gdz.top
Номер 2, страница 317 - гдз по химии 10 класс учебник Еремин, Кузьменко
Авторы: Еремин В. В., Кузьменко Н. Е., Теренин В. И., Дроздов А. А., Лунин В. В.
Тип: Учебник
Издательство: Просвещение
Год издания: 2023 - 2026
Уровень обучения: углублённый
Цвет обложки: белый, зелёный с радугой
Допущено Министерством просвещения Российской Федерации
Популярные ГДЗ в 10 классе
Глава 5. Азот- и серосодержащие органические соединения. Параграф 54. Ароматические амины. Диазосоединения - номер 2, страница 317.
App\Models\Task {#1030 // resources/views/models/task/default.blade.php #connection: "mysql" #table: "tasks" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:24 [ "id" => 663311 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_page_start" => "317" "field_page_end" => null "field_url" => "/10-klass/himiya/eremin-uchebnik/54-2" "field_display_title" => "2" "field_outside_task" => null "field_task_type" => Illuminate\Database\Eloquent\Collection {#1037 #items: array:1 [ 0 => App\Models\Term {#1036 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:6 [ "id" => 26 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "номер" "field_cases" => array:6 [ "field_accusative_case" => "номер" "field_creative_case" => "номером" "field_dative_case" => "номеру" "field_genitive_case" => "номера" "field_nominative_case" => "номер" "field_prepositional_case" => "номере" ] "field_short_name" => "№" ] #original: array:6 [ "id" => 26 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "номер" "field_cases" => array:6 [ "field_accusative_case" => "номер" "field_creative_case" => "номером" "field_dative_case" => "номеру" "field_genitive_case" => "номера" "field_nominative_case" => "номер" "field_prepositional_case" => "номере" ] "field_short_name" => "№" ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "field_match" => null "breadcrumbs" => [] "edition_groups" => Illuminate\Database\Eloquent\Collection {#1035 #items: [] #escapeWhenCastingToString: false } "top_parent_branch" => Illuminate\Database\Eloquent\Collection {#1046 #items: array:1 [ 0 => App\Models\Branch {#1045 #connection: "mysql" #table: "branches" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:24 [ "id" => 662753 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_display_title" => "Азот- и серосодержащие органические соединения" "field_branch_order" => "5" "field_url" => null "field_branch_type" => Illuminate\Database\Eloquent\Collection {#1050 #items: array:1 [ 0 => App\Models\Term {#1047 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:7 [ "id" => 29 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Глава" "field_cases" => array:6 [ …6] "field_page_check_not_needed" => null "field_short_name" => null ] #original: array:7 [ "id" => 29 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Глава" "field_cases" => array:6 [ …6] "field_page_check_not_needed" => null "field_short_name" => null ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "field_page_start" => "300" "field_branch_display" => "0" "field_branch_expanded" => "0" "field_display_branch_in_title" => "1" "field_display_task_interval" => "0" "field_display_branch_page" => "1" "field_branch_title_in_content" => "0" "field_navigation_title" => null "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "field_branch_cover" => [] "field_branch_covers" => [] "book" => Illuminate\Database\Eloquent\Collection {#1086 #items: array:1 [ 0 => App\Models\Book {#1049 #connection: "mysql" #table: "books" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:50 [ "id" => 1003 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_tree_default_status" => "tasks" "field_pages_status" => null "field_subject" => Illuminate\Database\Eloquent\Collection {#1051 #items: array:1 [ 0 => App\Models\Term {#1048 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:10 [ "id" => 6495 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Химия" "field_abbreviated_name" => null "field_cases" => array:6 [ …6] "field_foreign_lang_name" => null "field_short_name" => null "field_subject_type" => "technical_subject" "field_translit" => "himiya" ] #original: array:10 [ "id" => 6495 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Химия" "field_abbreviated_name" => null "field_cases" => array:6 [ …6] "field_foreign_lang_name" => null "field_short_name" => null "field_subject_type" => "technical_subject" "field_translit" => "himiya" ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "field_class" => Illuminate\Database\Eloquent\Collection {#1052 #items: array:1 [ 0 => App\Models\Term {#1053 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:6 [ "id" => 5459 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "10" "field_cases" => array:6 [ …6] "field_translit" => "desjatyj" ] #original: array:6 [ "id" => 5459 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "10" "field_cases" => array:6 [ …6] "field_translit" => "desjatyj" ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "field_publisher" => Illuminate\Database\Eloquent\Collection {#1054 #items: array:1 [ 0 => App\Models\Term {#1055 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:6 [ "id" => 5153 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Просвещение" "field_cases" => null "field_translit" => "prosveschenie" ] #original: array:6 [ "id" => 5153 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Просвещение" "field_cases" => null "field_translit" => "prosveschenie" ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "field_author" => Illuminate\Database\Eloquent\Collection {#1056 #items: array:5 [ 0 => App\Models\Term {#1057 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:12 [ "id" => 4330 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Еремин" "field_bio" => null "field_degree_rp" => null "field_foreign_lang_name" => null "field_foreign_lang_patronymic" => null "field_foreign_lang_surname" => null "field_name" => "Вадим" "field_patronymic" => "Владимирович" "field_surname_rp" => null ] #original: array:12 [ "id" => 4330 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Еремин" "field_bio" => null "field_degree_rp" => null "field_foreign_lang_name" => null "field_foreign_lang_patronymic" => null "field_foreign_lang_surname" => null "field_name" => "Вадим" "field_patronymic" => "Владимирович" "field_surname_rp" => null ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } 1 => App\Models\Term {#1058 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:12 [ "id" => 4876 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Кузьменко" "field_bio" => null "field_degree_rp" => null "field_foreign_lang_name" => null "field_foreign_lang_patronymic" => null "field_foreign_lang_surname" => null "field_name" => "Николай" "field_patronymic" => "Егорович" "field_surname_rp" => null ] #original: array:12 [ "id" => 4876 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Кузьменко" "field_bio" => null "field_degree_rp" => null "field_foreign_lang_name" => null "field_foreign_lang_patronymic" => null "field_foreign_lang_surname" => null "field_name" => "Николай" "field_patronymic" => "Егорович" "field_surname_rp" => null ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } 2 => App\Models\Term {#1059 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:12 [ "id" => 5912 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Теренин" "field_bio" => null "field_degree_rp" => null "field_foreign_lang_name" => null "field_foreign_lang_patronymic" => null "field_foreign_lang_surname" => null "field_name" => "Владимир" "field_patronymic" => "Ильич" "field_surname_rp" => null ] #original: array:12 [ "id" => 5912 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Теренин" "field_bio" => null "field_degree_rp" => null "field_foreign_lang_name" => null "field_foreign_lang_patronymic" => null "field_foreign_lang_surname" => null "field_name" => "Владимир" "field_patronymic" => "Ильич" "field_surname_rp" => null ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } 3 => App\Models\Term {#1060 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:12 [ "id" => 4290 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Дроздов" "field_bio" => null "field_degree_rp" => null "field_foreign_lang_name" => null "field_foreign_lang_patronymic" => null "field_foreign_lang_surname" => null "field_name" => "Андрей" "field_patronymic" => "Анатольевич" "field_surname_rp" => null ] #original: array:12 [ "id" => 4290 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Дроздов" "field_bio" => null "field_degree_rp" => null "field_foreign_lang_name" => null "field_foreign_lang_patronymic" => null "field_foreign_lang_surname" => null "field_name" => "Андрей" "field_patronymic" => "Анатольевич" "field_surname_rp" => null ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } 4 => App\Models\Term {#1061 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:12 [ "id" => 5031 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Лунин" "field_bio" => null "field_degree_rp" => "доктор химических наук, академика РАН" "field_foreign_lang_name" => null "field_foreign_lang_patronymic" => null "field_foreign_lang_surname" => null "field_name" => "Валерий" "field_patronymic" => "Васильевич" "field_surname_rp" => "Лунина" ] #original: array:12 [ "id" => 5031 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Лунин" "field_bio" => null "field_degree_rp" => "доктор химических наук, академика РАН" "field_foreign_lang_name" => null "field_foreign_lang_patronymic" => null "field_foreign_lang_surname" => null "field_name" => "Валерий" "field_patronymic" => "Васильевич" "field_surname_rp" => "Лунина" ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "field_author_foreign" => Illuminate\Database\Eloquent\Collection {#1062 #items: [] #escapeWhenCastingToString: false } "field_book_type" => Illuminate\Database\Eloquent\Collection {#1063 #items: array:1 [ 0 => App\Models\Term {#1064 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:10 [ "id" => 6671 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Учебник" "field_book_type_foreign" => null "field_cases" => array:6 [ …6] "field_plural_form" => null "field_short_name" => null "field_short_name_foreign" => null "field_translit" => "uchebnik" ] #original: array:10 [ "id" => 6671 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Учебник" "field_book_type_foreign" => null "field_cases" => array:6 [ …6] "field_plural_form" => null "field_short_name" => null "field_short_name_foreign" => null "field_translit" => "uchebnik" ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "field_country" => Illuminate\Database\Eloquent\Collection {#1065 #items: array:1 [ 0 => App\Models\Term {#1066 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:6 [ "id" => 9 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Россия" "field_cases" => array:6 [ …6] "field_translit" => "rossiya" ] #original: array:6 [ "id" => 9 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Россия" "field_cases" => array:6 [ …6] "field_translit" => "rossiya" ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "field_city" => Illuminate\Database\Eloquent\Collection {#1067 #items: array:1 [ 0 => App\Models\Term {#1068 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:6 [ "id" => 15 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Москва" "field_cases" => array:6 [ …6] "field_translit" => "moskva" ] #original: array:6 [ "id" => 15 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Москва" "field_cases" => array:6 [ …6] "field_translit" => "moskva" ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "field_series" => Illuminate\Database\Eloquent\Collection {#1069 #items: [] #escapeWhenCastingToString: false } "field_umk" => Illuminate\Database\Eloquent\Collection {#1070 #items: [] #escapeWhenCastingToString: false } "field_level_of_education" => Illuminate\Database\Eloquent\Collection {#1071 #items: array:1 [ 0 => App\Models\Term {#1072 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:6 [ "id" => 39 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "углублённый" "field_cases" => array:6 [ …6] "field_translit" => "uglublennyy" ] #original: array:6 [ "id" => 39 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "углублённый" "field_cases" => array:6 [ …6] "field_translit" => "uglublennyy" ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "field_standart_of_education" => Illuminate\Database\Eloquent\Collection {#1073 #items: array:1 [ 0 => App\Models\Term {#1074 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:10 [ "id" => 6706 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "ФГОС (старый)" "field_cases" => array:6 [ …6] "field_color" => null "field_end_year" => "2022" "field_start_year" => "2019" "field_translit" => "fgos-old" "field_type" => null ] #original: array:10 [ "id" => 6706 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "ФГОС (старый)" "field_cases" => array:6 [ …6] "field_color" => null "field_end_year" => "2022" "field_start_year" => "2019" "field_translit" => "fgos-old" "field_type" => null ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "field_publication_number" => "10" "field_publication_type" => Illuminate\Database\Eloquent\Collection {#1075 #items: array:1 [ 0 => App\Models\Term {#1076 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:6 [ "id" => 33 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "стереотипное" "field_cases" => array:6 [ …6] "field_translit" => "stereotipnoe" ] #original: array:6 [ "id" => 33 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "стереотипное" "field_cases" => array:6 [ …6] "field_translit" => "stereotipnoe" ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "field_under_the_edition" => Illuminate\Database\Eloquent\Collection {#1077 #items: array:1 [ 0 => App\Models\Term {#1061} ] #escapeWhenCastingToString: false } "field_under_the_edition_degree" => "доктор химических наук, академика РАН" "field_cover_description" => "с радугой" "field_publication_year" => "2023" "field_publication_year_until" => null "field_part" => "" "field_part_writing" => "" "field_second_foreign_language" => null "field_for_whom" => null "field_allowed" => "Допущено Министерством просвещения Российской Федерации" "field_reserve_field" => null "field_link_to_source" => null "field_tasks_count" => "697" "field_priority" => "10" "field_default_folder" => "/himiya_10/eremin-u23/" "field_isbn" => null "field_cover" => array:1 [ 0 => "/media/himiya_10/eremin-u23/covers/cover1.webp?ts=1738768732" ] "field_cover_alts" => array:1 [ 0 => "" ] "field_covers" => array:1 [ 0 => array:4 [ "path" => "/media/himiya_10/eremin-u23/covers/cover1.webp?ts=1738768732" "alt" => "" "width" => "1200" "height" => "1576" ] ] "field_popular_book" => null "field_recommended_books" => Illuminate\Database\Eloquent\Collection {#1078 #items: [] #escapeWhenCastingToString: false } "field_new_book" => Illuminate\Database\Eloquent\Collection {#1079 #items: [] #escapeWhenCastingToString: false } "field_old_book" => Illuminate\Database\Eloquent\Collection {#1080 #items: [] #escapeWhenCastingToString: false } "field_url" => "/10-klass/himiya/eremin-uchebnik" "field_cover_color" => Illuminate\Database\Eloquent\Collection {#1081 #items: array:2 [ 0 => App\Models\Term {#1082 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:6 [ "id" => 45 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "белый" "field_cases" => array:6 [ …6] "field_translit" => "belyy" ] #original: array:6 [ "id" => 45 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "белый" "field_cases" => array:6 [ …6] "field_translit" => "belyy" ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } 1 => App\Models\Term {#1083 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:6 [ "id" => 47 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "зелёный" "field_cases" => array:6 [ …6] "field_translit" => "zelyonyy" ] #original: array:6 [ "id" => 47 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "зелёный" "field_cases" => array:6 [ …6] "field_translit" => "zelyonyy" ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "breadcrumbs" => array:3 [ "class" => 381 "subject" => 558 "class_subject" => 500 ] ] #original: array:50 [ "id" => 1003 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_tree_default_status" => "tasks" "field_pages_status" => null "field_subject" => Illuminate\Database\Eloquent\Collection {#1051} "field_class" => Illuminate\Database\Eloquent\Collection {#1052} "field_publisher" => Illuminate\Database\Eloquent\Collection {#1054} "field_author" => Illuminate\Database\Eloquent\Collection {#1056} "field_author_foreign" => Illuminate\Database\Eloquent\Collection {#1062} "field_book_type" => Illuminate\Database\Eloquent\Collection {#1063} "field_country" => Illuminate\Database\Eloquent\Collection {#1065} "field_city" => Illuminate\Database\Eloquent\Collection {#1067} "field_series" => Illuminate\Database\Eloquent\Collection {#1069} "field_umk" => Illuminate\Database\Eloquent\Collection {#1070} "field_level_of_education" => Illuminate\Database\Eloquent\Collection {#1071} "field_standart_of_education" => Illuminate\Database\Eloquent\Collection {#1073} "field_publication_number" => "10" "field_publication_type" => Illuminate\Database\Eloquent\Collection {#1075} "field_under_the_edition" => Illuminate\Database\Eloquent\Collection {#1077} "field_under_the_edition_degree" => "доктор химических наук, академика РАН" "field_cover_description" => "с радугой" "field_publication_year" => "2023" "field_publication_year_until" => null "field_part" => "" "field_part_writing" => "" "field_second_foreign_language" => null "field_for_whom" => null "field_allowed" => "Допущено Министерством просвещения Российской Федерации" "field_reserve_field" => null "field_link_to_source" => null "field_tasks_count" => "697" "field_priority" => "10" "field_default_folder" => "/himiya_10/eremin-u23/" "field_isbn" => null "field_cover" => array:1 [ 0 => "/media/himiya_10/eremin-u23/covers/cover1.webp?ts=1738768732" ] "field_cover_alts" => array:1 [ 0 => "" ] "field_covers" => array:1 [ 0 => array:4 [ "path" => "/media/himiya_10/eremin-u23/covers/cover1.webp?ts=1738768732" "alt" => "" "width" => "1200" "height" => "1576" ] ] "field_popular_book" => null "field_recommended_books" => Illuminate\Database\Eloquent\Collection {#1078} "field_new_book" => Illuminate\Database\Eloquent\Collection {#1079} "field_old_book" => Illuminate\Database\Eloquent\Collection {#1080} "field_url" => "/10-klass/himiya/eremin-uchebnik" "field_cover_color" => Illuminate\Database\Eloquent\Collection {#1081} "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "breadcrumbs" => array:3 [ "class" => 381 "subject" => 558 "class_subject" => 500 ] ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "branch_parent" => Illuminate\Database\Eloquent\Collection {#1084 #items: [] #escapeWhenCastingToString: false } ] #original: array:24 [ "id" => 662753 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_display_title" => "Азот- и серосодержащие органические соединения" "field_branch_order" => "5" "field_url" => null "field_branch_type" => Illuminate\Database\Eloquent\Collection {#1050} "field_page_start" => "300" "field_branch_display" => "0" "field_branch_expanded" => "0" "field_display_branch_in_title" => "1" "field_display_task_interval" => "0" "field_display_branch_page" => "1" "field_branch_title_in_content" => "0" "field_navigation_title" => null "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "field_branch_cover" => [] "field_branch_covers" => [] "book" => Illuminate\Database\Eloquent\Collection {#1086} "branch_parent" => Illuminate\Database\Eloquent\Collection {#1084} ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "parent_branches" => Illuminate\Database\Eloquent\Collection {#1121 #items: array:2 [ 0 => App\Models\Branch {#1129 #connection: "mysql" #table: "branches" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:24 [ "id" => 662753 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_display_title" => "Азот- и серосодержащие органические соединения" "field_branch_order" => "5" "field_url" => null "field_branch_type" => Illuminate\Database\Eloquent\Collection {#1130 #items: array:1 [ 0 => App\Models\Term {#1047} ] #escapeWhenCastingToString: false } "field_page_start" => "300" "field_branch_display" => "0" "field_branch_expanded" => "0" "field_display_branch_in_title" => "1" "field_display_task_interval" => "0" "field_display_branch_page" => "1" "field_branch_title_in_content" => "0" "field_navigation_title" => null "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "field_branch_cover" => [] "field_branch_covers" => [] "book" => Illuminate\Database\Eloquent\Collection {#1131 #items: array:1 [ 0 => App\Models\Book {#1049} ] #escapeWhenCastingToString: false } "branch_parent" => Illuminate\Database\Eloquent\Collection {#1132 #items: [] #escapeWhenCastingToString: false } ] #original: array:24 [ "id" => 662753 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_display_title" => "Азот- и серосодержащие органические соединения" "field_branch_order" => "5" "field_url" => null "field_branch_type" => Illuminate\Database\Eloquent\Collection {#1130} "field_page_start" => "300" "field_branch_display" => "0" "field_branch_expanded" => "0" "field_display_branch_in_title" => "1" "field_display_task_interval" => "0" "field_display_branch_page" => "1" "field_branch_title_in_content" => "0" "field_navigation_title" => null "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "field_branch_cover" => [] "field_branch_covers" => [] "book" => Illuminate\Database\Eloquent\Collection {#1131} "branch_parent" => Illuminate\Database\Eloquent\Collection {#1132} ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } 1 => App\Models\Branch {#1133 #connection: "mysql" #table: "branches" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:24 [ "id" => 662756 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_display_title" => "Ароматические амины. Диазосоединения" "field_branch_order" => "54" "field_url" => null "field_branch_type" => Illuminate\Database\Eloquent\Collection {#1137 #items: array:1 [ 0 => App\Models\Term {#1134 #connection: "mysql" #table: "terms" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:7 [ "id" => 32 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Параграф" "field_cases" => array:6 [ …6] "field_page_check_not_needed" => null "field_short_name" => "§" ] #original: array:7 [ "id" => 32 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "name" => "Параграф" "field_cases" => array:6 [ …6] "field_page_check_not_needed" => null "field_short_name" => "§" ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "field_page_start" => "310" "field_branch_display" => "0" "field_branch_expanded" => "0" "field_display_branch_in_title" => "1" "field_display_task_interval" => "0" "field_display_branch_page" => "1" "field_branch_title_in_content" => "0" "field_navigation_title" => null "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "field_branch_cover" => [] "field_branch_covers" => [] "book" => Illuminate\Database\Eloquent\Collection {#1136 #items: array:1 [ 0 => App\Models\Book {#1049} ] #escapeWhenCastingToString: false } "branch_parent" => Illuminate\Database\Eloquent\Collection {#1135 #items: array:1 [ 0 => App\Models\Branch {#1045} ] #escapeWhenCastingToString: false } ] #original: array:24 [ "id" => 662756 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_display_title" => "Ароматические амины. Диазосоединения" "field_branch_order" => "54" "field_url" => null "field_branch_type" => Illuminate\Database\Eloquent\Collection {#1137} "field_page_start" => "310" "field_branch_display" => "0" "field_branch_expanded" => "0" "field_display_branch_in_title" => "1" "field_display_task_interval" => "0" "field_display_branch_page" => "1" "field_branch_title_in_content" => "0" "field_navigation_title" => null "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "field_branch_cover" => [] "field_branch_covers" => [] "book" => Illuminate\Database\Eloquent\Collection {#1136} "branch_parent" => Illuminate\Database\Eloquent\Collection {#1135} ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "content" => Illuminate\Database\Eloquent\Collection {#1118 #items: array:3 [ 0 => App\Models\Element {#1111 #connection: "mysql" #table: "elements" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:7 [ "id" => 819116 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "edition" => Illuminate\Database\Eloquent\Collection {#1103 #items: array:1 [ 0 => App\Models\Edition {#1095 #connection: "mysql" #table: "editions" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:21 [ "id" => 1829 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "title" => "Условие" "field_order" => "1" "field_publisher" => Illuminate\Database\Eloquent\Collection {#1110 …2} "field_content_type" => "free" "field_content_mode" => "text, image" "field_page_content_mode" => "image" "field_content_text_checked" => null "field_page_content_text_checked" => "0" "field_solution_author" => "Автор" "field_moderator" => "vadim" "field_edition_type" => "statement" "field_root_dir" => "0-" "field_responsible" => Illuminate\Database\Eloquent\Collection {#1107 …2} "field_comment" => null "field_similar_book" => Illuminate\Database\Eloquent\Collection {#1108 …2} "field_process_formula" => "katex" "field_edition_group" => Illuminate\Database\Eloquent\Collection {#1105 …2} "field_content_source" => null ] #original: array:21 [ "id" => 1829 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "title" => "Условие" "field_order" => "1" "field_publisher" => Illuminate\Database\Eloquent\Collection {#1110 …2} "field_content_type" => "free" "field_content_mode" => "text, image" "field_page_content_mode" => "image" "field_content_text_checked" => null "field_page_content_text_checked" => "0" "field_solution_author" => "Автор" "field_moderator" => "vadim" "field_edition_type" => "statement" "field_root_dir" => "0-" "field_responsible" => Illuminate\Database\Eloquent\Collection {#1107 …2} "field_comment" => null "field_similar_book" => Illuminate\Database\Eloquent\Collection {#1108 …2} "field_process_formula" => "katex" "field_edition_group" => Illuminate\Database\Eloquent\Collection {#1105 …2} "field_content_source" => null ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "task" => array:2 [ "refs" => "663311" "type" => "task" ] "text" => "<p><strong>2.</strong> Почему анилин при хранении на воздухе темнеет?</p>" "img" => array:1 [ 0 => array:5 [ "name" => "2-1.jpg" "alt" => null "width" => "856" "height" => 73 "path" => "/media/himiya_10/eremin-u23/0-54/2-1.webp?ts=1738779663" ] ] ] #original: array:7 [ "id" => 819116 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "edition" => Illuminate\Database\Eloquent\Collection {#1103} "task" => array:2 [ "refs" => "663311" "type" => "task" ] "text" => "<p><strong>2.</strong> Почему анилин при хранении на воздухе темнеет?</p>" "img" => array:1 [ 0 => array:5 [ "name" => "2-1.jpg" "alt" => null "width" => "856" "height" => 73 "path" => "/media/himiya_10/eremin-u23/0-54/2-1.webp?ts=1738779663" ] ] ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } 1 => App\Models\Element {#1106 #connection: "mysql" #table: "elements" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:6 [ "id" => 819389 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "edition" => Illuminate\Database\Eloquent\Collection {#1090 #items: array:1 [ 0 => App\Models\Edition {#1104 #connection: "mysql" #table: "editions" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:21 [ "id" => 1830 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "title" => "Решение" "field_order" => "2" "field_publisher" => Illuminate\Database\Eloquent\Collection {#1102 …2} "field_content_type" => "free" "field_content_mode" => "image" "field_page_content_mode" => "" "field_content_text_checked" => "0" "field_page_content_text_checked" => "0" "field_solution_author" => "Ладыко (Торчило)" "field_moderator" => "vadim" "field_edition_type" => "solution" "field_root_dir" => "1-" "field_responsible" => Illuminate\Database\Eloquent\Collection {#1099 …2} "field_comment" => null "field_similar_book" => Illuminate\Database\Eloquent\Collection {#1100 …2} "field_process_formula" => "" "field_edition_group" => Illuminate\Database\Eloquent\Collection {#1097 …2} "field_content_source" => null ] #original: array:21 [ "id" => 1830 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "title" => "Решение" "field_order" => "2" "field_publisher" => Illuminate\Database\Eloquent\Collection {#1102 …2} "field_content_type" => "free" "field_content_mode" => "image" "field_page_content_mode" => "" "field_content_text_checked" => "0" "field_page_content_text_checked" => "0" "field_solution_author" => "Ладыко (Торчило)" "field_moderator" => "vadim" "field_edition_type" => "solution" "field_root_dir" => "1-" "field_responsible" => Illuminate\Database\Eloquent\Collection {#1099 …2} "field_comment" => null "field_similar_book" => Illuminate\Database\Eloquent\Collection {#1100 …2} "field_process_formula" => "" "field_edition_group" => Illuminate\Database\Eloquent\Collection {#1097 …2} "field_content_source" => null ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "task" => array:2 [ "refs" => "663311" "type" => "task" ] "img" => array:1 [ 0 => array:5 [ "name" => "2-1.jpg" "alt" => null "width" => "1930" "height" => 219 "path" => "/media/himiya_10/eremin-u23/1-54/2-1.webp?ts=1738779750" ] ] ] #original: array:6 [ "id" => 819389 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "edition" => Illuminate\Database\Eloquent\Collection {#1090} "task" => array:2 [ "refs" => "663311" "type" => "task" ] "img" => array:1 [ 0 => array:5 [ "name" => "2-1.jpg" "alt" => null "width" => "1930" "height" => 219 "path" => "/media/himiya_10/eremin-u23/1-54/2-1.webp?ts=1738779750" ] ] ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } 2 => App\Models\Element {#1098 #connection: "mysql" #table: "elements" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:6 [ "id" => 1515709 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "edition" => Illuminate\Database\Eloquent\Collection {#1087 #items: array:1 [ 0 => App\Models\Edition {#1096 #connection: "mysql" #table: "editions" #primaryKey: "id" #keyType: "int" +incrementing: false #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:21 [ "id" => 5553 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "title" => "Решение 2" "field_order" => "3" "field_publisher" => Illuminate\Database\Eloquent\Collection {#1093 …2} "field_content_type" => "free" "field_content_mode" => "text" "field_page_content_mode" => "" "field_content_text_checked" => null "field_page_content_text_checked" => "0" "field_solution_author" => "Gemini 2.5 Pro" "field_moderator" => "tolik" "field_edition_type" => "solution" "field_root_dir" => "2-" "field_responsible" => Illuminate\Database\Eloquent\Collection {#1092 …2} "field_comment" => null "field_similar_book" => Illuminate\Database\Eloquent\Collection {#1091 …2} "field_process_formula" => "katex" "field_edition_group" => Illuminate\Database\Eloquent\Collection {#1088 …2} "field_content_source" => null ] #original: array:21 [ "id" => 5553 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "title" => "Решение 2" "field_order" => "3" "field_publisher" => Illuminate\Database\Eloquent\Collection {#1093 …2} "field_content_type" => "free" "field_content_mode" => "text" "field_page_content_mode" => "" "field_content_text_checked" => null "field_page_content_text_checked" => "0" "field_solution_author" => "Gemini 2.5 Pro" "field_moderator" => "tolik" "field_edition_type" => "solution" "field_root_dir" => "2-" "field_responsible" => Illuminate\Database\Eloquent\Collection {#1092 …2} "field_comment" => null "field_similar_book" => Illuminate\Database\Eloquent\Collection {#1091 …2} "field_process_formula" => "katex" "field_edition_group" => Illuminate\Database\Eloquent\Collection {#1088 …2} "field_content_source" => null ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "task" => array:2 [ "refs" => "663311" "type" => "task" ] "text" => "<p>Анилин ($C_6H_5NH_2$) темнеет при хранении на воздухе в результате процесса окисления кислородом ($O_2$), который содержится в атмосфере. Этот процесс значительно ускоряется под действием света.</p><p>Причина такой легкой окисляемости кроется в строении молекулы анилина. Он относится к ароматическим аминам, и его аминогруппа ($-NH_2$), непосредственно связанная с бензольным кольцом, очень активна и чувствительна к действию окислителей.</p><p>Процесс окисления является сложным и многостадийным:</p><ol><li>На начальном этапе анилин окисляется до различных промежуточных соединений, например, до хинонимина.</li><li>Эти промежуточные продукты, как правило, нестабильны и очень реакционноспособны. Они вступают в дальнейшие реакции поликонденсации и полимеризации друг с другом.</li><li>В конечном итоге образуется сложная смесь высокомолекулярных соединений, известных под общим названием "анилиновый черный". Эти полимерные молекулы имеют сложную структуру с протяженными системами сопряженных двойных связей.</li></ol><p>Именно наличие этих протяженных сопряженных систем (хромофорных групп) в молекулах продуктов окисления обуславливает их способность поглощать свет в широкой области видимого спектра. Поглощение большей части падающего света человеческий глаз воспринимает как темный цвет. Таким образом, потемнение анилина — это визуальное проявление его химического превращения из бесцветного вещества в смесь окрашенных полимерных продуктов.</p><p><strong>Ответ:</strong> Анилин темнеет при хранении на воздухе из-за того, что он легко окисляется атмосферным кислородом, в результате чего образуется сложная смесь полимерных продуктов, имеющих темную окраску.</p>" ] #original: array:6 [ "id" => 1515709 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "edition" => Illuminate\Database\Eloquent\Collection {#1087} "task" => array:2 [ "refs" => "663311" "type" => "task" ] "text" => "<p>Анилин ($C_6H_5NH_2$) темнеет при хранении на воздухе в результате процесса окисления кислородом ($O_2$), который содержится в атмосфере. Этот процесс значительно ускоряется под действием света.</p><p>Причина такой легкой окисляемости кроется в строении молекулы анилина. Он относится к ароматическим аминам, и его аминогруппа ($-NH_2$), непосредственно связанная с бензольным кольцом, очень активна и чувствительна к действию окислителей.</p><p>Процесс окисления является сложным и многостадийным:</p><ol><li>На начальном этапе анилин окисляется до различных промежуточных соединений, например, до хинонимина.</li><li>Эти промежуточные продукты, как правило, нестабильны и очень реакционноспособны. Они вступают в дальнейшие реакции поликонденсации и полимеризации друг с другом.</li><li>В конечном итоге образуется сложная смесь высокомолекулярных соединений, известных под общим названием "анилиновый черный". Эти полимерные молекулы имеют сложную структуру с протяженными системами сопряженных двойных связей.</li></ol><p>Именно наличие этих протяженных сопряженных систем (хромофорных групп) в молекулах продуктов окисления обуславливает их способность поглощать свет в широкой области видимого спектра. Поглощение большей части падающего света человеческий глаз воспринимает как темный цвет. Таким образом, потемнение анилина — это визуальное проявление его химического превращения из бесцветного вещества в смесь окрашенных полимерных продуктов.</p><p><strong>Ответ:</strong> Анилин темнеет при хранении на воздухе из-за того, что он легко окисляется атмосферным кислородом, в результате чего образуется сложная смесь полимерных продуктов, имеющих темную окраску.</p>" ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "next" => array:2 [ "refs" => "663312" "type" => "task" ] "previous" => array:2 [ "refs" => "663310" "type" => "task" ] "book" => Illuminate\Database\Eloquent\Collection {#1114 #items: array:1 [ 0 => App\Models\Book {#1049} ] #escapeWhenCastingToString: false } "page" => Illuminate\Database\Eloquent\Collection {#1117 #items: array:1 [ 0 => App\Models\BookPage {#1042 #connection: "mysql" #table: "book_pages" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:21 [ "id" => 926213 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_page_start" => "317" "field_url" => "/10-klass/himiya/eremin-uchebnik/page-317" "field_display_title" => "317" "field_folder" => "1" "field_image_name" => "317" "field_branch_parent" => Illuminate\Database\Eloquent\Collection {#1040 #items: [] #escapeWhenCastingToString: false } "field_weight" => "0" "field_book_parent" => Illuminate\Database\Eloquent\Collection {#1089 #items: array:1 [ 0 => App\Models\Book {#1049} ] #escapeWhenCastingToString: false } "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "edition_groups" => Illuminate\Database\Eloquent\Collection {#1085 #items: [] #escapeWhenCastingToString: false } "content" => Illuminate\Database\Eloquent\Collection {#1125 #items: array:1 [ 0 => App\Models\Element {#1122 #connection: "mysql" #table: "elements" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:6 [ "id" => 1100797 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "edition" => Illuminate\Database\Eloquent\Collection {#1123 …2} "book_page" => array:2 [ …2] "img" => array:1 [ …1] ] #original: array:6 [ "id" => 1100797 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "edition" => Illuminate\Database\Eloquent\Collection {#1123 …2} "book_page" => array:2 [ …2] "img" => array:1 [ …1] ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } "next" => array:2 [ "refs" => "926214" "type" => "book_page" ] "previous" => array:2 [ "refs" => "926212" "type" => "book_page" ] "tasks" => Illuminate\Database\Eloquent\Collection {#1214 #items: array:10 [ 0 => App\Models\Task {#1230 #connection: "mysql" #table: "tasks" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:24 [ "id" => 663310 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_page_start" => "317" "field_page_end" => null "field_url" => "/10-klass/himiya/eremin-uchebnik/54-1" "field_display_title" => "1" "field_outside_task" => null "field_task_type" => Illuminate\Database\Eloquent\Collection {#1231 …2} "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "field_match" => null "breadcrumbs" => [] "edition_groups" => Illuminate\Database\Eloquent\Collection {#1232 …2} "top_parent_branch" => Illuminate\Database\Eloquent\Collection {#1233 …2} "parent_branches" => Illuminate\Database\Eloquent\Collection {#1234 …2} "content" => Illuminate\Database\Eloquent\Collection {#1237 …2} "next" => array:2 [ …2] "previous" => array:2 [ …2] "book" => Illuminate\Database\Eloquent\Collection {#1243 …2} "page" => array:2 [ …2] ] #original: array:24 [ "id" => 663310 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_page_start" => "317" "field_page_end" => null "field_url" => "/10-klass/himiya/eremin-uchebnik/54-1" "field_display_title" => "1" "field_outside_task" => null "field_task_type" => Illuminate\Database\Eloquent\Collection {#1231 …2} "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "field_match" => null "breadcrumbs" => [] "edition_groups" => Illuminate\Database\Eloquent\Collection {#1232 …2} "top_parent_branch" => Illuminate\Database\Eloquent\Collection {#1233 …2} "parent_branches" => Illuminate\Database\Eloquent\Collection {#1234 …2} "content" => Illuminate\Database\Eloquent\Collection {#1237 …2} "next" => array:2 [ …2] "previous" => array:2 [ …2] "book" => Illuminate\Database\Eloquent\Collection {#1243 …2} "page" => array:2 [ …2] ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } 1 => App\Models\Task {#1236 #connection: "mysql" #table: "tasks" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:24 [ "id" => 663311 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_page_start" => "317" "field_page_end" => null "field_url" => "/10-klass/himiya/eremin-uchebnik/54-2" "field_display_title" => "2" "field_outside_task" => null "field_task_type" => Illuminate\Database\Eloquent\Collection {#1235 …2} "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "field_match" => null "breadcrumbs" => [] "edition_groups" => Illuminate\Database\Eloquent\Collection {#1242 …2} "top_parent_branch" => Illuminate\Database\Eloquent\Collection {#1244 …2} "parent_branches" => Illuminate\Database\Eloquent\Collection {#1240 …2} "content" => Illuminate\Database\Eloquent\Collection {#1238 …2} "next" => array:2 [ …2] "previous" => array:2 [ …2] "book" => Illuminate\Database\Eloquent\Collection {#1241 …2} "page" => array:2 [ …2] ] #original: array:24 [ "id" => 663311 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_page_start" => "317" "field_page_end" => null "field_url" => "/10-klass/himiya/eremin-uchebnik/54-2" "field_display_title" => "2" "field_outside_task" => null "field_task_type" => Illuminate\Database\Eloquent\Collection {#1235 …2} "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "field_match" => null "breadcrumbs" => [] "edition_groups" => Illuminate\Database\Eloquent\Collection {#1242 …2} "top_parent_branch" => Illuminate\Database\Eloquent\Collection {#1244 …2} "parent_branches" => Illuminate\Database\Eloquent\Collection {#1240 …2} "content" => Illuminate\Database\Eloquent\Collection {#1238 …2} "next" => array:2 [ …2] "previous" => array:2 [ …2] "book" => Illuminate\Database\Eloquent\Collection {#1241 …2} "page" => array:2 [ …2] ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } 2 => App\Models\Task {#1239 #connection: "mysql" #table: "tasks" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:24 [ "id" => 663312 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_page_start" => "317" "field_page_end" => null "field_url" => "/10-klass/himiya/eremin-uchebnik/54-3" "field_display_title" => "3" "field_outside_task" => null "field_task_type" => Illuminate\Database\Eloquent\Collection {#1252 …2} "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "field_match" => null "breadcrumbs" => [] "edition_groups" => Illuminate\Database\Eloquent\Collection {#1253 …2} "top_parent_branch" => Illuminate\Database\Eloquent\Collection {#1254 …2} "parent_branches" => Illuminate\Database\Eloquent\Collection {#1255 …2} "content" => Illuminate\Database\Eloquent\Collection {#1258 …2} "next" => array:2 [ …2] "previous" => array:2 [ …2] "book" => Illuminate\Database\Eloquent\Collection {#1264 …2} "page" => array:2 [ …2] ] #original: array:24 [ "id" => 663312 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_page_start" => "317" "field_page_end" => null "field_url" => "/10-klass/himiya/eremin-uchebnik/54-3" "field_display_title" => "3" "field_outside_task" => null "field_task_type" => Illuminate\Database\Eloquent\Collection {#1252 …2} "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "field_match" => null "breadcrumbs" => [] "edition_groups" => Illuminate\Database\Eloquent\Collection {#1253 …2} "top_parent_branch" => Illuminate\Database\Eloquent\Collection {#1254 …2} "parent_branches" => Illuminate\Database\Eloquent\Collection {#1255 …2} "content" => Illuminate\Database\Eloquent\Collection {#1258 …2} "next" => array:2 [ …2] "previous" => array:2 [ …2] "book" => Illuminate\Database\Eloquent\Collection {#1264 …2} "page" => array:2 [ …2] ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } 3 => App\Models\Task {#1257 #connection: "mysql" #table: "tasks" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:24 [ "id" => 663313 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_page_start" => "317" "field_page_end" => null "field_url" => "/10-klass/himiya/eremin-uchebnik/54-4" "field_display_title" => "4" "field_outside_task" => null "field_task_type" => Illuminate\Database\Eloquent\Collection {#1256 …2} "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "field_match" => null "breadcrumbs" => [] "edition_groups" => Illuminate\Database\Eloquent\Collection {#1263 …2} "top_parent_branch" => Illuminate\Database\Eloquent\Collection {#1265 …2} "parent_branches" => Illuminate\Database\Eloquent\Collection {#1261 …2} "content" => Illuminate\Database\Eloquent\Collection {#1260 …2} "next" => array:2 [ …2] "previous" => array:2 [ …2] "book" => Illuminate\Database\Eloquent\Collection {#1278 …2} "page" => array:2 [ …2] ] #original: array:24 [ "id" => 663313 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_page_start" => "317" "field_page_end" => null "field_url" => "/10-klass/himiya/eremin-uchebnik/54-4" "field_display_title" => "4" "field_outside_task" => null "field_task_type" => Illuminate\Database\Eloquent\Collection {#1256 …2} "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "field_match" => null "breadcrumbs" => [] "edition_groups" => Illuminate\Database\Eloquent\Collection {#1263 …2} "top_parent_branch" => Illuminate\Database\Eloquent\Collection {#1265 …2} "parent_branches" => Illuminate\Database\Eloquent\Collection {#1261 …2} "content" => Illuminate\Database\Eloquent\Collection {#1260 …2} "next" => array:2 [ …2] "previous" => array:2 [ …2] "book" => Illuminate\Database\Eloquent\Collection {#1278 …2} …1 ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } 4 => App\Models\Task {#1262 #connection: "mysql" #table: "tasks" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:24 [ …24] #original: array:24 [ …24] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } 5 => App\Models\Task {#1276 #connection: "mysql" #table: "tasks" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:24 [ …24] #original: array:24 [ …24] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } 6 => App\Models\Task {#1290 #connection: "mysql" #table: "tasks" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:24 [ …24] #original: array:24 [ …24] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } 7 => App\Models\Task {#1304 #connection: "mysql" #table: "tasks" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:24 [ …24] #original: array:24 [ …24] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } 8 => App\Models\Task {#1318 #connection: "mysql" #table: "tasks" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:24 [ …24] #original: array:24 [ …24] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } 9 => App\Models\Task {#1332 #connection: "mysql" #table: "tasks" #primaryKey: "id" #keyType: "int" +incrementing: true #with: [] #withCount: [] +preventsLazyLoading: false #perPage: 15 +exists: true +wasRecentlyCreated: false #escapeWhenCastingToString: false #attributes: array:24 [ …24] #original: array:24 [ …24] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ …1] } ] #escapeWhenCastingToString: false } ] #original: array:21 [ "id" => 926213 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_page_start" => "317" "field_url" => "/10-klass/himiya/eremin-uchebnik/page-317" "field_display_title" => "317" "field_folder" => "1" "field_image_name" => "317" "field_branch_parent" => Illuminate\Database\Eloquent\Collection {#1040} "field_weight" => "0" "field_book_parent" => Illuminate\Database\Eloquent\Collection {#1089} "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "edition_groups" => Illuminate\Database\Eloquent\Collection {#1085} "content" => Illuminate\Database\Eloquent\Collection {#1125} "next" => array:2 [ "refs" => "926214" "type" => "book_page" ] "previous" => array:2 [ "refs" => "926212" "type" => "book_page" ] "tasks" => Illuminate\Database\Eloquent\Collection {#1214} ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] } ] #escapeWhenCastingToString: false } ] #original: array:24 [ "id" => 663311 "created_at" => "2026-04-10 13:58:26" "updated_at" => null "field_page_start" => "317" "field_page_end" => null "field_url" => "/10-klass/himiya/eremin-uchebnik/54-2" "field_display_title" => "2" "field_outside_task" => null "field_task_type" => Illuminate\Database\Eloquent\Collection {#1037} "field_metatags_title" => null "field_metatags_description" => null "field_h1" => null "field_description_top" => null "field_description_bottom" => null "field_match" => null "breadcrumbs" => [] "edition_groups" => Illuminate\Database\Eloquent\Collection {#1035} "top_parent_branch" => Illuminate\Database\Eloquent\Collection {#1046} "parent_branches" => Illuminate\Database\Eloquent\Collection {#1121} "content" => Illuminate\Database\Eloquent\Collection {#1118} "next" => array:2 [ "refs" => "663312" "type" => "task" ] "previous" => array:2 [ "refs" => "663310" "type" => "task" ] "book" => Illuminate\Database\Eloquent\Collection {#1114} "page" => array:2 [ "refs" => "926213" "type" => "book_page" ] ] #changes: [] #casts: [] #classCastCache: [] #attributeCastCache: [] #dateFormat: null #appends: [] #dispatchesEvents: [] #observables: [] #relations: [] #touches: [] +timestamps: true +usesUniqueIds: false #hidden: [] #visible: [] #fillable: [] #guarded: array:1 [ 0 => "*" ] }
№2 (с. 317)
Условие. №2 (с. 317)
скриншот условия
2. Почему анилин при хранении на воздухе темнеет?
Решение. №2 (с. 317)
Решение 2. №2 (с. 317)
Анилин ($C_6H_5NH_2$) темнеет при хранении на воздухе в результате процесса окисления кислородом ($O_2$), который содержится в атмосфере. Этот процесс значительно ускоряется под действием света.
Причина такой легкой окисляемости кроется в строении молекулы анилина. Он относится к ароматическим аминам, и его аминогруппа ($-NH_2$), непосредственно связанная с бензольным кольцом, очень активна и чувствительна к действию окислителей.
Процесс окисления является сложным и многостадийным:
- На начальном этапе анилин окисляется до различных промежуточных соединений, например, до хинонимина.
- Эти промежуточные продукты, как правило, нестабильны и очень реакционноспособны. Они вступают в дальнейшие реакции поликонденсации и полимеризации друг с другом.
- В конечном итоге образуется сложная смесь высокомолекулярных соединений, известных под общим названием "анилиновый черный". Эти полимерные молекулы имеют сложную структуру с протяженными системами сопряженных двойных связей.
Именно наличие этих протяженных сопряженных систем (хромофорных групп) в молекулах продуктов окисления обуславливает их способность поглощать свет в широкой области видимого спектра. Поглощение большей части падающего света человеческий глаз воспринимает как темный цвет. Таким образом, потемнение анилина — это визуальное проявление его химического превращения из бесцветного вещества в смесь окрашенных полимерных продуктов.
Ответ: Анилин темнеет при хранении на воздухе из-за того, что он легко окисляется атмосферным кислородом, в результате чего образуется сложная смесь полимерных продуктов, имеющих темную окраску.
Другие задания:
Помогло решение? Оставьте отзыв в комментариях ниже.
Присоединяйтесь к Телеграм-группе @top_gdz
ПрисоединитьсяМы подготовили для вас ответ c подробным объяснением домашего задания по химии за 10 класс, для упражнения номер 2 расположенного на странице 317 к учебнику 2023 года издания для учащихся школ и гимназий.
Теперь на нашем сайте ГДЗ.ТОП вы всегда легко и бесплатно найдёте условие с правильным ответом на вопрос «Как решить ДЗ» и «Как сделать» задание по химии к упражнению №2 (с. 317), авторов: Еремин (Вадим Владимирович), Кузьменко (Николай Егорович), Теренин (Владимир Ильич), Дроздов (Андрей Анатольевич), Лунин (Валерий Васильевич), ФГОС (старый) углублённый уровень обучения учебного пособия издательства Просвещение.