную группы на достаточном расстоянии друг от друга для образования стабильного цикла.</p><p>В молекуле 4-аминомасляной кислоты (также известной как γ-аминомасляная кислота или ГАМК) аминогруппа ($ -NH_2 $) находится у четвертого атома углерода, а карбоксильная группа ($ -COOH $) — у первого. При нагревании происходит взаимодействие этих двух функциональных групп внутри одной молекулы.</p><p>В ходе реакции от карбоксильной группы отщепляется гидроксильная группа ($ -OH $), а от аминогруппы — один атом водорода ($ -H $). Эти частицы образуют молекулу воды ($ H_2O $). Между карбонильным атомом углерода и атомом азота образуется новая амидная связь, что приводит к замыканию углеродной цепи в пятичленный гетероцикл. Образовавшийся продукт называется <strong>γ-бутиролактам</strong> (согласно номенклатуре ИЮПАК — <strong>пирролидон-2</strong>).</p><p>Схематически эту реакцию можно изобразить следующим образом:</p><p>$$ \underset{\text{4-аминомасляная кислота}}{H_2N-CH_2-CH_2-CH_2-COOH} \quad \xrightarrow{t^{\circ}} \quad \underset{\text{γ-бутиролактам}}{\text{(пирролидон-2)}} \quad + \quad H_2O $$</p><p><strong>Ответ:</strong></p><p>Схема реакции получения лактама 4-аминомасляной кислоты представляет собой внутримолекулярную конденсацию, которая протекает при нагревании и сопровождается отщеплением молекулы воды и образованием циклического амида (γ-бутиролактама).</p><p>$$ \underset{\text{4-аминомасляная кислота}}{H_2N-CH_2-CH_2-CH_2-COOH} \quad \xrightarrow{t^{\circ}} \quad \underset{\text{γ-бутиролактам}}{\text{циклический амид}} \quad + \quad H_2O $$</p>" ] #original: array:6 [ "id" => 1515703 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "edition" => Illuminate\Database\Eloquent\Collection {#1087} "task" => array:2 [ "refs" => "663305" "type" => "task" ] "text" => "<p><strong>Решение</strong></p><p>Получение лактама из 4-аминомасляной кислоты — это реакция внутримолекулярной конденсации. Лактамы представляют собой циклические амиды, которые образуются из аминокислот, содержащих амино- и карбоксильную группы на достаточном расстоянии друг от друга для образования стабильного цикла.</p><p>В молекуле 4-аминомасляной кислоты (также известной как γ-аминомасляная кислота или ГАМК) аминогруппа ($ -NH_2 $) находится у четвертого атома углерода, а карбоксильная группа ($ -COOH $) — у первого. При нагревании происходит взаимодействие этих двух функциональных групп внутри одной молекулы.</p><p>В ходе реакции от карбоксильной группы отщепляется гидроксильная группа ($ -OH $), а от аминогруппы — один атом водорода ($ -H $). Эти частицы образуют молекулу воды ($ H_2O $). Между карбонильным атомом углерода и атомом азота образуется новая амидная связь, что приводит к замыканию углеродной цепи в пятичленный гетероцикл. Образовавшийся продукт называется <strong>γ-бутиролактам</strong> (согласно номенклатуре ИЮПАК — <strong>пирролидон-2</strong>).</p><p>Схематически эту реакцию можно изобразить следующим образом:</p><p>$$ \underset{\text{4-аминомасляная кислота}}{H_2N-CH_2-CH_2-CH_2-COOH} \quad \xrightarrow{t^{\circ}} \quad \underset{\text{γ-бутиролактам}}{\text{(пирролидон-2)}} \quad + \quad H_2O $$</p><p><strong>Ответ:</strong></p><p>Схема реакции получения лактама 4-аминомасляной кислоты представляет собой внутримолекулярную конденсацию, которая протекает при нагревании и сопровождается отщеплением молекулы воды и образованием циклического амида (γ-бутиролактама).</p><p>$$ \underset{\text{4-аминомасляная кислота}}{H_2N-CH_2-CH_2-CH_2-COOH} \quad \xrightarrow{t^{\circ}} \quad \underset{\text{γ-бутиролактам}}{\text{циклический амид}} \quad + \quad H_2O $$</p>" ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "next" => array:2 [ "refs" => "663306" "type" => "task" ] "previous" => array:2 [ "refs" => "663304" "type" => "task" ] "book" => Illuminate\Database\Eloquent\Collection {#1114 #items: array:1 [ 0 => App\Models\Book {#1049} ] #escapeWhenCastingToString: false } "page" => Illuminate\Database\Eloquent\Collection {#1117 #items: array:1 [ 0 => App\Models\BookPage {#1042 #connection: "mysql" #table: "book_pages" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:21 [ "id" => 926205 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_page_start" => "309" "field_url" => "/10-klass/himiya/eremin-uchebnik/page-309" "field_display_title" => "309" "field_folder" => "1" "field_image_name" => "309" "field_branch_parent" => Illuminate\Database\Eloquent\Collection {#1040 #items: [] #escapeWhenCastingToString: false } "field_weight" => "0" "field_book_parent" => Illuminate\Database\Eloquent\Collection {#1089 #items: array:1 [ 0 => App\Models\Book {#1049} ] #escapeWhenCastingToString: false } "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "edition_groups" => Illuminate\Database\Eloquent\Collection {#1085 #items: [] #escapeWhenCastingToString: false } "content" => Illuminate\Database\Eloquent\Collection {#1125 #items: array:1 [ 0 => App\Models\Element {#1122 #connection: "mysql" #table: "elements" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:6 [ "id" => 1100782 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "edition" => Illuminate\Database\Eloquent\Collection {#1123 …2} "book_page" => array:2 [ …2] "img" => array:1 [ …1] ] #original: array:6 [ "id" => 1100782 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "edition" => Illuminate\Database\Eloquent\Collection {#1123 …2} "book_page" => array:2 [ …2] "img" => array:1 [ …1] ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "next" => array:2 [ "refs" => "926206" "type" => "book_page" ] "previous" => array:2 [ "refs" => "926204" "type" => "book_page" ] "tasks" => Illuminate\Database\Eloquent\Collection {#1213 #items: array:5 [ 0 => App\Models\Task {#1225 #connection: "mysql" #table: "tasks" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:24 [ "id" => 663302 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_page_start" => "309" "field_page_end" => null "field_url" => "/10-klass/himiya/eremin-uchebnik/53-1" "field_display_title" => "1" "field_outside_task" => null "field_task_type" => Illuminate\Database\Eloquent\Collection {#1226 …2} "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "field_match" => null "breadcrumbs" => [] "edition_groups" => Illuminate\Database\Eloquent\Collection {#1227 …2} "top_parent_branch" => Illuminate\Database\Eloquent\Collection {#1228 …2} "parent_branches" => Illuminate\Database\Eloquent\Collection {#1229 …2} "content" => Illuminate\Database\Eloquent\Collection {#1232 …2} "next" => array:2 [ …2] "previous" => array:2 [ …2] "book" => Illuminate\Database\Eloquent\Collection {#1238 …2} "page" => array:2 [ …2] ] #original: array:24 [ "id" => 663302 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_page_start" => "309" "field_page_end" => null "field_url" => "/10-klass/himiya/eremin-uchebnik/53-1" "field_display_title" => "1" "field_outside_task" => null "field_task_type" => Illuminate\Database\Eloquent\Collection {#1226 …2} "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "field_match" => null "breadcrumbs" => [] "edition_groups" => Illuminate\Database\Eloquent\Collection {#1227 …2} "top_parent_branch" => Illuminate\Database\Eloquent\Collection {#1228 …2} "parent_branches" => Illuminate\Database\Eloquent\Collection {#1229 …2} "content" => Illuminate\Database\Eloquent\Collection {#1232 …2} "next" => array:2 [ …2] "previous" => array:2 [ …2] "book" => Illuminate\Database\Eloquent\Collection {#1238 …2} "page" => array:2 [ …2] ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } 1 => App\Models\Task {#1231 #connection: "mysql" #table: "tasks" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:24 [ "id" => 663303 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_page_start" => "309" "field_page_end" => null "field_url" => "/10-klass/himiya/eremin-uchebnik/53-2" "field_display_title" => "2" "field_outside_task" => null "field_task_type" => Illuminate\Database\Eloquent\Collection {#1230 …2} "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "field_match" => null "breadcrumbs" => [] "edition_groups" => Illuminate\Database\Eloquent\Collection {#1237 …2} "top_parent_branch" => Illuminate\Database\Eloquent\Collection {#1239 …2} "parent_branches" => Illuminate\Database\Eloquent\Collection {#1235 …2} "content" => Illuminate\Database\Eloquent\Collection {#1234 …2} "next" => array:2 [ …2] "previous" => array:2 [ …2] "book" => Illuminate\Database\Eloquent\Collection {#1252 …2} "page" => array:2 [ …2] ] #original: array:24 [ "id" => 663303 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_page_start" => "309" "field_page_end" => null "field_url" => "/10-klass/himiya/eremin-uchebnik/53-2" "field_display_title" => "2" "field_outside_task" => null "field_task_type" => Illuminate\Database\Eloquent\Collection {#1230 …2} "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "field_match" => null "breadcrumbs" => [] "edition_groups" => Illuminate\Database\Eloquent\Collection {#1237 …2} "top_parent_branch" => Illuminate\Database\Eloquent\Collection {#1239 …2} "parent_branches" => Illuminate\Database\Eloquent\Collection {#1235 …2} "content" => Illuminate\Database\Eloquent\Collection {#1234 …2} "next" => array:2 [ …2] "previous" => array:2 [ …2] "book" => Illuminate\Database\Eloquent\Collection {#1252 …2} "page" => array:2 [ …2] ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } 2 => App\Models\Task {#1236 #connection: "mysql" #table: "tasks" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:24 [ "id" => 663304 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_page_start" => "309" "field_page_end" => null "field_url" => "/10-klass/himiya/eremin-uchebnik/53-3" "field_display_title" => "3" "field_outside_task" => null "field_task_type" => Illuminate\Database\Eloquent\Collection {#1233 …2} "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "field_match" => null "breadcrumbs" => [] "edition_groups" => Illuminate\Database\Eloquent\Collection {#1251 …2} "top_parent_branch" => Illuminate\Database\Eloquent\Collection {#1253 …2} "parent_branches" => Illuminate\Database\Eloquent\Collection {#1249 …2} "content" => Illuminate\Database\Eloquent\Collection {#1248 …2} "next" => array:2 [ …2] "previous" => array:2 [ …2] "book" => Illuminate\Database\Eloquent\Collection {#1266 …2} "page" => array:2 [ …2] ] #original: array:24 [ "id" => 663304 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_page_start" => "309" "field_page_end" => null "field_url" => "/10-klass/himiya/eremin-uchebnik/53-3" "field_display_title" => "3" "field_outside_task" => null "field_task_type" => Illuminate\Database\Eloquent\Collection {#1233 …2} "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "field_match" => null "breadcrumbs" => [] "edition_groups" => Illuminate\Database\Eloquent\Collection {#1251 …2} "top_parent_branch" => Illuminate\Database\Eloquent\Collection {#1253 …2} "parent_branches" => Illuminate\Database\Eloquent\Collection {#1249 …2} "content" => Illuminate\Database\Eloquent\Collection {#1248 …2} "next" => array:2 [ …2] "previous" => array:2 [ …2] "book" => Illuminate\Database\Eloquent\Collection {#1266 …2} "page" => array:2 [ …2] ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } 3 => App\Models\Task {#1250 #connection: "mysql" #table: "tasks" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:24 [ "id" => 663305 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_page_start" => "309" "field_page_end" => null "field_url" => "/10-klass/himiya/eremin-uchebnik/53-4" "field_display_title" => "4" "field_outside_task" => null "field_task_type" => Illuminate\Database\Eloquent\Collection {#1247 …2} "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "field_match" => null "breadcrumbs" => [] "edition_groups" => Illuminate\Database\Eloquent\Collection {#1265 …2} "top_parent_branch" => Illuminate\Database\Eloquent\Collection {#1267 …2} "parent_branches" => Illuminate\Database\Eloquent\Collection {#1263 …2} "content" => Illuminate\Database\Eloquent\Collection {#1261 …2} "next" => array:2 [ …2] "previous" => array:2 [ …2] "book" => Illuminate\Database\Eloquent\Collection {#1264 …2} "page" => array:2 [ …2] ] #original: array:24 [ "id" => 663305 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_page_start" => "309" "field_page_end" => null "field_url" => "/10-klass/himiya/eremin-uchebnik/53-4" "field_display_title" => "4" "field_outside_task" => null "field_task_type" => Illuminate\Database\Eloquent\Collection {#1247 …2} "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "field_match" => null "breadcrumbs" => [] "edition_groups" => Illuminate\Database\Eloquent\Collection {#1265 …2} "top_parent_branch" => Illuminate\Database\Eloquent\Collection {#1267 …2} "parent_branches" => Illuminate\Database\Eloquent\Collection {#1263 …2} "content" => Illuminate\Database\Eloquent\Collection {#1261 …2} "next" => array:2 [ …2] "previous" => array:2 [ …2] "book" => Illuminate\Database\Eloquent\Collection {#1264 …2} "page" => array:2 [ …2] ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } 4 => App\Models\Task {#1262 #connection: "mysql" #table: "tasks" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:24 [ "id" => 663306 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=> null "field_page_start" => "309" "field_page_end" => "310" "field_url" => "/10-klass/himiya/eremin-uchebnik/53-5" "field_display_title" => "5" "field_outside_task" => "0" "field_task_type" => Illuminate\Database\Eloquent\Collection {#1275 …2} "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "field_match" => null "breadcrumbs" => [] "edition_groups" => Illuminate\Database\Eloquent\Collection {#1276 …2} "top_parent_branch" => Illuminate\Database\Eloquent\Collection {#1277 …2} "parent_branches" => Illuminate\Database\Eloquent\Collection {#1278 …2} "content" => Illuminate\Database\Eloquent\Collection {#1281 …2} "next" => array:2 [ …2] "previous" => array:2 [ …2] "book" => Illuminate\Database\Eloquent\Collection {#1287 …2} "page" => array:2 [ …2] ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } ] #original: array:21 [ "id" => 926205 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_page_start" => "309" "field_url" => "/10-klass/himiya/eremin-uchebnik/page-309" "field_display_title" => "309" "field_folder" => "1" "field_image_name" => "309" "field_branch_parent" => Illuminate\Database\Eloquent\Collection {#1040} "field_weight" => "0" "field_book_parent" => Illuminate\Database\Eloquent\Collection {#1089} "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "edition_groups" => Illuminate\Database\Eloquent\Collection {#1085} "content" => Illuminate\Database\Eloquent\Collection {#1125} "next" => array:2 [ "refs" => "926206" "type" => "book_page" ] "previous" => array:2 [ "refs" => "926204" "type" => "book_page" ] "tasks" => Illuminate\Database\Eloquent\Collection {#1213} ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } ] #original: array:24 [ "id" => 663305 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_page_start" => "309" "field_page_end" => null "field_url" => "/10-klass/himiya/eremin-uchebnik/53-4" "field_display_title" => "4" "field_outside_task" => null "field_task_type" => Illuminate\Database\Eloquent\Collection {#1037} "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "field_match" => null "breadcrumbs" => [] "edition_groups" => Illuminate\Database\Eloquent\Collection {#1035} 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№4 (с. 309)
Условие. №4 (с. 309)
скриншот условия
4. Изобразите схему реакции получения лактама 4-аминомасляной кислоты.
Решение. №4 (с. 309)
Решение 2. №4 (с. 309)
Решение
Получение лактама из 4-аминомасляной кислоты — это реакция внутримолекулярной конденсации. Лактамы представляют собой циклические амиды, которые образуются из аминокислот, содержащих амино- и карбоксильную группы на достаточном расстоянии друг от друга для образования стабильного цикла.
В молекуле 4-аминомасляной кислоты (также известной как γ-аминомасляная кислота или ГАМК) аминогруппа ($ -NH_2 $) находится у четвертого атома углерода, а карбоксильная группа ($ -COOH $) — у первого. При нагревании происходит взаимодействие этих двух функциональных групп внутри одной молекулы.
В ходе реакции от карбоксильной группы отщепляется гидроксильная группа ($ -OH $), а от аминогруппы — один атом водорода ($ -H $). Эти частицы образуют молекулу воды ($ H_2O $). Между карбонильным атомом углерода и атомом азота образуется новая амидная связь, что приводит к замыканию углеродной цепи в пятичленный гетероцикл. Образовавшийся продукт называется γ-бутиролактам (согласно номенклатуре ИЮПАК — пирролидон-2).
Схематически эту реакцию можно изобразить следующим образом:
$$ \underset{\text{4-аминомасляная кислота}}{H_2N-CH_2-CH_2-CH_2-COOH} \quad \xrightarrow{t^{\circ}} \quad \underset{\text{γ-бутиролактам}}{\text{(пирролидон-2)}} \quad + \quad H_2O $$
Ответ:
Схема реакции получения лактама 4-аминомасляной кислоты представляет собой внутримолекулярную конденсацию, которая протекает при нагревании и сопровождается отщеплением молекулы воды и образованием циклического амида (γ-бутиролактама).
$$ \underset{\text{4-аминомасляная кислота}}{H_2N-CH_2-CH_2-CH_2-COOH} \quad \xrightarrow{t^{\circ}} \quad \underset{\text{γ-бутиролактам}}{\text{циклический амид}} \quad + \quad H_2O $$
Другие задания:
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